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The conventional collector for diasporemineral is oleic acid(OLA),which is highly insoluble and must be used in high dosage in bauxite flotation.Firstly flotation experiments with every reagent(sodium oleate,tween-20)were carried out and it was shown that sodium oleate was an effective diaspore collector,whereas nonionic surfactant tween-20 showed little collectivity.Then experiments were carried out with sodium oleate as the main collector with the addition of tween-20 to study the influences of potentiator on diaspore flotation.It could be seen from the experiments that potentiator had a marked influence on the recovery of diaspore,which was raised by more than 12% and that addition sequence also affected the flotation behavior.It gave the best results with the reagents mixed thoroughly before added and the best ratio of collector oleic acid and potentiator tween-20 stood at 10:1.From the calculation of the ingredients in the sodium oleate solution,at the pH 9,sodium oleate acted with surface of themineral with the acid-soap polymer [HOL·OL-].Zeta potential test showed that the potentiator promoted the absorption of collector on themineral surface,which lowered zeta potential.As could be seen from surface tension experiments,the addition of potentiator tween-20 lowered the CMC(critical micelle concentration) value of oleic acid solution,which was equivalent to raise the power of the agents.By the adsorptive capability tests,with the addition of tween-20,the adsorption of oleic acid on diaspore got more. 相似文献
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本文研究了用表面活性剂Tween20作增溶剂,双硫腙为显色剂直接光度法测定鱼的含汞量并与传统经萃取分离后再测定的方法进行了比较,同时作了回收实验,表明该法测定结果精确可靠。 相似文献
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甘油与丙酮反应制得异丙又甘油,减压蒸馏后,对产物进行了IR,^1HNMR表征。异丙叉甘油与油酸反应合成了单油酸甘油酯,并通过正交实验优化了酯化反应条件。结果表明,以3%油酸质量分数的对甲苯磺酸为催化剂,在n(异丙又甘油):n(油酸)=1:3:1,带水剂甲苯用量为理论产水量的10倍,酯化反应7h的条件下,酯化反应油酸转化率最高达98.5%。 相似文献
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Span80 的水解与液膜溶胀的关系 总被引:7,自引:0,他引:7
测定了油溶性表在性剂失水山梨糖醇酐单油酸脂(Span80)在碱性介质中水解的速率常数,实验表明Span80的水解在一定条件下不可当作零级反应处理,探讨了Span80水解与液膜溶胀的关系。 相似文献
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