随机波浪对浪溅区三维结构物冲击作用试验研究

通过物理模型试验研究了随机波浪对位于浪溅区三维结构物的冲击作用.试验波浪为单向随机波.试验中波浪分别从正向(波向角β＝0°)和斜向(β＝15°、30°、45°)入射,入射波波高H1/3=7.5～20 cm,谱峰周期Tp=0.75～2.0 s,模型相对净空s与入射波高H1/3之比为0～0.5.对不同试验组次试验数据的统计分析比较得出:正向波和斜向波作用于结构物底面的冲击压力特征值,中部大、周围小;波浪冲击压力等值线基本上垂直对称分布于波向线两侧;结构物所受波浪冲击力随入射波波高增大而增大,对应相对板宽的变化出现2个峰值,在相对净空s/H1/3为0.1和0.2时到达最大值.     

Molecularly Imprinted Polymer Based on GO-QDs as Enhanced Fluorescent Nanoscale Device for Specific Recognition of Target Protein

In this work the enhanced molecularly imprinted optosensing material based on graphene oxide-quantum dots （ GO- QDs） was synthesized for highly selective and sensitive specific recognition of the target protein, bovine serum albumin （BSA）. Here, GO was introduced to enhance the efficiency of mass-transfer in recognition of target protein. Molecularly imprinted polymer coated GO-QDs using BSA as template （BMIP-coated GO-QDs ） exhibited a fast mass-transfer speed, which could be ascribed to the high volume of efficient surface area and high target recognition efficiency of the synthesized nanoscale device. Under optimal conditions, it was found that the BSA as target protein could remarkably quench the relative fluorescence intensity of BMIP- coated GO-QDs linearly in a concentration-dependent manner that was best described by a Stern-Volmer equation. The Ksv （Stern- Volmer constant） for template BSA was much higher than bovine hemoglobin （BHb） and lysozyme （Lyz）, implying a highly selective recognition ability of the BMIP-coated GO-QDs to BSA. This enhanced fluorescent nanoscale device may provide opportunities to develop a system that is efficient and effective and has potential in the design of highly effective fluorescent receptor for recognition of target protein in Droteomics studies.