The v-v energy transfer of highly vibrationally excited states (I)

The relaxation of the highly vibrationally excited CO (v = 1–8) by CO₂ is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture of CHBr₃ with O₂ generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO₂ molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (10¹⁴ cm³ · molecule⁻¹ · s⁻¹), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO². For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u³ mode of CO² For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u¹ mode of CO².     

The v-v energy transfer of highly vibrationally excited states (II)

The vibrational energy transfer from highly vibrationally excited CO to H₂O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser photolysis of CHBr₃ and O₂ the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H₂O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for CO(v)/H₂O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (10¹³cm³ · molecule^-1· s^-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H₂O is suggested.     

重庆市三峡库区医疗垃圾现状及无害化处理分析

医疗垃圾属于一类危险废物，必须进行无害化处理。文章论述了医疗垃圾的特性和危害性，对重庆市三峡库区目前医疗垃圾管理和处理的现状进行了分析，针对其特点，提出对三峡库区医疗垃圾有效的管理措施和进行分区集中处理，具体分析了医疗垃圾处理技术方案：分类收集、密闭运输、预处理、焚烧、完全填埋等。通过无害化处理后，杜绝医疗垃圾对环境的污染，以保护三峡库区生态环境和水资源。     

电喷汽油机怠速不良故障的诊断方法

分析了电喷汽油发动机怠速控制系统的工作原理,总结了怠速不良故障的常见原因,介绍了常见的3种怠速不良故障的诊断方法。     

虾青素的化学合成法概述

虾青素是萜类化合物β-胡萝卜素的一种，广泛存在于自然界中，具有较强的抗氧化活性和多种生理活性，应用于诸多领域.综述了虾青素的几种化学合成方法，再展望了虾青素的发展前景.     

概率一致假想地震及在砂土液化小区划中应用

对文献提出的用点源模型确定假想地震的方法作了进一步的改进和补充，给出了用断层破裂模型确定想地震的方法，并首次尝试运用概率一致的假想地震进行砂土液化的评估，为进行以概率为基础的砂土液化小区划找到了一条捷径。     

弗里德曼消费函数和持久收入

对弗里德曼消费函数和持久收入进行了较深入的研究，进一步阐明了弗里德曼经验公式所对应的经济环境，并得出一个新的持久收入估计公式．     

加入WTO对我国科技期刊的宏观影响

加入WTO以后，中国科技期刊将在理念、政策及管理环境、竞争环境、布局结构以及其它相关因素等方面发生的深刻变化。科技期刊应该尽快树立与WTO规划相适应的意识和理念，按WTO的要求，加快自身的调整，增强核心竞争力，从而在日趋激烈的竞争条件下，获得继续生存与发展的空间。     

催化氧解褐煤生产黄腐植酸的实验研究

对云南曲靖褐煤进行H2O2、HNO3氧解提取黄腐植酸的研究,考察了H2O2、HNO,氧解中N—Mn—TiO2介孔催化剂对黄腐植酸产率和组成结构的影响,对系列氧化产物OFA和NFA进行了官能团含量定性、定量分析,红外光谱分析．研究结果表明：两种N—Mn—TiO2介孔催化剂都能显著提高黄腐植酸的产率,催化剂1（N：Mn：Ti比为16：0．001：1焙烧温度400℃）、催化剂2（N：Mn：Ti比为16：0．001：1焙烧温度100℃）催化H2O2、HNO3氧解时产率较不加时分别增加了32．17％、10．69％和8．61％、7．49％．理化组成研究表明：加入催化剂后,H2O2氧解产物中的总酸性基含量变化不大,羧基含量增加,酚羟基含量降低,HNO3氧解产物中总酸性基、酚羟基含量降低．OFA与NFA的结构组成不同．     

一类奇异二阶边值问题的多重解

利用变分方法得到了一类非线性奇异二阶边值问题多重解的个数至少是2n,并应用该结论说明了一个具体的边值问题至少有14个解.