σ-迁移反应过渡态的分子轨道研究

本文按立体化学进程对σ-H迁移和σ-C迁移反应过渡态的轨道拓朴类型进行了分类,并计算了反应过渡态的分子轨道能级以及相应反应的活化能.     

Sound scattering in dense granular media

The sound propagation in a dense granular medium is basically characterized by the ratio of wavelength to the grain size. Two types of wave transport are distinguished： one corresponds to coherent waves in the long wavelength limit, the other to short-wavelength scattered waves by the inhomogeneous contact force networks. These multiply scattered elastic waves are shown to exhibit a diffusive characteristics of transport over long distances of propagation. Determination of the transport mean free path l^＊ and the inelastic absorption （Q^-1） allows the inference of the structural properties of the material such as the heterogeneity and internal dissipation. The relevance of our experiments for seismological applications is discussed. Moreover, we apply the correlation technique of the configuration-specific sound scattering to monitoring the dynamic behaviour of the granular medium （irreversible rearrangements） under strong vibration, shearing and thermal cycling, respectively.     

一种求和方法

针对一类求和问题,提出一种新的方法:先将单和转化为二重和,再交换求和顺序,进而得到和式的封闭形式.通过几个典型实例说明此方法的优势.