粉末冶金陶瓷模工艺中的快速脱蜡新技术

粉末冶金陶瓷模工艺是一种先进的过净形成形工艺．本文报道该工艺中一种新的脱蜡技术．采用快速加热、管径集中热量和定向导热传热综合方法，在陶瓷模和大部分蜡模材料处于较低温度下，使蜡模材料来不及发生显著的热膨胀而直接蒸发，得到脱蜡干净、外形完整的陶瓷模．     

无机化学中共价键类型及其在元素周期表中变化规律

无机化学中常见共价键有双电子σ键(包括σ配键)、双电子π键、单电子键、三电子键、离域π键、多中心键、反馈π键(包括d-pπ键、d-dπ键和π←dπ键)等.不同化学键的形成,对物质性质有着重要影响.本文主要讨论无机化合物中常见共价键形成条件和特征,对物质性质影响及其在元素周期表中变化规律.     

High Speed Cutting Inconel 718 with Coated Carbide and Ceramic Inserts

High speed machining (HSM) technology is one of important aspects of advanced manufacturing technology. Nickel-based superalloys have been widely used in the aircraft and nuclear industry due to their exceptional thermal resistance and the ability to retain mechanical properties at elevated temperatures of service environment over 700 ℃. However, they are classified as difficult-to-cut materials due to their high shear strength, work hardening tendency, highly abrasive carbide particles in the microstructur...     

A New Shaping Model for Green Ceramic Balls

The shaping quality of green ceramic balls is directly related to the efficiency and cost of later machining for the ceramic balls. Until now the shaping for green ceramic balls is still conducted by handwork. In this paper, a new shaping model for green ceramic balls was designed. In the new model, two grinding wheels with the same generator line as circular arc are mounted on symmetry, and their axes are parallel. The green ball can be put in the enveloping space formed by the two grinding wheels. The rad...     

粘结开裂破坏框架柱性能的研究

本文以试验结果为基础,通过轴压力、配筋、配箍、加载方向的变化,分析了这些因素对产生粘结开裂破坏框架柱性能的影响,并给出了产生粘结开裂破坏的m值下限。     

引线键合的界面特性

利用扫描电镜和EDS能谱分析研究了Al-Al,Au-Al和Au-Ag超声键合横界面和纵切面的微观结构特性及其变化,分析了键合界面结构随超声功率和作用时间变化的规律.研究结果表明:超声键合界面的形状特性像一个中央未结合的椭圆,皱脊周边产生键合,其键合强度取决于激烈起皱的周边和未结合的中央面;当作用力和功率固定时,随着时间的增加,键合区向中央延伸;当作用力和作用时间固定时,随功率的增加,焊接区里皱脊面扩大;Au-Ag扩散偶的Kirkendall扩散效应及Au-Al键合界面可能形成金属间化合物.     

Finesse 全瓷冠适合性的体外实验研究

目的 :测量Finesse全瓷冠的边缘浮出量及粘固剂的厚度 ,并与金属全冠及金瓷全冠相比较 ,为Finesse全瓷冠的临床应用提供适合性方面的理论依据。方法 :用片切法测量 3组全冠粘固前、后边缘浮出量及粘固剂的厚度。结果 :Finesse全瓷冠粘固前、后的边缘浮出量分别为 (37 6 1± 9 13) μm、(6 5 85± 15 11) μm ,粘固剂厚度为 (40 84± 9 73) μm ,与金属全冠及金瓷全冠相比较 ,均无显著性差异 ;3组全冠粘固前和粘固后的边缘浮出量有显著性差异。结论 :Finesse全瓷冠适合性良好 ,完全可为临床应用 ;粘接对全冠修复体的边缘浮出量有影响。     

Theoretical study on the lithium bond interaction of furan homologues C_4H_4Y (Y=O, S) with LiCH_3 via DFT and MP2

The optimizations geometries and interaction energy corrected by BSSE of the complexes between C4H4Y (Y=O, S) and CH3Li have been calculated at the B3LYP/6-311 G** and MP2/6-311 G** levels. Three complexes were obtained. Abnormally, the calculations showed that all the C10—Li14 bond lengths increased obviously but the blue-shift of C10—Li14 stretching frequency occurred after formed complexes. The calculated binding energy with basis set super-position error (BSSE) and zero-point vibrational energy corrections of complexes I―III is ?45.757, ?35.700 and ?39.107 kJ·mol?1, respectively. The analyses on the combining interaction with the atom-in-molecules theory (AIM) also showed that a relatively strong lithium bond interaction presented in furan homologues C4H4Y---LiCH3 systems. Natural bond orbital theory (NBO) analysis has been performed, and the results revealed that the com- plex I is formed with n-σ type lithium bond interaction between C4H4O and LiCH3, complex II is formed with π-s type lithium bond interaction between C4H4O and LiCH3, and complex III is formed with π-s and n-s type lithium bond interactions between C4H4S and LiCH3, respectively.