浅谈铁和碱反应

文献［１～６］报道：“铁同强碱不发生作用”．我们用干燥的铁粉和氢氧化钠进行实验．实验证明：铁能跟强碱反应，反应的化学方程式为     

Influence of Microstructure and Sintering Routes on Transport Properties of Apatite Materials for Fuel Cells

1 Results Oxy-apatite materials are thought as zirconia-substitutes in Solid Oxide Fuel Cells due to their fast ionic conduction. However, the well known difficulties related to their densification prevent them from being used as such. This study presents strategies to obtain oxy-apatite dense materials and the influence of elaboration route on transport properties. Particular emphasis is put on the microstructure effect on ion conduction. By the combined use of freeze-drying and conventional or spark p...     

羧基淀粉的制备及其吸附性能的研究

本文研究羧基淀粉的制备条件与吸附重金属离子的容量关系,并研究它的使用条件和性能。     

混合氯化稀土催化合成DOP,DOM和DOA

本文报道:价廉的混合氯化稀土,对合成DOP等增塑剂有明显的催化效果。产品精制简单,转化率高,有应用前景。     

氯化铝工业生产中几个工艺技术问题的探讨

本文详细论述了利用废铝生产氯化铝过程中,设备及各控制因此对产品质量和颗粒度的影响,(?)了适宜的控制条件和设计要求,为生产不同用户需求的合格产品提供了可靠的依据。     

半导体单晶硅的离子束蚀刻实验研究

离子束蚀刻是一种有超精细加工能力的微细加工技术,广泛应用于微电子、光子技术、表面科学等领域。硅及其化合物常用来制作大规模集成电路,在其表面蚀刻出具有一定几何布图尺寸的沟槽。其深度、宽度、边壁倾角及槽底形状等直接影响器件的性能。     

MeV Pb离子在非晶Si中的射程离散──离子束混合和增强扩散的影响

１．０ＭｅＶ２０８Ｐｂ离子在非晶Ｓｉ中的投影射程ＲＰ和射程偏差ΔＲＰ作为注量和温度二者的函数用背散射法进行测定．注量的变化范围为５×１０１３～７×１０１４ｃｍ－２．注入是在室温和ｔ＝－１２０℃下完成的．由由实验所确定的投影射程，射程偏差与注量或温度无关，并且分别等于２９５和７２．２ｎｍ．与ＴＲＩＭ８６的计算结果相比较，发现ＲＰ的偏离为１８％，而ΔＲＰ的偏离为３６％．ＲＰ和ΔＲＰ二者与注量及温度的无关性，排除了所观察到的与ＴＲＩＭ的矛盾是由于注入期间辐射增强扩散或离子束混合效应而引起的解释。     

镁改型蛭石对铵离子的交换性能

对经人工改型所得的镁型蛭石进行了铵离子交换性能的研究．在不同pH值下测定了镁型蛭石对NHr的全交换容量，在不同温度下测定了样品的平衡等温线．结果表明，镁型蛭石对NH4^ 的交换总量随pH值的变化而波动，在pH值为7时其交换总量为59．32mmol／100g，其选择性随温度的降低而升高，这为蛭石作为一种新型填料提供了一定的理论依据。     

Parity Nonconservation in of Multiply Dielectronic Recombination Charged Ions

A parity nonconserving （PNC） asymmetry in the cross section for dielectronic recombination of polarized electrons on multiply charged ions with Z≥40 is discussed. This effect is strongly enhanced for close doubly-excited states of opposite parity in the intermediate compound ion. Such states are known for He-like ions. However, these levels have large energy and large radiative widths which hampers observation of the PNC asymmetry. We argue that accidentally degenerate states of more complex ions may be more suitable for the coresponding experiment.     

Ab initio study of the effects of Ag/Mn doping on the electronic structure of LiFePO_4

Based on density functional theory (DFT) of the first-principle for the cathode materials of lithium ion battery, the electronic structures of Li(Fe1-xMex)PO4 (Me = Ag/Mn, x = 0―0.40) are calculated by plane wave pseudo-potential method using Cambridge serial total energy package (CASTEP) program. The calculated results show that the Fermi level of mixed atoms Fe1-xAgx moves into its conduction bands (CBs) due to the Ag doping. The Li(Fe1-xAgx)PO4 system displays the periodic direct semiconductor characteristic with the increase of Ag-doped concentration. However, for Fe1-xMnx mixed atoms, the Fermi level is pined at the bottom of conduction bands (CBs), which is ascribed to the interaction be-tween Mn(3d) electrons and Fe(4s) electrons. The intensity of the partial density of states (PDOS) near the bottom of CBs becomes stronger with the increase of Mn-doped concentration. The Fermi energy of the Li(Fe1-xMnx)PO4 reaches maximum at x = 0.25, which is consistent with the experimental value of x = 0.20. The whole conduction property of Mn-doped LiFePO4 is superior to that of Ag-doped LiFePO4 cathode material, but the structural stability is reverse.