On the Circulant and Aperiodic Models of Deconvolution

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乳清酸的2.5次微分示波极谱法测定

拟定了乳清酸的2.5次微分示波极谱测定新方法.结果表明在0.8 mol/L HCl介质中,乳清酸产生一灵敏的极谱还原波,峰电位Ep =-0.77 V(vs.SCE);其2.5次微分极谱峰峰电流ep″与乳清酸浓度在4.0×10-8～4.0×10-5 mol/L范围内呈良好线性关系(r=0.999 6,n=9),检测限为1.0×10-8 mol/L;13次平行测量4.0×10-7 mol/L乳清酸的峰电流,所得RSD为1.8%.该方法可直接用于测定牛奶中乳清酸的含量.     

A gas chromatography/mass spectrometry method for the simultaneous analysis of 50 phenols in wastewater using deconvolution technology

Phenolic compounds exist widely in the influents and effluents of sewage treatment plants (STPs) and most are un-regulated. In this study, a gas chromatography-mass spectrometry (GC-MS) method for the simultaneous analysis of 50 phenolic compounds in wastewater was developed. Deconvolution technology was used to identify contaminants that are covered by co-extracted materials. A mass spectral library containing all 50 silylated phenolic compounds was first established and used for deconvolution. Twelve typical phenolic compounds were selected to optimize the sample preparation procedures. Solid-phase extraction using a C18 cartridge coupled with an HLB cartridge was used for pre-concentration and dichloromethane was used for elution. The solutes were derivatized and analyzed by GC-MS. The blank and matrix spike recoveries ranged from 57.46% to 136.4% and 47.87% to 114.8%, respectively. Method detection limits ranged from 3.64 to 97.64 ng L⁻¹. The relative standard deviations of all the recovery experiments were lower than 13.6%. The instrument limits of quantification ranged from 0.7 to 87.7 pg. The method has been applied to analyze the influents and effluents of 5 Chinese STPs. Except for regulated phenolic compounds (phenol and 2,4,6-trichlorophenol), three un-regulated phenolic compounds, including 2-chlorophenol, 2,5-dichlorophenol and 2,4-dichloro-3-ethyl-6-nitrophenol were identified in the effluent wastewater. The detected concentrations of un-regulated phenolic compounds could possibly cause environmental effects, indicating that immediate attention is required to prevent complications.     

计算机辅助解析FTIR定量研究蛋白质构象的应用进展

综述了计算机辅助解析傅里叶变换红外光谱在蛋白质构象定量研究中的应用进展,简要介绍了红外光谱测定及二阶导数谱、去卷积和曲线拟合等计算机数学处理方法.对已有的研究结果进行了分类总结,最后讨论了该领域中存在的问题和发展方向.     

Satellite Image Adaptive Restoration Using Periodic Plus Smooth Image Decomposition and Complex Wavelet Packet Transforms

A satellite image adaptive restoration method was developed that avoids ringing artifacts at the image boundary and retains oriented features. The method combines periodic plus smooth image decomposition with complex wavelet packet transforms. The framework first decomposes a degraded satellite image into the sum of a "periodic component" and a "smooth component". The Bayesian method is then used to estimate the modulation transfer function degradation parameters and the noise. The periodic component is deconvoluted using complex wavelet packet transforms with the deconvolution result of the periodic component then combined with the smooth component to get the final recovered result. Tests show that this strategy effectively avoids ringing artifacts while preserving local image details (especially directional textures) without amplifying the noise. Quantitative comparisons illustrate that the results are comparable with previous methods. Another benefit is that this approach can process large satellite images with parallel processing, which is important for practical use.     

退卷积过程中的低能尾修正

本文详述了康普顿轮廓测量退卷积处理过程中,关于低能端谱形畸变(即低能尾)的修正的思路和具体方法     

基于消卷积的三维成像雷达散射截面测量技术

基于三维成像雷达散射截面积(RCS, Radar cross section)测量技术是近年新兴的一种灵活、高效的RCS测量技术。该技术基于三维线阵合成孔径雷达(SAR, Synthetic aperture radar)测量系统对目标进行近场三维高分辨成像,通过近远场变换算法,得到目标的远场RCS,具备近场、外场测量能力。基于成像的RCS测量,其成像精度就直接影响着RCS的测量精度,因此,为了得到高质量的RCS结果,就需要得到高分辨的图像。本文采用压缩感知三维成像算法对目标进行成像,有效提高了RCS的反演精度,并分析了改进CLEAN算法的抑制旁瓣原理,得出两种方法都是基于消卷积原理对旁瓣进行抑制。用MATLAB和FEKO测量仿真,结果表明压缩感知算法提取散射中心效果更好,且提高了RCS的反演精度。     

反褶积与信噪比的关系研究

在地震资料数字处理中 ,分辨率与信噪比是一对相互制约的矛盾 ,为了在反褶积处理过程中控制信噪比 ,从理论上分析了反褶积后剖面信噪比降低的原因 .以不同相位子波为例 ,从时间域出发 ,利用最小平方反滤波原理计算出反褶积算子 ,并验证了反褶积后剖面信噪比的降低是受反子波能量的影响 .为了兼顾分辨率和信噪比 ,进而分析讨论了反褶积中的白噪化问题 ,提出可以用加入白噪的方法来控制信噪比 ,但白噪不易加入过大 ,否则 ,由于加入白噪后求出的反子波不再是原来子波的逆 ,从而又将影响剖面分辨率的提高     

康普顿轮廓测量中的数据处理

以铁的γ射线散射谱为例说明康普顿轮廓数据处理的全过程。主要包括：减本底、退卷积、标度变换、吸收修正、截面修正、多次散射修正等。     

Deconvolution techniques for characterizing indoor UWB wireless channel

A deconvolution algorithm is proposed to account for the distortions of impulse shape introduced by propagation process. By finding the best correlation of the received waveform with the multiple templates, the number of multipath components is reduced as the result of eliminating the ＂phantom paths＂, and the captured energy increases. Moreover, it needs only a single reference measurement in real measurement environment （do not need the anechoic chamber）, which by far simplifies the templates acquiring procedure.