鱼腥藻毒素合成中间体的不对称合成

报道(一)-AnTx-a关键中间体的四步合成新途径,设计一个新型(一)-AnTx-a类似物并以同法合成其中间体,本法是对以Mannich反应为基础的AnTX-a的合成策略的补充。     

巷道底板上锚杆布置形式对预防底鼓效果的模拟研究

本文采用三个边界元模型对巷道底板上锚杆的不同布置形式对防治底鼓的效果进行了模拟研究。根据研究结果,提出采用在巷道底板上分期安装锚杆的方法,可有效地防治巷道底鼓。本文对巷道底鼓产生机理和防治措施的研究结果,具有一定的理论价值和应用参考价值。     

等温淬火球墨铸铁的磨粒磨损行为

在实验室条件下对两种经等温淬火处理的工业球墨铸铁进行了磨粒磨损实验。并与在相同实验条件下的一系列耐磨粒磨损钢的实验结果进行了比较。结果表明,经等温淬火后的两种球墨铸铁均比专门耐磨粒磨损钢具有更好的抗磨粒磨损性。 这两种球墨铸铁的优良性能来源于其铁素体-奥氏体双相基体所特有的形貌。这种双相基体可在磨粒磨损中引起奥氏体向应力诱发马氏体转变,从而造成高的加工硬化特性。本文还把组织和机械诱发相变的影响作为等温淬火温度和时间的函数进行了研究。     

Self-assembling Characteristics of Amphiphilic Star Block Copolymers with a Polyelectrolyte Shell

1 Results Amphiphilic block copolymers are capable of forming supramolecular assemblies resembling those observed in nature,such as spherical micelles,worm micelles,and vesicles.Changing the solvent composition,ionic strength or pH of the polymer solution may induce the self-assembly of block copolymers or trigger the transition between the geometries of noncovalent assemblies.In the current work,we have synthesised starlike amphiphilic block copolymers having hydrophobic poly(methyl methacrylate),PMMA,core,and hydrophilic poly(acrylic acid),PAA,shell.The self-assembling characteristics of these polymers have been investigated in aqueous solutions by light scattering and direct visualisation by cryo-transmission electron microscopy (cryoTEM)[1]. Computer simulations along with the theoretical predictions made for the star-like system based on mean-field theory have been used to support the experimental observations[2]. The association of the starlike macromolecules resembles that of charged biopolymers,such as actin,since a balance between attractive and repulsive forces is required for the formation of cylindrical assemblies and can be manipulated by changing the pH or the ionic strength of the solvent[3].