滇西小龙潭矿区始新世岩浆岩的成因及其地质意义

云南省宾川县小龙潭矿区是一个大型斑岩型铜多金属矿床,铜矿体主要产于斑岩体及其外围接触带,矿化与斑岩体密切相关。对矿区主要侵入岩开展全岩地球化学、锆石LA-ICPMS U-Pb年代学和Hf同位素研究,获得含矿二长斑岩的~(206)Pb/~(238)U加权平均年龄为(35.98±0.16)Ma,属于始新世岩浆活动的产物。斑岩体SiO_2质量分数变化较大(64.81%~69.6%),高钾(4.36%~10.95%)和碱(Na_2O+K_2O8%),A/CNK为0.99~1.36,属高钾的碱性—过碱性、准铝质—过铝质斑岩;富集大离子亲石元素(K、Rb、Ba、Sr等)、亏损高场强元素(Ta、Nb、P、Ti等),富集轻稀土元素、亏损重稀土元素;虽被划入富碱侵入岩及A型花岗岩,但具C型埃达克岩地球化学特征。斑岩体锆石ε_(Hf)(t)值为-26.93~1.66,地壳模式年龄为1 009~4141 Ma,显示斑岩体来源于下地壳物质的部分熔融,并有幔源物质的加入。结合区域演化特征,认为小龙潭斑岩体形成于造山期后的拉张环境,陆陆碰撞挤压后应力松弛,岩浆沿断裂及次级断裂上侵,进而形成铜多金属矿床。     

<Emphasis Type="Italic">In situ</Emphasis> boron isotope measurements of natural geological materials by LA-MC-ICP-MS

There are two main methods to determine boron isotopic composition. One is the solution method, in which boron is purified after the samples are dissolved in solution and the boron isotope ratios are determined by thermal ionization mass spectrometry (P-TIMS and N-TIMS) or multicollector inductively coupled plasma mass spectrometry (MC-ICP-MS). The other is an in-situ analysis method, in which the in-situ boron isotopic ratios in minerals are analyzed directly using secondary ion mass spectrometry (SIMS) or laser ablation multicollector inductively coupled plasma mass spectrometry (LA-MC-ICP-MS). In the in-situ analysis method for boron isotopes, the multifarious chemical purification and separation processes of the solution method are avoided, with increased work efficiency. In addition, the microzones and microbeddings of minerals can be analyzed in-situ to reveal the fine processes and conditions of mineral formation. In this study, using the standard-sample-bracketing (SSB) method, mass bias of the instrument and the fractionation of isotopes were calibrated, and the in-situ determination method of LA-MC-ICP-MS for boron isotopes was established. Through detailed analyses on a series of boron isotope standards and samples, a matrix effect was assessed but not detected, and the analysis results were in accordance with the formerly reported values or P-TIMS determined values, within the error range. The analytical results for IAEA B4 and IMR RB1 with relatively high boron contents were δ¹¹B = –(8.36±0.58)‰ (2σ, n=50) and δ¹¹B = –(12.96±0.97)‰ (2σ, n=57), respectively; the analytical result for IAEA B6 with relatively low boron content was δ¹¹B = –(3.29±1.12)‰ (2σ, n=35). In-situ measurements for B isotopes were performed on geological samples such as tourmaline, ulexite, ludwigite, inyoite and ascharite, with the results consistent with those determined by P-TIMS, within the error range.     

山间盆地砂岩型铀矿成矿物质来源研究——以吐哈盆地和二连盆地为例

通过野外观察、镜下鉴定和锆石测年分析,研究吐哈盆地和二连盆地砂岩型铀矿的成矿物质来源。研究结果表明,吐哈盆地目的层锆石年龄主要集中在(440.9±2.3)Ma,其物源应为加里东期片麻状花岗岩侵入体,铀源主要来自于预富集。二连盆地物源主要来源于古河道上游和两侧岩体,铀源主要以岩体铀的风化淋滤为主,地层中火山碎屑岩也为铀的富集提供了补充。并在此基础上分析了山间盆地铀源条件对铀成矿的控制与影响。