Synthesis of Thermoresponsive Poly（ diethyleneglycol methacrylate-co-6-Ovinyladipoyl-D-glucopyranose） Glycopolymer via RAFT Polymerization

The monomer 6-O-vinyladipoyl-D-glucopyranose（ VAG）was synthesized by lipase catalyzed trans-esterification of divinyladipate with D-glucopyranose. A novel double hydrophilic glycopolymer poly（ diethyleneglycol methacrylate-co-6-Ovinyladipoyl-D-glucopyranose）（ P（ DEGMA-co-VAG）） with narrow polydispersity（ PDI） and thermosensitivity was prepared by reversible addition-fragmentation chain transfer（ RAFT）polymerization. P（ DEGMA-co-VAG） was characterized by1 H NMR,FTIR and gel permeation chromatography（ GPC）. The characterization of UV-visible spectroscopy showed that the micelles from glycopolymer P（ DEGMA-co-VAG） were thermo-responsive and the low critical solution temperature（ LCST） could be controlled by the molar ratio of monomers. When the molar ratio of DEGMA and VAG was 2∶ 1,the LCST of P（ DEGMA-co-VAG） was36 ℃ in aqueous solution,which could form nano micelles in the human body environment. It was found that P（ DEGMA-co-VAG）was non-toxic at 0. 1-1 mg / m L concentrations when incubated with pig iliac endothelial cells（ PIECs） for 24 h. Thus,the synthesized glycopolymers has great potential as drug delivery carriers.     

棉纤维中果胶与角质的附生关系

对棉纤维中果胶和角质层的角质的附生关系进行假设,构建了4种模型:层层式、层层-分散式、树状-分散式和树状式.通过脱蜡前后染色和草酸铵抽提对棉纤的果胶含量加以测定,经过扫描电子显微镜(SEM)和衰减全反射傅里叶红外光谱(FTIR-ATR)分析得出:果胶与角质的附生关系符合层层式,角质中不含游离果胶,角质与果胶并无相互穿插、迭加或包覆,而是有着较为清晰的层次界限,角质在外层,果胶在内层,果胶将蜡状物质黏附于纤维素或半纤维素的表面.     

古尔班通古特沙漠生物结皮中微生物分布的时空差异

对新疆古尔班通古特沙漠生物结皮层微生物分布的时空差异及其与土壤因子的关系进行了研究,结果表明:微生物分布受沙垄地貌部位、土层深度、季节影响呈现时空差异．空间尺度上,细菌在春秋季均为垄顶最少,垄间低地最多．放线菌及真菌在沙垄不同地貌部位的空间分布基本一致,但春秋季的空间分布格局有差异．含水量与微生物总数量的变化趋势一致,春秋季均表现为垄顶最少,垄间低地最多,春季尤为明显．在0-20cm土层中,微生物各类群的垂直分布受地貌部位和季节影响呈不同变化趋势．时间尺度上,春秋季微生物总数量、微生物各类群数量在背风坡、迎风坡及垄间低地均表现为春季>秋季,在背风坡表现的尤为明显．微生物各类群在垄间低地的垂直分布春秋季均表现为:细菌随土层加深增多;放线菌随土层加深减少;真菌先增后减．微生物各类群在垄顶的垂直分布春秋季有差异．含水量在各地貌部位0—30cm各土层,均表现为春季>秋季,0～10cm土层中尤为明显。微生物总数中细菌占绝大多数,依次为放线菌、真菌．细菌比例春季>秋季,放线菌和真菌则相反．微生物分布与有机质、全氮、全磷、速效磷、速效钾、pH、电导、盐分、过氧化氢酶、脲酶、中性磷酸酶、碱性磷酸酶有显著的相关性．     

喷雾沉积法制备多功能纸夹板及其性能

纸夹板外固定骨折部位联合外敷传统中药治疗骨折,在中医骨伤科临床中被广泛使用。纸夹板具有质量轻、固定简便、方便患肢进行功能锻炼的优点,但是中药异味对部分患者感官刺激较大,严重影响患者的人际交往环境。以普通的纸夹板为基底,采用喷雾沉积技术,制备了氧化石墨烯(graphene oxide, GO)负载的多功能纸夹板。采用扫描电子显微镜、傅里叶变换红外光谱和力学性能测试分别研究了多功能纸夹板的表面形貌、理化性能和力学性能,并研究了中药异味吸附性能和红外保健功能。研究结果表明,表面负载GO的功能纸夹板,随着GO负载量的增加,其力学性能、中药气味吸附率、光热转化性能和蓄热变化率随之提高。当GO负载量为0.8%时,功能纸夹板的拉伸强度为10.98 MPa,中药气味吸附率达到60.25%,其蓄热变化率为3.8℃/min。     

Molecularly Imprinted Polymer Based on GO-QDs as Enhanced Fluorescent Nanoscale Device for Specific Recognition of Target Protein

In this work the enhanced molecularly imprinted optosensing material based on graphene oxide-quantum dots （ GO- QDs） was synthesized for highly selective and sensitive specific recognition of the target protein, bovine serum albumin （BSA）. Here, GO was introduced to enhance the efficiency of mass-transfer in recognition of target protein. Molecularly imprinted polymer coated GO-QDs using BSA as template （BMIP-coated GO-QDs ） exhibited a fast mass-transfer speed, which could be ascribed to the high volume of efficient surface area and high target recognition efficiency of the synthesized nanoscale device. Under optimal conditions, it was found that the BSA as target protein could remarkably quench the relative fluorescence intensity of BMIP- coated GO-QDs linearly in a concentration-dependent manner that was best described by a Stern-Volmer equation. The Ksv （Stern- Volmer constant） for template BSA was much higher than bovine hemoglobin （BHb） and lysozyme （Lyz）, implying a highly selective recognition ability of the BMIP-coated GO-QDs to BSA. This enhanced fluorescent nanoscale device may provide opportunities to develop a system that is efficient and effective and has potential in the design of highly effective fluorescent receptor for recognition of target protein in Droteomics studies.