含有{M[P4Mo6O31]2}夹心型磷钼酸盐构筑块的水溶性多酸化合物的合成与表征

采用水热方法合成了一个新的磷钼酸盐化合物，并通过元素分析、红外、紫外、循环伏安和单晶X射线衍射分析等手段对其进行了表征。单晶结构解析结构表明，该化合物的阴离子{Na[Mo₁₂O₂₄(OH)₆(PO₄H)₂(PO₄H_3/2)₂]}^6- 由2 个{Mo₆P₄O₃₁} 单元和一个八面体配位的金属钠离子共价组装形成，具有夹心型结构。该化合物是目前为止获得的第一个含有孤立M[Mo₆P₄O₃₁]₂ 夹心结构的水溶性多钼磷酸盐。该水溶性化合物将会作为一个基本的反应原料和基本构筑单元合成组装出更多结构新颖、性质丰富的新型多钼磷酸盐。     

Mechanism of the interaction between Au nanoparticles and polymerase in nanoparticle PCR

Nanoparticle PCR is a novel method to optimize DNA amplification. It performs well in improving specificity, enhancing sensitivity and speed. Several mechanisms were proposed in previous studies: one was based on the interaction between gold nanoparticles (AuNPs) and DNA while the other was attributed to the heat transfer property of AuNPs. In this paper, we propose that the interaction between AuNPs and DNA polymerase can significantly influence PCR. First, the addition of DNA polymerase can eliminate the inhibitory effects of excess AuNPs. Second, the addition of AuNPs will increase yield of the desired PCR product and make the optimum concentration of DNA polymerase move to higher value. Third, while excess polymerase might inhibit amplification efficiency, AuNPs can reverse this process and the yield of PCR amplification. Based on these results we propose a possible mechanism that AuNPs might modulate the activity of polymerase and improve PCR amplification.     

Identification of AtSM34, a novel tonoplast intrinsic protein-interacting polypeptide expressed in response to osmotic stress in germinating seedlings

Aquaporins are implicated in a wide variety of plant physiological processes, although the mechanisms involved in their regulation are not fully understood. To gain further insight into the regulatory factors involved in this process, we used a yeast two-hybrid system to screen for potential binding partners to the Arabidopsis tonoplast intrinsic protein (TIP) AtTIP1;1. This was the first protein identified to be associated with high water permeability in vacuolar membranes from Arabidopsis thaliana. Using ...     

Pure water splitting to generate H2 over strontium niobate and tantalate: A comparative study

To clarify the nature of different photocatalytic activities between niobate and tantalate,a comparative study of the water splitting into H2 over strontium niobate and tantalate was performed.These isostructural photocatalysts were prepared by a facile and simple hydrothermal reaction and characterized by powder X-ray diffraction(XRD),N2-sorption,UV-Vis diffuse reflectance spectra(UV-Vis DRS),and transmission electron microscopy(TEM).The effects of crystal structure,Brunauer-Emmett-Teller(BET) surface area,photoabsorption performance,morphology,and electronic structure are discussed.     

“20%的概率获得蛋糕”=“获得蛋糕的20%”?检验风险决策的期望法则假设

风险决策主流理论以期望法则的计算为核心假设,认为决策者需要进行"加权求和"的期望值计算过程.为检验这一基本假设,本研究采用相同的视觉材料设计了两类任务:将"%"看成"概率"的概率决策任务(风险决策)和将"%"看成"比例"的比例决策任务(计算决策).两任务均要求被试选择自己偏好的选项.考虑到被试在比例决策任务中须执行"加权求和"的期望值计算,方能使其收益最大化,我们推测,若被试在概率决策任务中也是根据"加权求和"规则做出决策,我们应当会发现影响"期望值计算"的诸因素(如计算难度、算术能力)同时影响两类任务.结果发现:计算难度和算术能力只影响比例决策任务绩效(其反应时更长,基于期望值选择的比例更高),但不影响概率决策任务绩效.相反,与"期望值计算"无关的"概率能力"和"感觉寻求人格"只影响概率决策任务绩效,但不影响比例决策任务绩效.该结果表明,概率能力和人格对风险决策的行为绩效起调节作用,人们在风险决策中可能并未按照期望法则的精确计算方式做出决策.期望法则家族理论将"加权求和"结果作为人类风险偏好的单一指数,或许是一种人为创造的错误指数.     

