纳米固体超强酸SO42-/ZnO催化合成乙酸异戊酯的研究

本文利用纳米固体超强酸SO4^2-/ZnO催化合成乙酸异戊酯的最佳反应条件,既反应时间2.0h,催化剂用量为酸质量的1.0%,酸醇比为1∶2,验证实验产率为96.7%,且该实验反应时间短,无腐蚀无污染,催化剂可回收可重复利用.     

浙西,皖南石煤及其建材制品中的放射性元素对人体的影响

在石煤资源丰富的浙西、皖南地区测试结果表明,部分石煤渣砖含有的铀等放射性辐射强度,已超过了非职业辐射工作人员的容许值。部分石煤渣砖和水泥中的当量镭比活度和有效镭浓度也超过了国家对非职业辐射工作人员的安全限量,因此应对石煤建材制品的生产和应用持慎重态度。铀等放射性元素在石煤层中仅是局部富集,含量高的石煤层限于个别地段。因而,对辐射强度大、放射性核素含量高的个别富集地段应放弃开采。同时,对生产工人要按国家有关辐射防护条例,采取有效防范和劳保措施。     

Chemical composition of decomposing stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations

Decomposition of stumps in successive rotation of Chinese fir （Cunninghamia lanceolata （Lamb.） Hook.） plantations was studied using a chronosequenee approach. The results showed that decomposition rate constant of Chinese fir stump was 0.02695 as calculated from Olson＇s model. The N content of stump increased during the first two-year decomposition. When the dead stump C/N ratio was 463.2 ± 27.3, the stumps started to release N. The pattern of P release was similar to that for N. However, K content of stumps showed a consistent declining trend over time during the whole decomposition. ^13C nuclear magnetic resonance spectroscopy with cross polarization and magic-angle spinning （^13C CPMAS-NMR） was used to analyse organic carbon （C） components in decomposing stumps. The ^13C CPMAS-NMR spectra of stumps displayed that stump was dominated by cellulose and hemieellulose. The spectra also showed the accumulation of intensity in alkyl C, aromatic C, and earboxyl C spectral regions, which was expected as the labile cellulose and hemieellulose components in O-alkyl C spectral region were selectively decomposed first.     

由新型TOP224Y构成12V／40W开关电源

单片开关电源正显示出强大的生命力,并以其优良的性能倍受人们青睐．中阐述了利用被人们誉为“顶级开关电源”的反激式单片开关电源芯片TOP224Y构成12V、40W的开关电源电路设计。     

^226Ra evidence for the ecosystem shift over the past 40 years in the North Pacific Subtropical Gyre

Surface seawater was collected for ~(226)Ra measurement in the North Pacific Subtropical Gyre from July to October, 1999 and October to December, 2003. Combined with the historical data reported for this sea area, a declined trend of surface ~(226)Ra concentrations was observed since 1960s, indicating the ecosystem shift in response to global warming. On one side, the enhanced stratification of the upper water column resulting from global warming reduced the ~(226)Ra input from the depth, on the other, the temporal increase of biological production resulting from the climate-related ecosystem structure change strengthened the ~(226)Ra removal from the surface ocean. Both the physical and biological processes resulted in the decrease of surface ~(226)Ra concentrations in the North Pacific Subtropical Gyre. The temporal trend of surface ~(226)Ra concentrations was consistent with the trends of chlorophyll a, silicate, phosphate and primary production previously reported. This study provided ~(226)Ra evidence for the ecosystem shift under global change.     

On the Hejek-Renyi Inequality

In this paper we give an elementary and unified proof of the Hajek-Renyi inequality, and get a general version of this inequality which not only covers the all known results but also derives some new results.     

蕴含Ar＋1^（m）-可图序列刻划定理的一个构造性证明

采用构造性方法证明了蕴含Ar＋1^（m）-可图序列刻划定理．     

Fission Yield Data Systematics for ^238U

Based on the mass distribution data up to 200 MeV measured by Zoner with kinetic energy method （corrected）, the systematics on dependence of chain yield on incident neutron energy for each mass number A with a linear and quadric function was studied. And also the systematics of mass distribution on mass A and incident neutron energy was investigated by using 5 （or 3 ） Gaussian model. A code of nonlinear squared least method was developed and the parameters were deduced by fitting the experimental data. The calculated results with the parameters obtained could reproduce the experimental data used well. But comparisons with the data measured by radiochemistry method show some systematical difference. It is shown that there is some systematical difference between the measured data with kinetic and radioactive nuclide methods, the masons of which need to be investigate further.     

超强酸催化有机酸衍生化分离分析研究

固体超强酸具有较高的反应活性和较好的选择性．文章研究了玫瑰茄油在固体超强酸催化下合成高级脂肪酸脂．再采用GC—MS对其中的脂肪酸进行了定性和定量分析．玫瑰茄油中各种脂肪酸的质量分数分别为棕榈酸18%；硬脂酸30%；油酸38%；亚油酸14%。     

焙烧温度对S2O8^2-／ZrO2介孔超强酸的结构与性能的影响

以硝酸锆为锆源,以阴离子表面活性剂十二烷基硫酸钠（SDS）为模板剂,S2O8^2-浸渍无定形Zr（OH）4,制得介孔S2O8^2-／ZrO2固体超强酸,通过N2吸附－脱附、XRD分析、Hammett非水滴定、TEM等方法,考察了不同焙烧温度对S2O8^2-／ZrO2介孔超强酸晶体结构、酸强度等性能的影响。结果表明,当焙烧温度600℃,S2O8^2-／ZrO2样品比表面积为140m2／g,平均孔径在3～4nm之间,酸强度H0≤-12．7,为介孔相固体超强酸。