FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

海上电泵结蜡井热循环洗井工艺参数优化设计

为探索海上油田电泵举升结蜡井热循环洗井工艺井筒温度场分布规律，综合考虑潜油电机增温、电缆散热、热流体注入量、注入深度、注入温度、结蜡管段传热和海水空气导热的影响，基于热能守恒原理，建立了电泵井结蜡热循环洗井工艺井筒温度场计算模型，分析了热流体注入温度和注入量对混合产出流体的井筒温度分布的影响。研究结果表明，随着注入量的增加混合产出液沿程井筒温度增加，随着注入温度的增加混合产出液沿程井筒温度增加。该方法可有效指导现场措施工艺的实施，达到延长结蜡井的清蜡周期、延缓产液/产油量下降速度的目的。     

漳州某基坑抽水引起地面沉降的初探

由于基坑快速抽水导致基坑周边地面沉降。通过对场地因抽水引起地面沉降的计算和试抽水等方面的前期工作,分析了因基坑降水对地面沉降的影响,并据此来调整完善基坑降水方案,取得了明显的社会和经济效益。     

反渗透系统的设计思路探讨

反渗透作为一种重要的水处理技术,越来越广泛地应用到各种领域,其处理水源也变得复杂多样化,因此要求在反渗透系统和反渗透预处理设计时予以高度关注。本文主要讨论针对不同水源时反渗透系统的设计思路。     

福州盆地南北港冲淤规律与洪涝灾害对策

本文探讨了福州盆地南北港冲淤规律，近年来北港洪水分流量呈上升趋势，洪峰对北港的压力加大，文中还对福州城防洪涝灾害的措施等方面作了研究。     

Electrochemical Preparation of WO_3 Nanowire Arrays

1 Results Ordered WO3 nanowires arrays have been fabricated by electrochemical deposition with anodic aluminum oxide (AAO) templates and annealing the W nanowire arrays in air at 400 ℃. The morphology and the chemical composition of WO3 nanowires arrays were characterized by Scanning Electron Microscopy (SEM),Transmission Electron Microscopy (TEM), X-ray Photoelectron Spectroscopy (XPS), and X-ray diffraction (XRD). The results show that the diameters of the WO3 nanowires are about 90 nm, which is in go...     

催化裂解法制备螺旋状碳纳米管的实验研究

在硅片上用直流溅射镀铁的方法制备催化剂 ,通过乙炔在 70 0°C下催化裂解制备碳纳米管 .对热解产物进行了扫描电镜观察和 X射线衍射测试 .本文通过对有氢气预处理和没有氢气预处理两种情况下催化裂解法制备的碳纳米管的形貌、管径大小等性质的研究 ,来初步揭示螺旋状碳纳米管的生长机理 .     

高频等离子体化学气相淀积法制备TiO2超细粒子

利用ＴｉＣｌ４＋Ｏ２体系，在高频等离子体化学气相淀积反应器中合成了纯度高、粒度细的ＴｉＯ２粒子。考察了工艺条件对ＴｉＯ２粒子物性的影响；探讨了ＴｉＯ２粒子晶型控制的方法，金红石型质量分数可通过工艺条件控制；探讨了ＴｉＯ２粒子晶型控制的方法。金红石型质量分数可通过工艺条件控制，减少ＴｉＯ２单体浓度可提高金红石型质量分数；也可通过在原料ＴｉＣｌ４中添加ＡｌＣｌ３等晶型转化剂，使可转化为单一金红石型Ｔｉ     

化学气相沉积法制备光谱选择性碲膜

用化学气相沉积法制备碲薄膜,其步骤为：通过电化学方法制得碲化氢,碲化氢在室温下分解后在聚乙烯塑料箔上沉积得到碲薄膜.用傅里叶红外光谱仪、紫外/可见/近红外光谱仪、X射线衍射仪及扫描电镜表征碲薄膜的光学性能和结构.结果表明,化学气相沉积法在Mn-O覆盖的聚乙烯塑料箔上沉积得到的碲薄膜在大气窗口（8～13μm）光谱区域具有很高的透过率,同时能阻挡几乎所有的太阳光谱,表明碲薄膜是适用于辐射制冷装置的太阳光辐射屏蔽材料.