Grenvillian orogeny in the Southern Cathaysia Block: Constraints from U-Pb ages and Lu-Hf isotopes in zircon from metamorphic basement

Metamorphic basement rocks in the Cathaysia Block are composed mainly of meta-sediments with different ages. New zircon U-Pb geochronological results from the meta-sedimentary rocks exposed in the Zengcheng and Hezi areas, southern Cathaysia Block, show that they consist dominantly of early Neoproterozoic （1.0-0.9 Ga） materials with minor Paleo- to Mesoproterozoic and late Neoproterozoic （0.8-0.6 Ga） components, suggesting that the detritus mostly come from a Grenvillian orogen. The youngest detrital zircon ages place a constraint on the deposition time of these sediments in Late Neoproterozoic. Zircon Hf isotopic compositions indicate that the Grenvillian zircons were derived from the reworking of Mesoproterozoic arc magmatic rocks and Paleoproterozoic continental crust, implying an arc-continent collisional setting. Single-peak age spectra and the presence of abundant euhedral Grenvillian zircons suggest that the sedimentary provenance is not far away from the sample location. Thus, the Grenvillian orogen probably preexisted along the southern margin of the Cathaysia Block, or very close to the south. Similarity in the ages of Grenvillian orogeny and the influence of the assembly of Gondwana in South China with India and East Antarctic are discussed, with suggestion that South China was more likely linked with the India-East Antarctica continents in Early Neoproterozoic rather than between western Laurentia and eastern Australia.     

巨轮型多金属氧酸盐纳米超薄多层膜的制备

首次将巨轮型纳米多孔多金属氧酸盐Na₁₅［Mo^VI₁₂₆Mo^V₂₈O₄₆₂H₁₄(H₂O)₇₀］_0.5［Mo^VI₁₂₄Mo^V₂₈O₄₅₇H₁₄(H₂O)₆₈］_0.5·ca.400H₂O通过层层自组装的方法,与聚乙烯基亚胺（PEI）通过静电作用自组装形成纳米超薄多层膜。该膜的制备过程通过紫外可见光谱进行监测,巨轮型纳米多孔多金属氧酸盐的特征吸收峰的吸收值随着层数的增加呈线性增长关系,表明在纳米超薄多层膜的组装过程中巨轮型多金属氧酸盐的结构没有被破坏,自组装成膜的过程是一个层层均一、反复生长的过程,每层吸附循环沉积的聚电解质和多金属氧酸盐的量相等。对纳米超薄多层膜的偏振紫外光谱的研究表明巨轮型纳米多孔多金属氧酸盐分子在纳米超薄膜中不是杂乱无章随意排列堆积的,而是在带高负电荷的巨轮型纳米多孔多金属氧酸阴离子间存在的静电排斥作用下彼此平行倾斜在基片表面并且与基片表面成一定的取向角从而减低整个体系的能量达到最稳定状态。     

Paleoproterozoic basement beneath the southern Jiangxi Province: Evidence from U-Pb ages and Lu-Hf isotopes in zircons from the Doushui lamprophyre

This paper presents geochemical analyses of a lamprophyre intruding the Caledonian Doushui granite body in Shangyou County, southern Jiangxi Province. U-Pb dating and Hf-isotope analyses are espe-cially carried out for zircons from it. Petrological and geochemical features show that the lamprophyre belongs to a high-K, weakly alkaline pyroxene-biotite lamprophyre. It is characterized by high Mg# (0.74), Ni (253 μg/g) and Cr (893 μg/g) contents, and also enriched in incompatible elements, such as REE, Rb, Sr...     

高压消毒岗位与屏障内岗位的工作协作探讨

高压消毒锅是介于屏障系统内外之间的物理消毒器械,也是物品内流的重要关口,高压消毒锅消毒物品的效率高低将直接影响消毒与屏障内岗位的工作配合。制定消毒制度,协调消毒与屏障内岗位的配合,对提高屏障系统的工作效率十分重要。     

Discovery of Paleoproterozoic rapakivi granite on the northern margin of the Yangtze block and its geological significance

The Huashanguan rapakivi pluton in Zhongxiang,Hubei Province,China,is the first discovered Proterozoic rapakivi pluton in the Yangtze block.Based on field and petrographical observations,a typical rapakivi texture was found in the northern portion of the Huashanguan granitic pluton.Almost all the K-feldspar phenocrysts were round to oval in shape and most had plagioclase coatings known as rapakivi phenocrysts.Alkali feldspars and quartz had two or more generations.Petrochemically,the Huashanguan rapakivi granites were characterized as having high values of Si,K,Fe,Th,U,La,Ga,Ce,Sm and LREE,low values of Ca,Mg,Sr,Nb,Y and HREE,and a negative Eu anomaly.These geochemical characteristics of the Huashanguan granites were concordant with typical rapakivi granites,and had an affinity to A-type granites.LA-ICP-MS U-Pb zircon dating also was conducted.The dating yielded a 207Pb/206Pb weighted mean age of 1851±18 Ma (MSWD =1.2),which represents the age of the pluton emplacement.The age of 803±170 Ma at the lower intercept in the concordia diagram corresponds to the age of a later deformation event which affected the pluton,and suggests that the Huashanguan pluton was influenced by Neoproterozoic thermo-tectonic events after its formation.The discovery of Paleoproterozoic Huashanguan rapakivi granites indicates continental rifting or a post-orogenic extensional event that took place in the Paleoproterozoic in the Yangtze block.These events may be related to the breakup of the Paleoproterozoic Columbia supercontinent.