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本文利用纳米固体超强酸SO4^2-/ZnO催化合成乙酸异戊酯的最佳反应条件,既反应时间2.0h,催化剂用量为酸质量的1.0%,酸醇比为1∶2,验证实验产率为96.7%,且该实验反应时间短,无腐蚀无污染,催化剂可回收可重复利用. 相似文献
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应用聚丙烯酰胺凝胶电泳法研究了西藏黄牛的Am和Es同工酶,得出了其基因频率和基因型频率.结果表明,西藏黄牛的Am和Es两个同工酶位点的基因分布及其频率与瘤牛种(Bosindicus)差异较大,而与普通牛种(Bostaurus)较为一致,这进一步从同工酶位点上验证了我们对西藏黄牛的Y染色体特征和血液蛋白多态性的研究结果 相似文献
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HUANG Zhiqun XU Zhihong BOYD Sue WILLIAMS David 《科学通报(英文版)》2005,50(22):2581-2586
Decomposition of stumps in successive rotation of Chinese fir (Cunninghamia lanceolata (Lamb.) Hook.) plantations was studied using a chronosequenee approach. The results showed that decomposition rate constant of Chinese fir stump was 0.02695 as calculated from Olson's model. The N content of stump increased during the first two-year decomposition. When the dead stump C/N ratio was 463.2 ± 27.3, the stumps started to release N. The pattern of P release was similar to that for N. However, K content of stumps showed a consistent declining trend over time during the whole decomposition. ^13C nuclear magnetic resonance spectroscopy with cross polarization and magic-angle spinning (^13C CPMAS-NMR) was used to analyse organic carbon (C) components in decomposing stumps. The ^13C CPMAS-NMR spectra of stumps displayed that stump was dominated by cellulose and hemieellulose. The spectra also showed the accumulation of intensity in alkyl C, aromatic C, and earboxyl C spectral regions, which was expected as the labile cellulose and hemieellulose components in O-alkyl C spectral region were selectively decomposed first. 相似文献
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采用构造性方法证明了蕴含Ar+1^(m)-可图序列刻划定理. 相似文献
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Based on the mass distribution data up to 200 MeV measured by Zoner with kinetic energy method (corrected), the systematics on dependence of chain yield on incident neutron energy for each mass number A with a linear and quadric function was studied. And also the systematics of mass distribution on mass A and incident neutron energy was investigated by using 5 (or 3 ) Gaussian model. A code of nonlinear squared least method was developed and the parameters were deduced by fitting the experimental data. The calculated results with the parameters obtained could reproduce the experimental data used well. But comparisons with the data measured by radiochemistry method show some systematical difference. It is shown that there is some systematical difference between the measured data with kinetic and radioactive nuclide methods, the masons of which need to be investigate further. 相似文献
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固体超强酸具有较高的反应活性和较好的选择性.文章研究了玫瑰茄油在固体超强酸催化下合成高级脂肪酸脂.再采用GC—MS对其中的脂肪酸进行了定性和定量分析.玫瑰茄油中各种脂肪酸的质量分数分别为棕榈酸18%;硬脂酸30%;油酸38%;亚油酸14%。 相似文献
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以硝酸锆为锆源,以阴离子表面活性剂十二烷基硫酸钠(SDS)为模板剂,S2O8^2-浸渍无定形Zr(OH)4,制得介孔S2O8^2-/ZrO2固体超强酸,通过N2吸附-脱附、XRD分析、Hammett非水滴定、TEM等方法,考察了不同焙烧温度对S2O8^2-/ZrO2介孔超强酸晶体结构、酸强度等性能的影响。结果表明,当焙烧温度600℃,S2O8^2-/ZrO2样品比表面积为140m2/g,平均孔径在3~4nm之间,酸强度H0≤-12.7,为介孔相固体超强酸。 相似文献
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利用低温方法制备了S2O82-/TiO2固体超强酸催化剂,研究了该催化剂在乙酸和异戊醇酯化反应中的催化活性和稳定性.观察了焙烧温度、(NH4)2S2O8溶液浸渍浓度对催化剂催化性能的影响,以及催化剂用量、醇酸比、反应时间、反应温度等因素对酯化率的影响.结果表明:在450~500℃焙烧和用1.00mol/L的(NH4)2S2O8浸渍所得的S2O82-/TiO2对酯化反应具有良好的催化活性,反应的最佳醇酸摩尔比为1.2:1,催化剂用量为反应物料总量的1.0%,反应时间1.5h,反应温度110~120℃,酯化率可达95%. 相似文献
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朱先阳 《井冈山大学学报(自然科学版)》2010,(1):11-13
利用几何逼近的方法证明了一个凸体的L2投影体是一个以原点为中心的椭球,研究了投影不等式Petty猜想的L2形式的逆形式,建立了L2投影体与标准化下的经典投影体之间的包含和反包含关系,及解答了一个约束最小化问题。 相似文献