LaMnO3不同晶位掺杂的磁电阻效应

基于研究钙钛矿型氧化物磁电阻效应的目的,采用固相反应法制备了实验所需的单相多晶样品,主要就La位二价金属离子掺杂和稀土互掺及Mn位掺杂对LaMnO3磁电阻影响的实验结果作比较研究,发现La位稀土互掺对磁电阻的影响可以用晶格效应来解释,并明确指出La位和Mn位掺杂是提高和调制钙钛矿型锰氧化物超大磁电阻效应的一种有效途径.     

Y^3＋,La^3＋对CaSO4：Eu^2＋发光性质的影响

用沉淀法合成了掺杂Y~(3 ),La~(3 )的CaSO_4:Eu~(2 )稀土发光材料,研究了材料的晶体结构和荧光光谱,根据实验结果,所制样品基本上属正交晶系、C_(2v)空间群,Eu离子在CaSO_4中的激发峰为基态到4f~65d(E_g),(T_(2g))激发态的跃迁;样品发射主峰位于383um,属于Eu~(2 )的~5P_(7/2)→~8S_(2/7)跃迁,说明样品中Eu离子主要以Eu~(2 )的形式存在。CaSO_4:RE(La,Y)本身没有荧光,Y~(3 ),La~(3 )掺入CaSO_4:Eu中未改变基质的晶型结构,但可增强CaSO_4:Eu中Eu~(2 )的荧光强度。     

Role of doping and oxygen content in supercon—ductivity of La2CuO4＋δ

ＲｏｌｅｏｆｄｏｐｉｎｇａｎｄｏｘｙｇｅｎｃｏｎｔｅｎｔｉｎｓｕｐｅｒｃｏｎｄｕｃｔｉｖｉｔｙｏｆＬａ_２ＣｕＯ_（４＋δ）￥ＬｉＭｉｎｇ；ＨｕａｎｇＹｕｍｉｎｇ（ＳｃｈｏｏｌｏｆＣｈｅｍｉｓｔｒｙａｎｄＣｈｅｍｉｃａｌＥｎｇｉｎｅｅｒｉｎｇ，Ｓｏｕｔ...     

La对氢还原(W,Ni,Fe)复合氧化物粉末特性的影响

以喷雾干燥法制备的(W,Ni,Fe)复合氧化物粉末为原料,采用700℃、保温90 min的条件进行氢还原,研究稀土La不同含量对还原(W,Ni,Fe)复合氧化物粉末的影响;采用X射线衍射及高倍扫描电镜分别对还原后的复合粉末进行物相分析、晶粒尺寸测试和形貌观察,并对还原复合粉末的粒度、比表面进行测定与分析.研究结果表明:不加稀土La时还原粉末由W和γ-(Ni,Fe)两相组成,添加一定量的稀土La后还原粉末由W,γ-(Ni,Fe)和La(Nio75W0.25)O3三相组成;当La含量在0～0.8%范围内,随着La含量的增加,还原粉末粒度由96.6 nm降到60 nm,粉末Fsss粒度由0.64 μm降到0.36μm,粉末晶粒尺寸由26.1 nm降到22 rm未添加稀土La时还原粉末颗粒呈球形,添加一定量的稀土La,粉末颗粒呈球形或近球形;添加一定量的稀土La不仅可以有效地抑制晶粒的长大,还可以在一定程度上提高粉末的分散性.     

La掺杂对SrTiO_3纳米颗粒光催化性能的影响

采用高温固相反应法,向SrTiO_3中掺杂不同含量La制备光催化剂,通过XRD、SEM、UV-Vis等手段对其结构和形貌进行表征,并以罗丹明B(RhB)为模拟污染物,研究掺杂不同含量La所制催化剂对RhB的光催化降解能力的影响,从而评价所制催化剂的光催化性能。结果表明,随着掺La含量的增加,所制催化剂的晶体结构从SrTiO_3的立方晶系逐步向La_2Ti_2O_3的单斜晶系转变;La掺杂使得所制催化剂的禁带宽度减小、对紫外光的吸收阈值增大,使其光催化性能得到显著提升;掺La含量越高,所制催化剂的光催化性能越好。     

MgCl_2-KCl-AlF_3-(La_2O_3)熔盐体系电解制备Al-Mg-La中间合金

在质量比为41.5∶48.5∶10的MgCl_2-KCl-AlF3熔盐体系中加入质量分数为0.6%La_2O_3,利用电解法制备了Al-Mg-La合金.用ICP-OES(电感耦合等离子体光谱仪)和XRD进行了合金的组成和物相分析.研究结果表明,在电解温度800℃,阴极电流密度6.92A/cm2,槽电压5.3~5.4V,电解时间为1h的条件下,电流效率为86.2%,得到的合金主相为α-Mg基体、β-Al12Mg17相与Al11La3相.高的阴极电流密度有利于合金中镁含量的增加.     

Effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of La1−xMgxNi3.5 (x=0.20, 0.23, 0.25 at%) alloys

The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry.     

A new species of Notostrix (Acari: Eriophyidae), with notes on the host plants and distribution of species of this genus

Thirteen Notostrix Keifer species are presently known, all from leaves of palm trees (Arecaceae) to which they seemingly cause no major damage. A new species of this genus, Notostrix macrothrix sp. nov., is morphologically described based on adult females and males collected from coconut, Cocos nucifera L. (Arecaceae), on La Reunión Island. A discussion about the presently known distribution of mites of this genus is also presented. http://www.zoobank.org/urn:lsid:zoobank.org:pub:14C65CB2-AF56-4D85-AD49-56FA11119EF5     

三元配合物La(Et2 dtc)3(phen)的热化学性质

目的研究三元配合物La(Et2dtc)3(phen)的热化学性质.方法采用了微量热法和燃烧法.结果铜试剂(NaEt2dtc·3H2O)和邻菲咯啉(phen·H2O)与水合氯化镧(LaCl3·3.94H2O)在无水乙醇中反应,制得三元固态配合物La(Et2dtc)3(phen).在298.15 K下测得了该配合物的液相生成反应的焓变△rHθm(l),为(-8.801±0.043)kJ/mol,计算了固相生成反应的焓变△rHθm(s),为(70.428±0.293)kJ/mol;配合物的恒容燃烧能△cU为(-17 455.98±7.98)kJ/mol,其标准燃烧焓△cHθm和标准生成焓△fHθm经计算分别为(-17 475.19±7.98)kJ/mol,(-1 257.78±8.84)kJ/mol.结论IR光谱表明该配合物中La3+与3个NaEt2dtc中的6个硫原子双齿配位,同时与邻菲咯啉中的2个氮原子双齿配位,配位数为8.     

Research at channel level on the effect of LaCl3 on Radish (Raphanus satirus L.) vacuolar membrane

We recorded slow vacuolar (SV-type) channel currents of Radish vacuoles successfully for the first time by using the whole-vacuolar patch-clamp recording mode. SVtrye currents would increase and threshold potentials of activation would shift towards more negative values with the increase of concentrations of cytosolic Ca2+. When 2.5 mmol/L LaCl3 and 4 mmol/L EGTA were added to bath solutions,SV-type currents were suppressed remarkably. Then adding LaCl3 with different concentrations to pipette solutions, we found that LaCl3 with higher concentrations (＞ 4 × 10-7 mol/L)had a strong inhibitory effect on SV-type currents, while LaCl3 with lower concentrations (≤4 × 10-7 mol/L) promoted channel currents. This promoting effect provides an important basis at channel level for researching further the effects of rare earth on physiological activities of plants and the production-increase effects of rare earth fertilizers on crops.``