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Summary Aralkyl and alkyl isothiocyanates, like aryl isothiocyanates, undergo a selective and reversible reaction with essential thiol groups of D-glyceraldehyde-3-phosphate dehydrogenase; the former 2 substances require for a reversible reaction course a more alkaline medium and presence of a thiol.The authors are indebted to Dr J. Augustín for valuable discussions, to Dr E. Rená and Dr M. Gemeinerová for their technical assistence. The authors wish also to thank Dr H. R. Kricheldorf for sample of 4-(trimethylsilyl) butanoyl isothiocyanate 相似文献
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D. Podhradský Ľ. Drobnica P. Kristian 《Cellular and molecular life sciences : CMLS》1979,35(2):154-155
Summary Isothiocyanates react with deprotonated SH groups of investigated compounds to give the esters of N-monosubstituted dithiocarbamic acid. In the presence of the SH and NH2 groups (Cys, GSH), isothiocyanates react primarily with the SH groups. The reactions are dependent on the pKaSH values. 相似文献
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Aralkyl isothiocyanates, like aryl isothiocyanates, undergo a selective and reversible reaction with essential thiol groups of D-glyceraldehyde-3-phosphate dehydrogenase; the former 2 substances require for a reversible reaction course of more alkaline medium and presence of a thiol. 相似文献
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Zusammenfassung Es wird gezeigt, dass 1–2%iges Dimethylsulfoxyd sich als unschädliches Lösungsmittel für antibakterielle Substanzen besonders gut eignet. 相似文献
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Isothiocyanates react with deprotonated SH groups of investigated compounds to give the esters of N-monosubstituted dithiocarbamic acid. In the presence of the SH and NH2 groups (Cys, GSH), isothiocyanates react primarily with the SH groups. The reactions are dependent on the pKa SH values. 相似文献
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