Effects of Si and Ce on the microstructure and hydrogen storage property of Ti_(26.5)Cr_(20)V_(45)Fe_(8.5)Ce_(0.5) alloy

In this paper,the effects of Si and Ce on the microstructure and hydrogen storage property of Ti26.5 Cr20V45Fe8.5Ce0.5 alloy were studied,respectively.First of all,effects of Si on the microstructure and hydrogen storage properties of Ti26.5Cr20(V45Fe8.5)1-xSixCe0.5(x=0,0.5,1.0,1.5 and 2.0 at%)alloys were studied by X-ray diffraction,scanning electron microscopy and P-C isotherm measurements.As the Si addition increases,the hydrogen absorption capacities of alloys decrease but the equilibrium pressure incre...     

Thermal detection of surface plasmons on gold nanohole arrays

We used a thin-film thermocouple to detect the thermal effect of surface plasmons excited in Au nanohole array structures.We found that the thermal electromotive force of Au film with periodic nanohole structures is three times greater than that of a bare Au film for 785-nm laser excitation at a given power.This effect is caused by the resonant excitation of localized surface plas- mons in the nanoholes.In addition,we found that the thermal electromotive force(EMF)of the Au film with dumbbell-like na- nohole arrays depends strongly on the incident polarization.The thermal EMF is the greatest when the excitation light is polarized perpendicular to the long axis of the dumbbell.     

Remobilization of heavy metals during the resuspension of Liangshui River sediments using an annular flume

The release and transport of heavy metals(Ni,Cr,Cu and Pb) from Liangshui River sediments into the overlying water column during the resuspension event were determined using an annular flume with a velocity ranging from 0.15 to 0.35 m/s.It is shown that the suspended particulate matters(SPM) increased as much as nearly 25 times from 165 to 4220 mg/L as the velocity increased.Heavy metals showed an increase in dissolved phase as the velocity increased due to their desorption from the SPM.Acid-soluble heavy metals increased as the velocity increased,indicating that part of the heavy metals transformed from stable phase to labile phase during resuspension.Heavy metal concentrations in the SPM on volume normalization increased by approximately 2-6 times.However,on the mass weighted basis they decreased,approaching the bulk-sediment contents at high velocity,due to the "particle concentration effect".The distribution coefficients(K D) of heavy metals were higher at slower velocity during the sediment resuspension,which could be attributed to the decrease of fine particles(silt/clay fraction) during resuspension.     

变形液滴的反常形态演变

利用高速摄影技术研究了压扁液滴自由落体过程中的形态演变.实验中利用表面活性剂十二烷基硫酸钠(SDS)对液滴性质进行调控.实验发现,液滴的形态演变显著依赖于SDS浓度.有趣的是,SDS浓度为0.8 cmc时,液滴可较长时间保持压扁形态而不回复成球形.经受力分析,界面的Gibbs弹性不足以完全抵消Laplace压差所产生回复力.声场作用下产生的宏观表面浓度梯度导致强烈的Marangoni效应,赋予界面以额外弹性,从而与液滴回复力相抗衡.     

Effects of carbon diffusing field in alloy solvent on the growth of tower-shape diamond single crystal

High-quality type-Ib tower-shape diamond single crystals were synthesized in cubic anvil high pressure apparatus (SPD-6×1200) at 5.4 GPa and 1250-1450°C. The (100) face of seed crystal was used as the growth face, and FeNiMnCo alloy was used as the solvent/catalyst. Two kinds of carbon diffusing fields (type-B and type-G) were simulated by finite element method (FEM). Using the two kinds of carbon diffusing fields, many diamond single crystals were synthesized. The effects of carbon diffusing fields on the ...     

Effect of additive boron on type-Ib gem diamond single crystals synthesized under HPHT

The boron-doped type-Ib gem diamond crystals were synthesized successfully by adding amorphous boron into a system of graphite and Kovar catalyst under high pressure and high temperature (HPHT).The effect of additive boron on type-Ib gem diamond was extensively studied including the growth characteristic,morphology and nitrogen concentration.The synthesized boron-doped type-Ib gem diamond crystals were characterized by optical microscope (OM),scanning electron microscope (SEM) and infrared spectrometer (IR)...     

Electromagnetic behavior of two-dimensional quasi-crystal left-handed materials with dendritic unit

We demonstrated a two-dimensional quasi-crystal dendritic structure model with negative permeability. The microwave transmission and reflection properties of periodic and quasi-crystal dendritic structure mediums with varied angle incidence were measured. The results showed that the resonant peaks of quasi-crystal negative permeability samples and left-handed samples had tiny shift with the altering of incident angle. Because of the influence of coupling between quasi-crystal dendritic cells, the resonance of the entire material was enhanced or weakened. The quasi-crystal dendritic structure model will provide an easy method to design isotropic left-handed materials （LHMs）.     

模糊聚类土地分等定级方法之数据处理及算法研究

文章讨论模糊聚类土地分等定级中出现的数据处理及算法问题，列出主要的计算公式及计算机程序清单，有重要的推广应用价值。     

Dechlorination of 2,4-dichlorophenol by nickel nanoparticles under the acidic conditions

Metal nanoparticles are effective for remediation of contamination with a range of compounds including chlorinated organics.However,the sorption process of the passivation oxide layers on the metal nanoparticle surfaces may result in incomplete degradation of contaminants.This phenomenon can be prevented by an acidic washing procedure or reaction in an acidic medium.In this paper,nickel nanoparticles manufactured via the carbonyl powder process were analyzed using scanning electron microscopy,transmission electron microscopy,X-ray diffraction and energy-dispersive X-ray spectroscopy.The sorption and degradation of 2,4-dichlorophenol (2,4-DCP) by nickel nanoparticles under acidic conditions was then investigated.Transmission electron microscopy and XRD results showed that the nickel nanoparticles range in size from 10 to 20 nm,and a thin passivation layer of NiO is present on the surface.This oxide layer can be removed by pretreatment washing with acidic solutions.It was indicated that dechlorination was the key reaction pathway for degradation of 2,4-DCP by nickel nanoparticles under acidic conditions.The main degradation products were 4-Chlorophenol,2-Chlorophenol,and Phenol,and among these,Phenol was dominant.The acidic medium promoted degradation by providing an appropriate pH,and H+ may be involved in the reaction.Dechlorination of 2,4-DCP by nickel nanoparticles under the acidic condition follows the second order kinetic model,and the rate constants at 298,306,316 K are 0.02,0.2 and 0.3 (g L h)-1,respectively.     

Study on high efficient electric discharge milling of silicon carbide ceramic with high resistivity

A new method which employs a group pulse power supply for electric discharge milling of the silicon carbide ceramic with the resistivity of 500 Ω·cm is presented. Due to the good machining stability and high pulse utilization, the material removal rate （MRR） can reach 72.9 mm^3/min. The effects of high-frequency pulse duration, high-frequency pulse interval, peak voltage, peak current, polarity, rotate speed and group frequency on the process performance have been investigated. Also the EDMed surface microstructure is examined with a scanning electron microscope （SEM）, an X-ray diffraction （XRD）, an energy dispersive spectrometer （EDS） and a micro hardness tester. The results show that the conditions of smaller high-frequency pulse duration and pulse interval, higher peak voltage and peak current, and positive tool polarity are suitable for machining the SiC ceramic. The optimal rotate speed is 1090 r/min and the preferable group frequency is 730 Hz. In addition, there is a small quantity of iron on machined surface when machining with steel electrode. The average grain size of the EDMed surface is smaller than that of the unprocessed, and the micro hardness of machined surface is superior to that of the unprocessed.