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研究了YxGd(1-x)P3O9:Dy0.01(x=1,0.95,0.5,0)的真空紫外激发和发射光谱.直接观测到了Dy^3+在真空紫外波段的5d→4f发射,发现随着Gd^3+含量的增加,Dy^3+的5d→4f发射迅速减弱,这表明Gd^3+的存在分流了Dy^3+ 5d HS激发态的能量.基于实验结果,提出了一个量子剪裁模型. 相似文献
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Ammonia borane has received tremendous research attention in the past decade because of its potential for chemical hydrogen storage. This paper reviews recent studies about the behavior of ammonia borane at high pressures. While much work is still needed to comprehensively understand the pressure influence on this molecular crystal, a phase diagram based on the available experimental and theoretical data is constructed. Raman spectroscopy studies indicate five transitions upon compression up to 65 GPa at ambient temperature. Diffraction experiments and theoretical studies demonstrate that three of these transitions are first-order phase transformations in the sequence of I4mm-Cmc21-P21-(different) P21, and two are iso-structural. A low-temperature phase(Pmn21) and a high-temperature high-pressure phase(Pmna) are also recognized. 相似文献
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LIU Xiao-nan BAO Jun FU Yi-bin QI Ze-min ZHANG Guo-bin GAO Chen CHAN Ting-shan DROZD Vadym LIU Ru-shi 《中国科学技术大学学报》2007,(Z1)
研究了YxGd1-xP3O9:Dy0.01(x=1,0.95,0.5,0)的真空紫外激发和发射光谱.直接观测到了Dy3 在真空紫外波段的5d→4f发射,发现随着Gd3 含量的增加,Dy3 的5d→4f发射迅速减弱,这表明Gd3 的存在分流了Dy3 5d HS激发态的能量.基于实验结果,提出了一个量子剪裁模型. 相似文献
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