C(R)中非线性最佳逼近的特征

对 C(R)中一类非凸子集,在一特定的距离下,给出了最佳逼近的特征,其中包括 Kolmogorov 型与 Chebyshev 交错型特征定理。作为推论,我们得到了在这距离下有理最佳逼近的特征.     

单边双裂纹模型及其J积分的守恒性

针对某些工程结构特点,设计了单边双裂纹模型。然后先从理论上证明了其结构J积分的守恒性,再以焊接接头为例,通过体现焊接接头的几个特征参数,从力学和几何不均匀性两方面给予有限元方法数值实验证明,从而为工程结构中类似的缺陷评定奠定基础。     

炼镁还原罐材质的成份设计

本文针对炼镁还原罐在使用条件下的破坏形式及对该材质的成份设计进行了分析 ,还原罐材质在具有单一奥氏体的基础上 ,进行良好的合金化处理是提高其抗蠕变性和热强性的有效方法 ,对提高材质的使用寿命起到良好的作用。     

Observation of conformation-specific pathways in the photodissociation of 1-iodopropane ions.

Many molecules can rotate freely around single bonds and thereby interconvert between different conformations, such as gauche and anti 1,2-disubstituted ethane, a classic example of conformational isomerism. Even though rotation occurs rapidly at room temperature, the product selectivity seen in some reactions has been explained by conformation-dependent reaction mechanisms: if reactant molecules differing only in their conformation are located at different positions on the reaction path, they may undergo different reactions. But a direct verification of this effect is difficult, because the energy barrier separating conformational isomers is so low that under ambient conditions reactants with more than one conformation will be present. But by using temperatures low enough to suppress the interconversion between different conformations, gauche-1-iodopropane ions and anti-1-iodopropane ions have been selectively generated. Here we show that the kinetic energy released during the photodissociation of 1-iodopropane ions depends strongly on the conformation of the ions. Thermodynamic arguments and ab initio calculations indicate that this difference in kinetic energy release results from differences in the reaction mechanism, with gauche-1-iodopropane ions forming 2-propyl ions and anti-1-iodopropane ions forming protonated cyclopropane ions. These findings suggest that the well-known concept of conformation selection forms the basis of a simple scheme for reaction control, thus providing in some cases an attractive alternative for more involved schemes that utilize the phase and pulse shape of laser beams to control chemical reactions.     

精测安培表内阻的新方法——电桥伏安法

本文提出了精测安培表内阻的新方法,并将其与其它测量方法进行了比较。     

应力、应力纤维、Rho三者关系的研究进展

应力影响细胞的形状和骨架结构并因此控制许多与组织发展有关的关键行为，因此应力作用下细胞的种种响应问题成为生物力学目前最热的研究领域，应力纤维、Rho在研究应力信号如何被细胞感受过程中占据核心地位并已成为研究者关注的重点。本文依据国内外近几年进行的细胞对应力响应的研究进展对应力、应力纤维、Rho三者的相互关系进行了综述。     

Study on Approach for Computer-Aided Design and Machining of General Cylindrical Cam Using Relative Velocity and Inverse Kinematics

Cylindrical Cam Mechanism which is one of the best eq uipments to accomplish an accurate motion transmission is widely used in the fie lds of industries, such as machine tool exchangers, textile machinery and automa tic transfer equipments. This paper proposes a new approach for the shape design and manufacturing of the cylindrical cam. The design approach uses the relative velocity concept and the manufacturing approach uses the inverse kinematics concept. For the shape desig n, the contact points betw...     

双模随机晶体场对混合自旋1/2和自旋1纳米管上相变的影响

本文利用有效场理论研究了自旋1/2和自旋1混合Blume-Capel模型在具有双模随机晶体场的圆柱形Ising纳米管上的磁化和相变. 通过数值计算,我们得到了随温度和随机晶体场参数变化的相图和磁化强度. 结果表明: (1) 改变晶体场的概率和比例,双模随机晶体场可以描述不同掺杂原子对自旋的作用;(2) 对于一定的概率值、负或正的晶体场和晶体场的比例值都存在临界点;(3) 系统显示多种相变温度,一阶相变和二阶相变.     

煤中前沥青烯与沥青烯性质的研究

煤的溶剂抽出物中前沥青烯与沥青烯的质量之比随煤化程度增加而增加。原位热解红外光谱研究结果表明,它们的热稳定性与其结构参数有关,芳香度高,甲基取代结构多的前沥青烯比沥青烯的热稳定性好。前沥青烯与沥青烯在溶剂分级过程中表现出的溶解性与其结构参数无必然联系,而与其酸碱组分间的氢键强度有关。前沥青烯中酸碱组分间的氢键强度为５．１５～３０．９ｋＪ／ｍｏｌ;沥青烯为＜５．１５ｋＪ／ｍｏｌ。     

纳米催化剂KF/Al2O3制备条件的正交设计与优化

采用正交设计法优化了浸渍法制备固体超强碱KF/Al2O3催化剂工艺参数.以丙烯腈和丙二酸二乙酯的Michael加成反应收率为考察指标,对催化剂制备工艺进行优化,并采用SPSS统计软件包对制备工艺参数进行多元回归统计,并根据回归拟合的多项式数学模型,讨论了浸渍法制备的较佳工艺.