阳离子微粒聚合物在造纸工业中的应用

采用乳剂和溶液的聚合技术制备了不同电荷密度和胶体性质的阳离子微粒聚合物(CPMP)。论文探讨了阳离子微粒聚合物在造纸工业中的应用。研究表明用阳离子或阴离子的聚合物与阳离子微粒聚合物联合使用可以改善纸张的匀度和留着率。其机理可能是由干阳离子微粒聚合物的加入产生了更有效的架桥絮聚。另外阳离子微粒聚合物也是一种良好的施胶剂，研究结果表明施胶效果与聚合物添加量．电荷密度和微粒尺寸有关。通过施胶张可以获得更好的光学和物理性能。     

CHARACTERISTICS OF QUATERNARY AMMONIUM RESISTANT BACTERIA FROM A FINE PAPERMACHINE SYSTEM

To evaluate the biocide effect of quaternary ammonium chloride (QAC), a whitewater sample was taken from a fine papermachine headbox. By plate spreading method, 51 strains of facultative anaerobe were isolated morphologically. Then the strains were separately transferred to basal medium and were incubated before the beginning of log phase. To identify strains with different QAC resistance, 30-120 ppm of N-Alkyl-benzyl-dimethyl ammonium chloride were added to basal medium.Biocide effect was investigated by comparison of bacterial growth, which can be monitored by 600 nm light absorbance of basal medium suspension. Among 51 strains, only 2 strains can Survive for QAC concentration up to 120 ppm. API20E aud 16S rRNA gene sequencing technique were applied to identify two strains with highest (120 ppm)QAC resistance. One strain (HB22)was identified as Morganella morganii. HB22 can resist QAC concentration up to 150 ppm. HB22 is Gram-negative rod, motile with flagella, catalase positive, oxidase negative, Indole positive, H2S production negative, facultative anaerobe. HB22 has optimum growth condition of 35℃ and pH 7.0.HB22 can catabolize only glucose and D (+)-Mannose.The other (HB45) was identified with high similarity among Pseudomonas cf. monteili or Pseudomonas mosselii or Pseudomonas putida. HB45 can resist QAC concentration up to 200 ppm.HB45 is Gram-negative rod, motile with flagella,catalase positive, oxidase negative, Indole negative,H2S production negative, aerobe. HB45 has optimum growth condition of 30℃ and pH 7.4. HB45 can catabolize L-Arabinose, L(+)-Rhanmose, D (+)-Mannose, Glucose, Glycerol, Lactose, Maltose,Raffmose, Xylose, Cellulose and Xylan. The implication of this work to paper industry is also discussed.     

Studies on the Crystallization Properties and Morphology Structure of the Cationic Dyeable Polypropylene Fibers

The crystallization properties and morphology structure of the cationic dyeable polypropylene fibers which were produced by the blending spinning method were studied by making use of X-ray and scanning electron microscopy (SEM). It comes to the conclusions that the larger the crystallite size in the fibers is , the better the dycable properties of the fibers are and there is a little compatibility between the dyeable agent and polypropylene resin. And the dye-uptake of the fibers may be up to 90% because the dyeable agent can uniformly be scattered in polypropylene.     

浅谈铁和碱反应

文献［１～６］报道：“铁同强碱不发生作用”．我们用干燥的铁粉和氢氧化钠进行实验．实验证明：铁能跟强碱反应，反应的化学方程式为     

气相Lys分子体系捕获双电子单重激发态的特性

采用密度泛函理论（DFT）中的B3LYP方法, 在6-311+G(2df)基组水平上, 对气相赖氨酸（Lys）分子和Lys^2-的基态稳定构型进行优化, 并用含时密度泛函理论（TD DFT)方法考察气相Lys分子和带电离子体系单重激发态的特性. 结果表明： Lys分子体系捕获双电子时, 其体系能量有所增加； S1单重激发态与S0基态能量差值变小； 分子体系的荧光波长增加； S7单重激发态跃迁轨道数减少.     

Influence of Microstructure and Sintering Routes on Transport Properties of Apatite Materials for Fuel Cells

1 Results Oxy-apatite materials are thought as zirconia-substitutes in Solid Oxide Fuel Cells due to their fast ionic conduction. However, the well known difficulties related to their densification prevent them from being used as such. This study presents strategies to obtain oxy-apatite dense materials and the influence of elaboration route on transport properties. Particular emphasis is put on the microstructure effect on ion conduction. By the combined use of freeze-drying and conventional or spark p...     

咪唑季铵盐棉纤维制备及其对DOSO_3~-吸附性能研究

本文用20%的NaOH溶液对棉纤维的预处理、醚化、接枝合成工艺进行了优化;在不同条件下,研究了咪唑季铵盐棉纤维对DOSO~-_3的吸附性能.结果表明,用NaOH预处理棉纤维后,在适当的条件下醚化棉纤维素,再用氢氧化钠作催化剂,按3 g环氧基纤维素醚与10 mL甲基咪唑配比接枝,得到白色味唑季铵盐纤维素.用咪唑季铵盐棉纤维对DOSO~-_3进行吸附,吸附率可达91.8%,吸附效果令人满意.     

一种新型粘土稳定剂的合成与应用研究

本文简要报导了有机阳离子聚和物(氯化N,N—二甲基二烯丙基铵—二氧化硫)的合成方法,并对其作为粘土稳定剂的性能进行了评价。结果表明,该共聚物稳定粘土的能力高于目前国内外广泛使用的同类聚合物TDC。     

羧基淀粉的制备及其吸附性能的研究

本文研究羧基淀粉的制备条件与吸附重金属离子的容量关系,并研究它的使用条件和性能。     

Zn^2＋在电解还原铕（Ⅲ）过程中的催化行为研究

本文报道微量Zn~(2+)在电解还原铕(Ⅲ)离子过程中的催化作用,研究结果表明:当阴极中含Zn~(2+)时,铕(Ⅲ)离子将缩短到达定量还原的时间,用循环伏安法监控电极过程的结果表明:电极过程是准一级的催化过程。