FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

Acyl-chloride functionalized graphene oxide chemically grafted with hindered phenol and its application in anti-degradation of polypropylene

In this study,graphene oxide (GO) nanosheets were first functionalized by the acyl-chloride reaction and then reacted with hindered phenol (HP) to obtain HP grafted GO (GO-g-HP).The GO-g-HP prepared under the optimized condition exhibited a high efficiency against both thermal and photo oxidation of isotactic polypropylene (iPP).GO-g-HP exhibited a much better anti-aging efficiency than that of HP and GO used individually or that of their physical mixture.The outstanding anti-aging effect of GO-g-HP was attributed to the excellent synergistic effect produced between the chemically bonded GO and HP,which resulted in an improved oxygen barrier property of GO and excellent utilization of the free radical scavenging capability of GO and HP.Also,thanks to the grafting of HP on GO,the physical loss of HP,which was one of the main shortcomings for traditional small molecular antioxidants,was largely suppressed.It is expected that the GO-g-HP prepared can well meet the requirement of long-term applications of polymers in some harsh service conditions.     

110kv及其以下的油浸电力变压器的优化设计

变压器的优化设计是变压器设计的核心,根据变压器自身的特征,通常采用遗传算法进行优化。本系统通过采用改进GA的父代参与竞争的最优保存遗传算法进行优化,得到了几乎必然收敛的优化效果。     

志丹活性白土对食用油的脱色研究

以志丹白土为原料，经酸活化所得活性白土应用于食用油的脱色，详细研究了脱色工艺条件，并与浙江等地的活性白土产品的脱色效果进行比较，结果表明：志舟活化白土具有较好的脱色性能。     

200MW汽轮发电机组进油问题初析

对国产200MW汽轮发电机组普遍存在的向机内进油及密封油系统运行不稳定等问题进行了较为详细的分析,指出发电机氢侧回油腔窄小,回油不畅,密封瓦及内油挡安装不良;平衡阀灵敏度低,可靠性差;压差阀发卡发涩,跟踪性能差;密封油箱补排油不畅等因素是造成上述问题的主要原因,并提出了相应的改进措施。     

工程中常用的几种氧化沟及其发展

简要介绍了当今工程中常用的几种氧化沟技术的特点及其发展历程,主要包括Carrousel氧化沟、Orbal氧化沟、交替式氧化沟以及一体化氧化沟。     

抗癌药物蓖麻油提取物的气相色谱分析

文[1]曾报道将蓖麻油提取物精制品制成乳剂和多相脂质体,进行动物体内外抗癌活性实验,结果表明该提取物具有较强的抗癌活性,但其抗癌活性成分的组成和含量尚不清楚.本实验就蓖麻油提取物的组成和含量进行气相色谱分析.     

pH、温度和浓度对苯酚在V掺杂MoOx-C/Ti电极上的电催化氧化的影响

采用溶胶-凝胶法合成MoOx、MoOx-V5 (x%)胶体,通过Vulcan XC-72炭黑负载制备炭载钼系氧化物电催化剂.利用循环伏安法(CV)测试手段研究苯酚在电极上的氧化降解,考察了掺杂元素、溶液pH值、苯酚浓度、扫描速率、温度对苯酚氧化性能的影响.测试结果表明:苯酚在电极上的氧化是受扩散和电子转移联合控制的复杂过程;掺杂过渡金属元素V可以降低苯酚氧化的表观活化能,提高电化学性能;溶液的pH值越低,MoOx-C/Ti电极对苯酚的催化氧化活性越高;pH在0～6,苯酚的氧化经历了相似的历程,包含了相同的电子数和质子数;苯酚氧化峰电流随着浓度、温度的增加而增加,到一定程度后趋于稳定.     

美国对非石油战略的地缘政治透视

冷战时期，非洲由于丰富的自然资源和重要的战略位置成为美苏两个超级大国争夺的重要区域。冷战结束以后，随着前苏联的解体，非洲的战略地位有所下降，美国对非洲的兴趣也日益减弱。但近几年来，美国对非洲的战略开始由冷变热。文章从政治地理角度对美国近年来对非石油战略的转变进行了分析。     

增塑剂ZS-301的合成研究

以棕榈油为原料合成增塑剂ZS-301，对棕榈油品质(以熔点计)，氢氧化钠用量，氯化锌用量通过正交试验进行了确定。结果表明最佳条件为：选择熔点为48℃～51℃的棕榈油．氢氧化钠的用量16份，氯化锌用量15份(以棕榈油重量为100份计)。在最佳条件下所制得的10批样品均符合国外Pirelli公司同类产品的指标要求。