氟化物熔体中电解共沉积硼化钛的阴极过程

采用循环伏安法首次研究了ＬｉＦ－ＮａＦ－Ｋ２ＴｉＦ６－ＫＢＦ４熔盐体系中钛离子和硼离子在铂、钼电极上电化学还原及电合成硼化钛的阴极过程机理。对恒电位电解的沉积物进行了Ｘ射线衍射分析。结果表明，当体系中硼钛摩尔比Ｂ／Ｔｉ大于２时，钛与硼可在同一电位下实现电解共沉积并反应生成硼化钛。     

Superconductivity in Ba1−xSmxFFeAs and Eu1−xSmxFFeAs systems

We synthesized the samples Ba1-xSmxFFeAs and Eu1-xSmxFFeAs with ZrCuSiAs-type structure. These samples were characterized by resistivity and susceptibility. It is found that the substitution of rare earth metal for alkaline earth metal in the two systems suppresses the anomaly in resistivity and induces superconductivity. Superconductivity at 54 K in nominal composition Ba0.5Sm0.5FFeAs and at 51 K for Eu0.5Sm0.5FFeAs is realized, indicating that the superconducting transition temperatures in the iron arsenide fluorides is the same as that in oxypnictides with the same structure.     

Superconductivity in Ba_(1-x)Sm_xFFeAs and Eu_(1-x)Sm_xFFeAs systems

We synthesized the samples Ba1-xSmxFFeAs and Eu1-xSmxFFeAs with ZrCuSiAs-type structure. These samples were characterized by resistivity and susceptibility. It is found that the substitution of rare earth metal for alkaline earth metal in the two systems suppresses the anomaly in resistivity and in-duces superconductivity. Superconductivity at 54 K in nominal composition Ba0.5Sm0.5FFeAs and at 51 K for Eu0.5Sm0.5FFeAs is realized, indicating that the superconducting transition temperatures in the iron arsen...     

Fluoride evaporation and crystallization behavior of CaF2–CaO–Al2O3–(TiO2) slag for electroslag remelting of Ti-containing steels

To elucidate the behavior of slag films in an electroslag remelting process, the fluoride evaporation and crystallization of CaF₂–CaO–Al₂O₃–(TiO₂) slags were studied using the single hot thermocouple technique. The crystallization mechanism of TiO₂-bearing slag was identified based on kinetic analysis. The fluoride evaporation and incubation time of crystallization in TiO₂-free slag are found to considerably decrease with decreasing isothermal temperature down to 1503 K. Fish-bone and flower-like CaO crystals precipitate in TiO₂-free slag melt, which is accompanied by CaF₂ evaporation from slag melt above 1503 K. Below 1503 K, only near-spherical CaF₂ crystals form with an incubation time of less than 1 s, and the crystallization is completed within 1 s. The addition of 8.1wt% TiO₂ largely prevents the fluoride evaporation from slag melt and promotes the slag crystallization. TiO₂ addition leads to the precipitation of needle-like perovskite (CaTiO₃) crystals instead of CaO crystals in the slag. The crystallization of perovskite (CaTiO₃) occurs by bulk nucleation and diffusion-controlled one-dimensional growth.     

KZnF_3:Mn~(2+)的光谱和电子顺磁共振谱分析

本文使用Mn~(2+)的参量化d轨道和d~5电子Oh对称的双值不可约表示Hamiltonian矩阵对KZnF_3:Mn~(2+)和KMnF_3的吸收光谱和电子顺磁共振(EPR)谱进行了研究。从这些分析中我们得出了B、C和Dq对MnF_6~(4-)结构参量R的依靠关系,在实验误差范围内,B和C是常数,仅Dq随R变化,且给出了定量关系。并由KZnF_3:Mn~(2+)在15-300K温度范围内的吸收光谱和电子顺磁共振谱求得Mn~(2+)～F~-键长R的热膨胀为R=0.207 0～0.208 0nm.和dR/dT=3.508 8x10~(-6)nm/K。     

RE2O3-NH4HF2系合成稀土氟化物的反应规律

在RE2O3-NH4HF2系中,以稀土氧化物和氟化氢铵为原料,分别在常压和真空状态下,研究了该体系的各步反应,提出了新的合成REF3反应规律.粉状La2O3,Gd2O3与NH4HF2在低温下开始反应,产物为RENH4F4(RE=La,Gd),NH4F,NH3和H2O,高温下RENH4F4分解为REF3和NH4F,伴有NH4F的挥发和分解;整个过程包括合成、分解和脱铵三个步骤;真空可以降低反应的起止温度.制备稀土氟化物应采用"常压低温合成一真空高温分解、脱铵"工艺.     

函数连接型神经网络在氟化物非晶态形成条件中的应用

函数增强型神经网络(Functional Link Net,简称FLN)是一种无隐含层的新型网络,应用其三阶联合激励增强特性来对三元体系氟化物非晶态形成条件进行识别研究,识别准确率近100%.在对预测集的每一个输入信号添加10%的噪音干扰后,发现识别率依然不变.直到噪音添加到15%,仍然能准确判别.可见网络的容错能力是十分令人满意的.     

过磷酸钙生产中氟化氢及氟化物对环境的污染

为了对磷肥厂产生氟化氢及氟化物对环境污染进行调查,对磷肥生产车间以及车间外大气、排出废水、周边土壤和对照组进行氟化物含量测定.结果表明,磷肥生产车间和车间外大气、排出废水、土壤氟化物含量均高于对照组(P<0.05),故应加强对磷肥厂排出废水废气处理,加强环保意识.     

氟化物熔盐中B（Ⅲ）的电化学还原

用循环伏安法和卷积技术研究了ＬｉＦ－ＮａＦ低共熔体中，以ＫＢＦ４形式加入的Ｂ（Ⅲ）在铂电极上阴极还原机理。结果表明，Ｂ（Ⅲ）的电化学还原为简单的三电子一步反应，阴极过程在所研究的扫描速度下接近于可逆过程，且受扩散控制，硼在铂电极上形成可溶性产物。