FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

Acyl-chloride functionalized graphene oxide chemically grafted with hindered phenol and its application in anti-degradation of polypropylene

In this study,graphene oxide (GO) nanosheets were first functionalized by the acyl-chloride reaction and then reacted with hindered phenol (HP) to obtain HP grafted GO (GO-g-HP).The GO-g-HP prepared under the optimized condition exhibited a high efficiency against both thermal and photo oxidation of isotactic polypropylene (iPP).GO-g-HP exhibited a much better anti-aging efficiency than that of HP and GO used individually or that of their physical mixture.The outstanding anti-aging effect of GO-g-HP was attributed to the excellent synergistic effect produced between the chemically bonded GO and HP,which resulted in an improved oxygen barrier property of GO and excellent utilization of the free radical scavenging capability of GO and HP.Also,thanks to the grafting of HP on GO,the physical loss of HP,which was one of the main shortcomings for traditional small molecular antioxidants,was largely suppressed.It is expected that the GO-g-HP prepared can well meet the requirement of long-term applications of polymers in some harsh service conditions.     

半潜式钻井平台螺旋桨修复技术的应用研究进展

针对半潜式海洋钻井平台推进器螺旋桨面临的空泡腐蚀、电化学腐蚀以及海洋生物附着污损等问题，综述了焊接、粘接、热喷涂、冷喷涂修复技术的应用研究进展。认为目前的螺旋桨修复再制造技术普遍存在着修复层应力集中、结合强度低、孔隙率高、高温导致材料变性等缺陷，今后的研究工作应向着避免应力集中、增大修复层结合强度、降低作业温度、减小孔隙率的方向发展，以期能够制备更加致密均匀的修复层。     

环氧-呋喃防护材料的研制

碳化是引起水工钢筋混凝土钢筋锈蚀的重要因素之一．用糠醛、丙酮作活性稀释剂的环氧一呋喃涂料、玻璃钢与混凝土复合使用，粘接性能好，机械性能优良，防碳化、冻融能力强，与混凝土的弹性模量接近，能有效阻止混凝土碳化、钢筋(钢丝网)锈蚀．经过20余项工程应用及10余年的考验效果良好．     

井下抽油泵柱塞与泵筒运动规律的研究

用三元振动模型,综合考虑油柱、抽油杆柱和油管柱的振动.建立起数学模型并离散化,然后用微机编程求解微分方程组.对不同工况下的抽油泵运动规律和抽油机示功图进行分析研究,得出了油管应予锚定的结论,并给出了不同抽油机的适用范围.为进一步研究抽油泵的井下工作机理和故障原因打下了基础.     

用正交试验法确定最佳调剖施工参数

针对文明寨油田地质特征和开采现状，按照油藏数值模拟原理，以调剖井对应油井的增油降水创经济效益大小为考核指标，运用正交试验的均衡分散性和整齐可比性及Ｌ９（３４），正交表进行调剖最佳施工参数试验．经现场试验、分析、讨论发现：影响调剖效果的主要因素是措施半径，其次为施工排量和注入方式，且最佳施工参数是措施半径在３．５ｍ左右，施工排量在１９ｍ３／ｈ左右，按连续注入方式调剖。经文明察油田、卫城油田、马寨油田５０井次现场试验证明，较好地改善了注水井吸水剖面，对应油井取得了明显的增油降水效果，收到了较好的经济和社会效益．     

内隐知识的编码

知识的编码是一个渐进的过程，内隐知识和编码知识只是知识在不同编码程度时的表述，其中内隐知识高度依赖行为主体，而编码知识具有可共享性，能够脱离其生产者而存在和传播。内隐知识是伴随性的，它依赖于背景知识和知识生产者的洞察力、直觉、思维模式、信仰、经验等因素。内隐知识主要有四种编码方式：数字化、程序化、定义分类和隐性传播。     

变频调速装置在离心机拖动系统上的应用

对离心机拖动系统进行变频改造 ,既节约大量电能和设备维修费用 ,提高安全生产可靠性 ,又能提高生产自动化水平     

椭圆偏振法研究四方氧化锆对Zr-Sn-Nb合金氧化膜耐腐蚀性能的影响

将经过不同热处理的Zr-Sn-Nb合金样品放在350℃、16．8mol／LPa、0．01mol／LLiOH溶液的高压釜中进行腐蚀。用椭圆偏振法研究氧化膜中的四方氧化锆，发现经过580℃／冷轧／500℃处理的样品在腐蚀42天和190天后氧化膜中的四方氧化锆比其它样品的多。四方氧化锆是影响合金耐腐蚀性能的一个主要因素，四方氧化锆的形成有利于提高合金的耐腐蚀性能。     

合成N,N,N'''',N''''-四(2-甲酯基乙基)乙二胺的绿色工艺研究

为了解决合成聚酰胺-胺时回收液处理复杂、能耗大、并污染环境的问题,以合成N,N,N',N'-四(2-甲酯基乙基)乙二胺(TMCEDA)为研究对象,对不同真空度条件下的回收液进行了定性定量分析,在此基础上,采用分段减压蒸馏分离合成TMCEDA中的过量原料与溶剂,直接循环使用真空度在50 kPa-100 kPa的回收液的新工艺.应用气相色谱分析技术跟踪分析循环使用的回收液的成分,结果表明,经过40次循环使用的回收液,仍未见明显的杂质积累现象.该工艺对回收液的直接使用率高达98.0%,实现了TMCEDA的实验室绿色合成,可为其工业化生产提供参考.图7,表2,参11.