光谱添加剂在粉末样品分析中的作用

通过模拟实验,研究了具有不同作用的４种光谱添加剂对铁矿粉末样品分析的影响。实验结果表明,最佳载体效应和最佳缓冲效应所对应的添加剂质量分数一般不同。     

Effect of Graphene Nanoplatelets addition on mechanical properties of pure aluminum using a semi-powder method

In recent years, graphene has attracted considerable research interest in all fields of science due to its unique properties. Its excellent mechanical properties lead it to be used in nano-composites for strength enhancement. This paper reports an Aluminum–Graphene Nanoplatelets(Al/GNPs)composite using a semi-powder method followed by hot extrusion. The effect of GNP nano-particle integration on tensile, compressive and hardness response of Al is investigated in this paper. It is demonstrated that 0.3 wt% Graphene Nanoplatelets distributed homogeneously in the matrix aluminum act as an effective reinforcing filler to prevent deformation. Compared to monolithic aluminum(in tension), Al–0.3 wt% GNPs composite exhibited higher 0.2% yield strength(+14.7%), ultimate tensile strength(+11.1%) and lower failure strain( -40.6%). Surprisingly, compared to monolithic Al(in compression), Al–0.3 wt% GNPs composite exhibited same 0.2% compressive yield strength and lower ultimate compression strength(- 7.8%),and lower failure strain(- 20.2%). The Al–0.3 wt% GNPs composite exhibited higher Vickers hardness compared to monolithic aluminum(+11.8%).Scanning electron microscopy(SEM), Energy-Dispersive X-ray Spectroscopy(EDS) and X-ray diffraction(XRD) were used to investigate the surface morphology, elemental percentage composition, and phase analysis, respectively.     

磁性超微粉的结构分析

利用广角X射线衍射技术对晶态磁性超微粒子材料进行测试,根据测定的试样衍射线方向和衍射强度数据用布拉格定律作分析处理,求得衍射晶面间距和衍射线的相对衍射强度比等参数。按照JCPDS文件检索以确定材料晶体结构。     

基于截面纤维模型的RPC箱型桥墩抗震性能分析

为探讨RPC箱型桥墩的延性抗震性能，采用截面纤维模型编制了压弯构件非线性分析程序，程序考虑了轴力的二阶效应，能模拟水平荷载不同的加载方向角，可对包括卸载过程在内的全过程受力性能进行分析.通过3个施加常轴力的RPC箱型桥墩水平反复加载试验结果与数值分析对比，验证了程序的准确性.在此基础上运用编制的程序分析了轴压比、纵筋率、截面长宽比和截面开孔率等参数在不同水平荷载加载方向时对RPC桥墩延性抗震性能的影响，得到了最不利水平加载方向与截面长宽比之间的关系.     

复杂型腔中粉末注射成形充填过程的计算机模拟

在Hele—Shaw近似下采用有限元／有限差分混合法求解粉末注射成型充填过程，有限元法处理中面离散，厚度方向使用有限差分，运用控制体积法追踪运动边界，压力方程和能量方程顺序求解，实现了复杂型腔充填过程温度场、压力场和速度场的数值仿真，得到了较有价值的流场数值分析结果。     

射流原理在微粉粒度分级中的应用

本文阐述平面射流附壁流动原理——Coanda效应,以及它被应用于微粉粒度分级操作的试验结果。分级的颗粒范围小于10μm。     

全粉料AZS砖试验的显微结构分析

研究了在各种窑炉中,不同烧成温度下,全粉料AZS砖的显微结构,提出适合于生产的最佳方案。     

弯剪共同作用下的RPC梁截面分析程序探讨

为了研究配箍率对高强箍筋活性粉末混凝土梁抗剪性能的影响,开展6根配置HRB400级箍筋RPC梁的抗剪试验,考虑RPC的材料特征参数与钢纤维对斜截面承载力的影响,分析有腹筋与无腹筋梁在剪力传递机理及裂缝控制方面的差异,基于修正压力场理论,对开裂混凝土在拉、压应力下的本构关系及裂缝处的应力平衡条件进行适当修正,将弯矩效应叠加至纯剪作用建立RPC梁在弯剪复合作用下的分析模型,并根据弯剪复合作用采用MATLAB软件编制RPC梁斜截面抗剪强度分析计算程序,对RPC简支梁进行受剪强度分析,并将试验结果与计算结果进行对比分析,研究结果表明该计算程序能够较好地预测高强钢筋RPC梁的受剪承载力,具有一定的参考和实用价值。     

Comparison of the accuracy of powder and single-crystal X-ray diffraction techniques in determining organic crystal structure

This study demonstrates the accuracy of pow- der X-ray diffraction （PXRD） in determining the crystal structures of four organic molecules by comparing the structural information obtained from both single-crystal X-ray diffraction （SXRD） and PXRD techniques. Results showed that the PXRD technique had approximately the same precision as the SXRD technique. The majority of the relative deviations from PXRD-derived lattice parameters were within 4-0.2 % of the correct values （average of the SXRD data）, whereas the relative deviations in bond lengths and angles are within 4-1,0 %, All of the relative deviations were subjected to normal statistical distributions （# = 0） and coincided with the SXRD data. As an auxiliary implement of SXRD, PXRD is clearly an effective and powerful technique in establishing an accurate character- ization of organic molecules.     

ICP—Arc粉末进样法的微机自控设计

ICP粉末直接进样法是国内外光谱学界广泛兴趣,仍悬而未决的课题。作者采用均匀少量进样及改善蒸发条件等二步来解决。然而,每完成一次样品分析的过程:有装样时振动,吹样管预降计时,载气转换,ICP炬加入电孤,进样器加高频火花放电,启动曝光快门,计时,清洗进样器,终止曝光,停止电孤,火花放电和板移等十二项操作手续。所有操作,除装样振