BaTiO_3薄膜的制备及特性研究

本文以Ba(CH_3COO)_2和Ti(OC_4H_9)_4为原料,以CH_3COOH为催化剂,用溶胶-凝胶方法制备BaTiO0_3薄膜;用红外光谱研究原料水解与聚合形成BaTiO_3的机理;用Χ射线光谱研究薄膜结构,并研究工艺条件与电性能的关系。得到剩余极化强度为6.04μC/cm~2的铁电膜。     

Induced modi fi cations in the properties of Sr doped BiFeO3 multiferr oics

Multiferroics exhibit unique combination of ferroic properties,simultaneously.For instance,in BiFeO3,magnetic and electric properties co-exist.In this work,BiFeO3 and Sr-doped BiFeO3 samples with general formula,Bi1-x Srx FeO3(x=0.00,0.05,0.10,0.20,and 0.30) were synthesized by sol-gel auto-combustion technique,in order to investigate these ferroic properties.The samples were confrmed to have perovskite type rhombohedral structure,characteristic of BiFeO3.A dilute phase of Bi2Fe4O9was also found in all the Sr-doped samples.The micrographs of the palletized samples revealed that minutely doped Sr might not have any effect on the morphology of the samples.Frequency dependent dielectric measurements were carried out at room temperature for all the samples from 100 Hz to 1 MHz.The dielectric constant of un-doped sample at low frequency was 52 which decreased with increasing Sr doping.An enhancement of magnetic properties was observed with increasing the Sr contents.Pure BiFeO3 material was observed to have the least value of remanent magnetization.As the Sr2+ tions were doped in BiFeO3,its magnetization and remanence were increased to 0.867 emu/g and 0.175 emu/g,respectively,at x=0.30.