辽西建昌玲珑塔地区侏罗纪地层的离子探针锆石U-Pb定年:对最古老带羽毛恐龙的年代制约

辽西建昌玲珑塔地区髫髻山组火山-沉积岩地层中富含燕辽生物群(又称道虎沟生物群)的重要化石,并记录了若干重要的生物演化事件,特别是对研究鸟类的起源以及最早鸟类和恐龙祖先的分化均具有关键的意义,因而其地层时代问题备受关注.本文对建昌玲珑塔大西山含化石沉积层中的3个凝灰岩样品进行了详细的SIMS锆石U-Pb定年,获得了160.7±1.7,159.5±2.3和158.9±1.7Ma的年龄结果.根据近年广泛使用的地质年表GTS2004和新近修订的地质年表GTS2012,由侏罗兽和近鸟龙等构成的燕辽生物群生存于晚侏罗世早期,从而为最早哺乳动物和最早带毛恐龙的出现年代提供了确凿的同位素年代学证据.     

物理气相沉积法制备TP/TFA纳米薄膜与光致发光特性探究

为了探究有机荧光材料在微纳尺寸上的荧光特性，采用低真空物理气相沉积方法制备了茶碱（TP）和2，3，5，6-四氟对苯二甲酸（TFA）有机纳米薄膜。通过对TP和TFA薄膜的荧光性质进行表征发现：与TP粉末相比薄膜的荧光发射峰由1个增加到4个，发射波长范围拓宽了100 nm，TFA的荧光发射峰之间的相对荧光强度发生了变化，与原料粉末相比在408 nm处的荧光发射峰蓝移了7 nm，362 nm处的荧光发射峰红移了3 nm。另外随着纳米薄膜厚度的逐渐增加，其荧光效率也逐渐增大。通过对TP和TFA纳米薄膜的表面形貌表征发现：随着薄膜厚度的增加，颗粒的聚集形态尺寸逐渐增大，从而验证了荧光效率随膜厚增加而逐渐提升的特性。     

Informative gene selection using the Algebraic Connectivity Strength of Point and Scoring Criteria

This paper presents a novel method that integrates the Algebraic Connectivity Strength of Point(ACSP) and Scoring Criteria to identify genes associated with tumor type.First,for each gene,the ACSP is used to identify reliable expression levels of the gene in all the samples.The informative genes are then selected using Scoring Criteria based on these reliable expression levels.Finally,the Support Vector Machine(SVM) classifier is used to classify the two datasets of gene expression profiling.The results show that the informative genes selected by the proposed method have higher credibility than those selected by Scoring Criteria alone.     

Synthesis and characterization of N-aryloxo-functiona- lized β-ketoiminate rare-earth complexes and their catalytic activity for the polymerization of ε-caprolactone

The synthesis and characterization of dimeric rare-earth amides stabilized by a dianionic N-aryloxo functionalized ,8-ketoiminate ligand are described. Reactions of 4-（2-hydroxy-5-methyl-phenyl） imino-2-pentanone （LH2） with Ln[N（SiMe3）2]3（μ-Cl）Li（THF）3 in a 1：1 molar ratio in THF gave the dimeric rare-earth amido complexes [LLn{N（SiMe3）2}（THF）]2 [Ln = Nd （1）, Sm （2）, Yb （3）, Y （4）]. These complexes were well characterized, and the definitive molecular structures of complexes 3 and 4 were determined. It was found that complexes 1-4 can initiate the ring-opening polymerization of ε-caprolactone, and the ionic radii of the central metals have significant effect on the catalytic activity.     

