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Hch Zollinger 《Cellular and molecular life sciences : CMLS》1954,10(12):481-482
Summary In an aqueous buffer solution (pH 6...64) p-diazochlorbenzene reacts with 2-naphthol-6,8-disulphonic acid four times faster than with the deuterated compound 1-d-2-naphthol-6, 8-disulphonic acid. This shows that the proton loss is rate determining. Other diazo coupling reactions do not give such a kinetic isotope effect. 相似文献
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