冀东金矿集中区控矿条件探讨

论述了冀东金矿集中区绿岩型金矿的矿质来源，并恢复其矿源层的原岩。对构造及中小型岩浆任入体的控矿作用作了论述，并提出了成矿模式。     

m序列优选对及平衡Gold序列的产生与搜索

扩频通信系统需要相关性好的扩频码，因此，在分析m序列优选对，平衡Gold序列的产生方法和相关特性基础上，提出了一种采用C语言搜索m优选对和平衡Gold序列的计算机实现方法，给出了搜索程序流程图．该方法可以正确、快速地完成平衡Glod码的搜索，对扩频码的优选具有参考价值．     

Optical sensing of explosives in wastewater by competitive complexation

A facile strategy for optical sensing of explosives with the assistance of 1,3,5-Triazine-2,4,6-triamine(MEL) in aqueous solution is proposed. Upon exposure to MEL, the electron-sufficient amino group in MEL was prone to form complexes with electron-deficient nitro group in explosives. The interaction could be tuned by the amount of MEL to fully consumed nitro-contained explosives dissolved in wastewater, thus prevented the gold nanoparticles(GNPs) from combining with MEL. In comparison with common detection method, the dose-response curve procedure reported here was in good linear relationship from 0 μM to 80 μM with good correlation factor(R~2= 0.9871), and was satisfactorily agreed with the proposed theoretical model. The detection limit(Lo D) was1.1 μM by spectrometer, 3.0 μM visualized by naked eyes and 21.3 nM by calculation. The procedure described in this study could be finished within a few minutes and showed its effectiveness in explosive detection upright on the gold surface in real wastewater, making this proposed method a powerful tool in several sensing platforms.     

An effective amperometric biosensor based on graphene modified gold nanowire arrays for glucose detection

A novel glucose biosensor based on graphene nanosheets （GNs） modified gold nanowire arrays （AuN- WAs） electrode was constructed. Highly ordered gold nanowire arrays were prepared by direct electrodeposition in anodic aluminum oxide templates. GNs were synthe- sized through a public route involving graphite oxidation, exfoliation, and chemical reduction. Field emission scan- ning electron microscope and high-resolution transmission electron microscope were employed to characterize the as- prepared AuNWAs and GNs. Glucose oxidase was immobilized on the surface of GNs-AuNWAs modified electrode via a cross-linking method. The cyclic voltam- metry results showed that the GNs-AuNWAs-based glu- cose biosensors have high catalysis activity to hydrogen peroxide （H2O2） than those modified with GNs or AuN- WAs only. Furthermore, amperometric response was employed to detect glucose concentration owing to its simplicity, high selectivity, and relative low cost. Glucose biosensors based on GNs-AuNWAs showed excellent performance with high sen- sitivity of 40.25 μA cm^-2 （mmol/L）^-1, low detection limit of 0.02 mmol/L, and a linear range from 0.02 to 3 mmol/L.     

Alternative synthetic route for the heterometallic CO-releasing [Sb@Rh12(CO)27]3− icosahedral carbonyl cluster and synthesis of its new unsaturated [Sb@Rh12(CO)24]4− and dimeric [{Sb@Rh12Sb(CO)25}2Rh(CO)2PPh3]7− derivatives

The evolution of the optical absorption spectrum of bimetallic Ag-Au monolayer-protected clusters (MPC) obtained by progressively doping Ag into the experimentally known structure of Au133(SR)52 was predicted via rigorous time-dependent density-functional theory (TDDFT) calculations. In addition to monometallic Au133(SR)52 and Ag133(SR)52 species, 5 different (Ag-Au)133(SR)52 homotops were considered with varying Ag content and site positioning, and their electronic structure and optical response were analyzed in terms of Projected Density Of States (PDOS), the induced or transition electron density, and Transition Component Maps (TCM) at selected excitation energies. It was found that Ag doping led to the effects rather different from those encountered in bare metal clusters. And it was also observed that Ag doping could produce structured spectral features, especially in the 3–4 eV range but also in the optical region if Ag atoms were located in the sub-staple region, as rationalized by the accompanying electronic analysis. Additionally, Au doping into the staples of Ag-rich MPC also gave rise to a more homogeneous induced electron density. These findings show the great sensitivity of the electronic response of MPC nanoalloy systems to the exact location of the alloying sites.     

齐齐哈尔碾子山金长城侵蚀沟治理工程设计概论

本文作者紧密结合本地实际和通过多年来水利建筑工程具体实践取得的工作经验、体会和感受，阐述了实施碾子山金长城侵蚀沟治理工程的必要性，并对其工程设计做了简要概述，有针对性地提出了工程管理综合措施，对当前开展的“建生态市、创园林城”活动与和谐水利建设有一定借鉴和指导意义。     

流动注射在线聚氨酯柱富集火焰原子吸收法测定矿样中的痕量金

本文用聚氨酯泡沫塑料作为柱材料，研究制定了在线预富集流动注射火焰原子吸收测定痕量金的新方法．实验溶液含金０．０２μｇ／ｍｌ，酸度为５％～１０％王水，以甲基异丁酮为洗脱液．当流速为１６ｍｌ／ｍｉｎ时，富集倍数为进样１ｍｉｎ富集５０倍．该方法选择性好，用于地质矿样中痕量金的测定，相对误差为１．１％．     

Gold序列相关特性分析的某些新结果

扼要地介绍了Ｇｏｌｄ序列的产生及相关特性，提出了一种简单地求找相关函数方法；并从不同角度对典型的Ｇｏｌｄ序列的抗干扰容限进行了较为详细的讨论。     

公婆泉铜矿岛弧型含矿斑岩地质地球化学特征

目前发现的斑岩型铜矿的含矿斑岩均产于陆相环境，公婆泉铜矿斑岩是目前为止发现的惟一产于海相环境的含矿斑岩，围岩沉积环境，岩石化学和地球化学研究表明，含矿次英安斑岩和花岗闪长斑岩产于海相环境，形成于水下500－1000m，是中一晚志留纪哈萨克斯坦板块向（南）塔里木－中朝板块俯促时公婆泉－东七一山岛弧岩浆晚期分异的产物。     

金的主要脉体矿物——石英的研究

石英脉金,是岩金的一个重要类型.金的富集与石英的形成与演化有着直接或间接的联系.因此,笔者以小秦岭金矿的各种类型石英为例,讨论了它们的一系列矿物学特征,为金矿的评价及成因的研究提供了一定的有用信息.