FeCo-based hybrid MOF derived active species for effective oxygen evolution

Metal-organic frameworks(MOFs) have been regarded as promising catalyst materials due to the richness of coordinately unsaturated metal sites on the surface,which can act as catalytic active centres.In this study,a hybrid MOF material composed of Fe-based MOF and Co-based MOF was prepared with the involvement of graphene oxide nanosheets as additive.It was demonstrated that the hybrid MOF materials showed much higher electro-catalytic activity towards oxygen evolution than the single-phase counterparts.To drive current density of 10 mA cm~(-2),the hybrid CoFe-based MOF only needed an over potential of 290 mV in 1 M KOH.The catalytic activity could sustain for a longer time with only slight current density decrease.During oxygen evolution operation,the MOF catalyst evolved into catalytic active species but kept well the microscale sheet-like structure.It is thus believed that this study will provide an avenue for the development of advanced electrocatalysts.     

工业用PET及PA纤维模量-应变曲线的分析

通过拉伸试验数据得到应力—应变曲线和模量-应变曲线可以更全面地反映纤维的力学性能。PET及PA的模量—应变曲线都是明显的双峰曲线。结合拉伸过程中PET纤维内部结构的变化解释PET纤维的特征模量—应变曲线，并讨论如何提高持续使用应变范围的模量问题。PET模量—应变曲线上的第一个模量峰为初始模量，标志着无定形区缠结网的破坏；无定形区蜷曲大分子伸直时模量较低，导致出现模量低谷；由于伸直的缚结大分子模量较高，出现了第二个模量峰。     

自主机器人人工进化方法研究

在介绍人工进化研究状况的基础上 ,着重阐述了进化机器人学的关键问题 :基本概念、进化技术、进化计算和实验研究方法等 ,探索了进化机器人学未来的研究趋势及所面临的挑战 .     

线粒体蛋白组研究进展

线粒体蛋白组是指在线粒体中出现的所有蛋白质的集合,包括线粒体自身基因组编码的和 由核基因组编码的蛋白质.线粒体作为真核生物的重要细胞器,它参与去除氧化、产生能量和还原 性物质等等一些重要的生命活动过程.这些功能都依赖于线粒体蛋白组中的蛋白河的相互作用.要 对其有一个较为全面的认识,就必须对其蛋白组进行广泛且深入的研究.根据现有的一些研究成 果,对线粒体蛋白组在起源与进化、跨膜运输、研究方法和计算机预测作了简要综述.     

带电胶体系统固液相变的分子动力学研究

在修正Yukawa相互作用的基础上，采用常温分子动力学方法数值研究了带电胶体系统的大离子屏蔽效应和多分散性效应对其固液边界的影响．研究结果发现，在屏蔽长度较大时，固液相变曲线出现了明显偏差．初步定性认为这种相边界偏差现象来自于系统多体效应的增强．另外，数值研究了固液相变时键接取向序参数的变化．     

Banach空间中一类强非线性发展方程的反周期解

本文讨论一类强非线性发展方程的反周期解的存在性。针对一大类既含有单调非线性算子又含有非单调非线性算子的发展方程。我们巧妙地结合单调算子理论与Leray-Schauder不动点理论，证明了其反周期解的存在性。最后，举例说明理论结果在2m阶拟线性抛物型方向的时间反周期问题中的应用。     

High precision topographic data on Lop Nor basin's Lake "Great Ear" ? and the timing of its becoming a dry salt lake

High precision elevation measurements using DGPS were carried out along three representative tran- sects for the "Great Ear" area, a dry salt lake within the Lop Nor basin. Results indicate that the Lop Nor basin is only 5.2 m deep and its lowest point occurs at the center of the "Great Ear". In addition, the basin is asymmetric - steeper in the southwest (0.19‰) and gentler in the northeast (0.09‰). Points along the same "Great Ear" ring were found to have an identical elevation value, but different when from different ones (lower towards the center). The spacing of the "Great Ear" rings was found to be closely related with the surface steepness. The closer the "Great Ear" rings are spaced, the steeper the ground surface, and vice versa. These findings support the argument that the "Great Ear" rings are the former shoreline trails left behind by Lop Nor water during the last few episodes of recession towards its total dry up. A comprehensive analysis of the high precision elevation data, historical accounts, aerial and satellite photographs and imagery, and official topographic maps of the study area suggests that the "Great Ear" area in the Lop Nor basin was incorrectly mapped as being covered by a great body of water on the 1963 topographic maps. A re-interpretation of the 1958 aerial photographs and newer remote sensing imagery indicated that the "Great Ear" ring structure was already in place in 1958 and it continued to appear on the subsequent remote sensing data without any major changes. It is estimated that lake water in the "Great Ear" area of the Lop Nor basin disappeared between the late 1930s and early 1940s.     

多维函数全局寻优的团队进步算法

通过模仿团队进步需要的学习、探索行为和成员更新规则,提出了一种新颖的双群体演化算法,称为团队进步算法(TPA).算法将一个团队的成员分为精英和普通组,建立了两组的学习样板,定义了学习和探索运算,并合理设定了成员更新规则.两组成员在搜索过程中出现了明显分工,使算法兼备了全局搜索、局部搜索和定向搜索的能力.数值试验结果验证了新算法具有实现简单、全局寻优成功率高、收敛快、计算量少、坚韧性强和参数选择相对容易等特性,对解决优化应用问题具有较大的价值.     

绿洲-荒漠生态系统演化因素及其非线性探讨——以新疆为例

对立统一于干旱区的绿洲—荒漠生态系统在降水等自然因素和人类活动等人为因素的影响下不断进行着演化.从长期看,这一演化过程具有不可预测性,短期内却有细微可预见性.现如今在绿洲扩展同时,荒漠也在扩展,整体趋势仍是荒漠在扩展.为维持绿洲的稳定性,促使绿洲—荒漠系统处于一种稳定的发展趋势,本文从分析绿洲-荒漠这对对立统一的生态系统入手,在探讨引起这对生态系统演化的自然因素和人为因素的基础上,确定了自然因素中的降水和人为因素中的政府调控行为为演化的主导因素,初步探索了促使这对生态系统统演化的主导因素作用所具有的非线性关系,这对维持绿洲的稳定性,抑制荒漠扩展有一定的实际意义.