Study of Polyaniline/Vermiculie/Tert-fluoro Emulsion Composites Anticorrosion Coatings

1 Results Polyaniline (PANI) is one of the most promising materials for commercial applications.It can be applied to electronic devices and products such as light-emitting diodes,organic FETs,EMI shielding,secondary batteries,etc.Composites of polyaniline with other polymers or inorganic materials can provide new synergistic properties that cannot be attained from individual materials.Vermiculite (VMT) is a chain-layer magnesium-aluminum silicate mineral.We prepared composite anticorrosion coatings of p...     

钨对Ni-W-P合金镀层的结构和性能的影响

通过现代测试技术研究了化学沉积Ｎｉ－Ｗ－Ｐ合金镀层的结构、热稳定性、硬度、耐蚀性和抗冲刷腐蚀性能的影响．结果表明：Ｎｉ－Ｗ－Ｐ合金镀层的结晶状态主要由磷含量决定,但钨却使镀层形成非晶态结构所需的磷含量降低,同时钨的存在大大提高了合金镀层的热稳定性、硬度、耐蚀性和抗冲刷腐蚀性能．     

纳米结构陶瓷(n-WC/12Co)涂层材料精密磨削的试验研究

对纳米结构陶瓷(n—WC／12Co)涂层材料在金刚石砂轮精密磨削过程中的磨削力进行了较详细的试验研究，对常规结构陶瓷(c—WC／12Co)和n—WC／12Co涂层材料的磨削力作了对比磨削试验。分析了磨削工艺参数如砂轮磨削深度、工件进给速度、金刚石砂轮粘结剂类型和磨粒尺寸以及被磨试件材料特性等对磨削力的影响。结合被磨试件表面的扫描电镜(SEM)的观察，分析了n—WC／12Co涂层材料磨削的材料去除机理。     

紫外光固化水性聚氨酯-丙烯酸酯涂料研究

由甲苯二异氰酸酯、聚醚多元醇、二羟甲基丙酸、1，4-丁二醇及丙烯酸-2-羟基乙酯合成了紫外光固化聚氨酯一丙烯酸酯，产物经叔胺中和得自乳化水分散体系．考察了羧基含量、中和度、聚醚分子量、异氰酸酯指数等对乳液粒径、粘度、稳定性及漆膜的耐水性能和耐甲苯性能的影响．     

Development of Diamond-like Carbon Fibre Wheel

Introduction Diamond likecarbon(DLC)coatingshavebeen increasinglyappliedtomechanicalcomponentsandpartsduetotheirveryattractivemechanical,chemical, physical,electricalandopticalpropertiessuchashighdegreeofhardness,extremelylowfrictionalcoefficient, highwear resistance,highthermalconductivity,highmodulus,chemicalinertnessandlowdeposition temperature[1].AsshowninFig.1,DLCismadeofcarbon andhydrogenanditsstructureisamorphousorquasi amorphous,whereasdiamondandgraphitearemadeof carbonbuttheirstru…     

Damage evolution and failure mechanism of thermal barrier coatings under Vickers indentation by using acoustic emission technique

Acoustic emission(AE) technique was adopted to monitor the damage evolution of air plasma-sprayed(APS) yttria-partially-stabilized zirconia(YSZ) thermal barrier coatings(TBCs) during instrumented indentation testing, and then the failure mechanisms were investigated by cluster analysis and wavelet transform methods.The results of cluster analysis showed that there were three classes associated with distinct failure types for the 8YSZ coatings under Vickers indentation. Based on wavelet transform, these three clusters could be clearly distinguished from their dominant frequency bands, which were concentrated on levels A5(0–156.25 kHz), D5(156.25–312.5 kHz) and D4(312.5–625 kHz), respectively. Thus, the failure mechanism of 8YSZ coatings under Vickers indentation could be clarified by the distribution of different failure types in indentation depth. To sum up, as indentation load increases, the 8YSZ coatings can accommodate the indenter by elastic or little plastic deformation, microcracks propagation and then debonding at the splat boundaries. By comparing the distribution of AE signals induced by different failure types in indentation depth for samples with different thermal exposure time, it can be inferred that thermal exposure treatment can accelerate the degradation of APS 8YSZ TBCs.     

新型无卤可膨胀石墨防火涂料

以一种新型的物理膨胀型阻燃剂－可膨胀石墨为主,制取了一种无卤,环保,并具有优良防火性能的物理膨胀防火涂料,采用热重分析,小室燃烧法和模拟大板燃烧法等技术手段对化学膨胀型和物理膨胀型责两种防火涂料进行了比较分析,结果表明,与传统的化学膨胀型防火涂料相比,可膨胀石墨防火涂料在热降解,阻燃性,耐老化性,耐候性能等方面具有突出的优点。     

Ti-Ni-C系反应超音速火焰喷涂合成研究

以Ti粉、Ni粉和石墨为原料,制备了3种喷涂粉末,研究了制粒方式和粉末组成对超音速火焰合成金属陶瓷涂层组织的影响。结果表明,制粒方式在喷涂过程中对反应程度和涂层相组成起到关键的影响作用,聚乙烯醇(PVA)制粒比混合制粒更有利于喷涂过程中反应的进行,PVA制粒粉末喷涂涂层的相组成为TiC,Ni和少量Ti与Ni的氧化物,混合制粒粉末喷涂涂层中含有大量的氧化物相;超音速火焰喷涂合成过程中,粉末组分中一定量的Ti和Ni被氧化,增加Ni与C的含量对喷涂粉末的氧化有一定的抑制作用。     

陶瓷热障涂层的研究现状

对热障涂层的陶瓷层和结合层结构、等离子喷涂(APS)和电子束物理气相沉积(EB—PVD)制备工艺进行了综述，并介绍了热障涂层失效现象及其失效机理。     

纳米CaCO3改性丙烯酸涂料的研制

为了制备纳米CaCO3复合涂料，采用正交试验法研究了经不同改性剂改性制得的纳米CaCO3粉体在丙烯酸树脂中的分散工艺，制备了纳米CaCO3复合丙烯酸树脂浆液．探讨了不同纳米CaCO3和不同分散剂及其用量和丙烯酸树脂用量等因素对纳米CaCO3在丙烯酸树脂中分散性的影响，并优化出了最佳分散工艺条件：适合于在丙烯酸树脂中分散的纳米CaCO3是WO-12，丙烯酸树脂、纳米CaCO3和分散剂BYK-110质量配比为16：16．7：1．考察了纳米CaCO3复合丙烯酸浆液的贮存稳定性，并用TEM对其分散状态进行了表征．结果表明，优化条件下制得的浆液稳定性好，且纳米CaCO3在其中为纳米级分散．用该浆液制成的纳米复合涂料，与传统涂料相比其耐光性、耐水性、自洁性和贮存稳定性等显著改善．最后，用SEM对涂料进行了表征．图2，表5，参8