The comparison of biomarkers released by hydropyrolysis and Soxhlet extraction from source rocks of different maturities

The Permian Dalong Formation(P2d) source rocks from the mature Guangyuan outcrop section and the overmature Wangcang outcrop section in Sichuan Basin were selected.The Soxhlet extraction and kerogen catalytic HyPy were conducted on the P2d source rocks.The biomarkers obtained by both methods were compared to discuss their difference and the influence extent of thermal maturation on covalently bound biomarkers.The results show that covalently bound biomarkers can hardly be correlated to the corresponding free biomarkers due to severe thermal alterations and/or interference of migrated hydrocarbons in both outcrop sections and thermal maturation have much lower influence on covalently bound biomarkers in kerogens than on free biomarkers in Soxhlet extracts.The application of HyPy in study of biomarker geochemistry can reduce the thermal maturation effect on biomarkers(Ro≤2.4%) to a greater extent and the interference of migrated hydrocarbons between interbedded layers.The covalently bound biomarkers released by HyPy are useful in the study of biomarker geochemistry and oil-source correlation on high-overmature source rocks.     

红外光学系统中衍射面冷反射的分析与评价

研究了含有衍射面的红外光学系统中冷反射产生的原理, 并指出了衍射表面与折射表面的冷反射的差别. 光线在经过衍射表面后会发生多级衍射, 本文在考虑衍射效率的基础上定量分析了衍射表面的冷反射, 采用对衍射光线进行近轴光线追迹的方法, 给出了针对衍射表面冷反射的新评价标准. 结合一个折衍射混合中波红外光学系统实例, 具体分析了光学系统中衍射表面对冷反射的影响. 研究结果为红外光学系统中衍射表面的冷反射的分析与评价提供了一种全新的方法.     

Mining,characterization, and exploitation of EST-derived microsatellites in <Emphasis Type="Italic">Gossypium barbadense</Emphasis>

Simple sequence repeats (SSRs) have been widely applied as molecular markers in genetic studies. However, the number of ex-pressed sequence tags (ESTs) and SSR markers from Gossypium barbadense is fewer than those from other cotton species. In this study, EST-SSR distribution from G. barbadense was characterized and new G. barbadense-derived EST-SSR markers were de-termined on the basis of the ESTs obtained by randomly sequencing 2 cDNA libraries associated with fiber development in G. barbadense. By mining 9697 non-redundant ESTs, a total of 638 SSR loci derived from 595 ESTs were observed. In G. barba-dense, the frequency of ESTs containing SSRs was 6.13%, with an average of 1 SSR in every 10.4 kb of EST sequence. Further-more, trinucleotide was found to be the most abundant repeat type among 2–6-nucleotide repeat types. It accounted for 26.6% of the total, followed by the hexanucleotide (26.0%) and pentanucleotide repeats (25.9%). Among all the repeat motifs, (AAG)n accounted for the highest proportion. EST-SSR primer pairs were developed using the Primer3 program, and the redundant primers were removed using the virtual PCR approach. As a result, 380 non-redundant EST-SSR primer pairs were developed and used to detect polymorphisms between the mapping parents G. hirsutum ‘TM-1’ and G. barbadense ‘Hai7124’ for constructing linkage groups in cultivated allotetraploid cotton. Out of these, 98 (25.8%) primer pairs detected polymorphisms. Finally, 95 polymorphic loci from 82 primer pairs were integrated into the backbone genetic map; of these, 42 were mapped into the A subgenome and 53 into the D subgenome. The present work provided the foundation for constructing saturated genetic maps and conducting comparative genomic studies on different cotton species.     

Experimental and theoretical investigation of zinc diffusion in N-GaSb

Zinc diffusion process in N-GaSb was studied with excessive, appropriate and insufficient quantity of diffusion source (zinc pellets). Kink-and-tail type zinc concentration profiles obtained with appropriate zinc pellets quantity were successfully simulated using the assumption that the vacancy mechanism mediated by V⁰_Ga and kick-out mechanism mediated by I⁺_Ga take effect at the same time. It is found out that for diffusion temperature from 460°C to 500°C, the zinc surface concentration of the diffused samples has nearly no change and the logarithmic value of the zinc surface diffusion coefficient is linear with the reciprocal value of diffusion temperature; when the diffusion temperature is constant, both the zinc surface concentration and diffusion coefficient do not change with diffusion time.