新型双污泥反硝化除磷工艺的初步研究

介绍了基于反硝化除磷理论的双污泥工艺(A2N工艺),分析了传统双污泥工艺的优点和影响因素.摒弃了固有工艺流程冗长,基建费用过高;工艺出水氨氮过高等缺陷.在深入分析的基础上,设计了新型的双污泥工艺,缩短了工艺流程,提高了出水水质.改进后的工艺不仅可以解决同步脱氮除磷的问题,而且可用于再生水的生产.目前该工艺正在小试中,运行良好.     

调酸式催化水解稻壳制备乙酰丙酸的研究

试验采用调酸式稀酸催化水解工艺,从稻壳中提取乙酰丙酸.根据Box-Behnken实验设计方法,确定影响乙酰丙酸收率的主要因素分别为硫酸浓度、反应温度、反应时间和液固比,分别在三水平条件下进行了27次试验,并建立了二次方程的模型,R2=0.986 1,显示该模型具有较好的拟合度;进一步通过响应面分析确定优化的水解条件:硫酸浓度3.9%,温度227℃,反应时间32 min,液固比16:1.在调酸催化水解工艺条件下,目标产物收率为38.426%,与模型估计值接近.     

温度和污泥质量浓度对反硝化除磷的影响

以实验室运行的连续流双污泥同步除磷脱氮系统中沉池污泥为研究对象,分别考察了温度及污泥质量浓度,对反硝化除磷的影响.结果表明,反硝化聚磷菌属于低温耐冷菌,低温冲击对缺氧吸磷的影响并不大,10 ℃、20 ℃、30 ℃的最终吸磷量都很接近,3 ℃时吸磷也并没有停止,仍有9.12 mg/L的吸磷量.污泥质量浓度的变化对反硝化除磷效率的影响并不大,增大污泥系统的MLSS,可以提高缺氧初期的反硝化吸磷速度,和最终的吸磷总量,但单位污泥的吸磷量没有提高反而减小.     

Enhanced Biological Phosphorus Removal in SBR Using Glucose as a Single Organic Substrate

Enhanced biological phosphorus removal （EBPR） was investigated in an anaerobic/aerobic sequencing batch reactor （SBR） supplied with glucose as a single organic substrate. The results illustrated that EBPR process could also occur successfully with glucose other than short chain fatty acids （SCFAs）. High phosphorus release and polyhydroxyalkanoate （PHA） accumulation in the anaerobic phase was found vital for the removal of phosphorus during the aerobic phase. The measurement of intracellular reserves revealed that glycogen had a higher chance to replace the energy role of poly-P under anaerobic conditions. Moreover, glycogen was also utilized as the carbon source for PHA synthesis, as well as a reducing power as reported earlier. The accumulated PHA in this system was mainly in the form of poly-hydroxyvalerate （PHV） instead of poly-hydroxybutyrate （PHB）, and was inferred to be caused by the excess reducing power contained in glucose. Lactate as a fermentation product was also found released into the bulk solution. Applying fundamental biochemistry knowledge to the experimental results, a conceptual biochemical model was developed to explain the metabolism of the glucoseinduced EBPR.