江西南部版石盆地火山岩SHRIMP锆石U-Pb年龄及其地质意义

应用SHRIMP锆石U-Pb定年方法,对江西南部三南-寻乌火山岩带版石盆地原鸡笼嶂组凝灰岩和原版石组流纹岩开展年代学研究.结果表明,凝灰岩SHRIMP锆石U-Pb年龄为(142.5±1.3)Ma,流纹岩SHRIMP锆石U-Pb年龄为(131.4±1.3)Ma.根据新的国际地层表,晚侏罗世与早白垩世的界线划在(145.5...     

The age measures and its layer sequence tratigraphy of Late Quaternary sediment in Lushan Dajiaochang of China

Through the scientific investigation on Lushan for a long time, detailed studies have been carried out on the geologic stratum section of Late Quaternary in Dajiaochang. The series age data of complete stratigraphic section and full time formation since 400 kaBP were based on the results of the analyses using the dating methods with various instruments such as the ancient geomagnetism, electronics spin resonance （ESR）, 36C1 and lumines- cence dating, etc. Corresponding to these data, it identified the paleomagnetic polarity events including Biwa- III event （320 kaBP）, Biwa- 1I event （260 kaBP）, Biwa- I event （180 kaBP, scarcity due to the disturbance of the iron dish）, Blake event （100 kaBP） and Laschamp event （20 kaBP, didn＇t grow due to the activities of the surface）, etc. Combined with the sequence stratigraphy, layer type characteristics and its sediment environment, the strati- graphic can be divided into 4 stages of development respectively ： Stage [ is the climate period of glacial epoch （200-400 kaBP）; stage 11 is the climate period of interglacial epoch （100-200 kaBP）; stage llI is the climate peri- od of periglacial epoch （10-100 kaBP）; stage IV is the climate period ofpostglacial epoch （0-10 kaBP）.     

In situ simultaneous determination of trace elements, U-Pb and Lu-Hf isotopes in zircon and baddeleyite

This paper describes a combined method of simultaneously measuring U-Pb and Lu-Hf isotopes as well as trace elements in Phalaborwa baddeleyite and 91500, GJ-1, TEMORA-1 and SK10-2 zircons by means of Neptune MC-ICPMS and Agilent Q-ICPMS connected to a 193 nm excimer laser ablation system. Material ablated by laser was carried in different proportions into Q-ICPMS for U-Pb isotopic and trace elemental and MC-ICPMS for Lu-Hf isotopic compositions. Experiments indicate that different proportions of ablated material for the Q-ICPMS and MC-ICPMS （6：4, 5：5 and 4：6 respectively） do not show any bias for the zircon/baddeleyite U-Pb age, Lu-Hf isotope and trace elemental compositions within analytical errors. Using 40-60 μm spot size, the obtained U-Pb ages of Phalaborwa baddeleyite, 91500, GJ-1, TEMORA and SK10-2 zircons are 2065±15 （2σ, n=20）, 1063±6 （2σ, n=-19）, 613±6 （2σ, n=20）, 416±5 （2σ, n=20） and 32.6±0.5 （2σ, n=20） Ma, respectively. The ^176Hf/^177Hf ratios are 0.281231±24 （2SD, n=20）, 0.282310±35 （2SD, n=19）, 0.282028±34 （2SD, n=20）, 0.282687±34 （2SD, n=20） and 0.282752±53 （2SD, n=20）, respectively. The obtained trace elemental compositions are identical to the reference values. Therefore, this kind of technique makes it possible to simultaneously obtain the U-Pb age, Lu-Hf isotopes and trace elemental compositions of zircon and baddeleyite, which could be an important tool in solving problems in earth sciences.     

Caledonian reworking of Paleoproterozoic basement in the Cathaysia Block: Constraints from zircon U-Pb dating,Hf isotopes and trace elements

A combined study of zircon U-Pb dating, Hf isotopes and trace elements has been carried out for granodioritic neosomes of migmatites from the Tianjingping area in northwestern Fujian Province. Zircons are characterized by zoning, higher Th/U ratios （mostly≥0.1）, HREE enrichment, and positive Ce and negative Eu anomalies, and show features similar to magmatic or anatectic zircons. Apparent ^206Pb/^238U ages for the zircons are 447±2 Ma （95 % conf., MSWD=0.88）, corresponding to a Caledonian event. εHf（t） values are -13.3 to -9.7, indicating a crustal source. Two-stage Hf model ages are 1.7 to 1.9 Ga, suggesting that protolith of the migmates was probably formed in the Paleoproterozoic. The granodioritic neosomes have the characteristics of peraluminous calc-alkaline granite, and their REE patterns and trace elements spidergrams show features of middle to upper crustal rocks. Together with previous studies, we conclude that the protolith of the Cathaysia basement in the Tianjingping area was likely formed in the middle-late Paleoproterozoic and experienced partial melting during the Caledonian period. The recognition of Caledonian reworking of the Paleoproterozoic basement in the Cathaysia Block provides a new insight into the tectonic evolution of the Cathaysia Block in the Caledonian period and the interaction between the Cathaysia Block and the Yangtze Block.     

Mesoproterozoic age for Xiamaling Formation in North China Plate indicated by zircon SHRIMP dating

Zircon grains of magmatic origin from tuffite layers in the Xiamaling Formation at Zhaojiashan Village, Xuanhua area, Hebei Province, were used for zircon dating with a Sensitive High-Resolution Ion Microprobe （SHRIMP Ⅱ）, which gives a weighted mean ^207Pb/^206Pb age of 1366±9 Ma. It shows a very similar age （1368±12 Ma） as the zircon dating from the Xiamaling Formation in Western Hill, Beijing. This age proposes that the Xiamaling Formation in the North China plate should be of Mesoproterozoic, instead of Neoproterozoic based on K-Ar, Ar-Ar dating. The new zircon age also indicates the development of macrofossils algae from the Mesoproterozoic age.     

Permian volcanisms in eastern and southeastern margins of the Jiamusi Massif, northeastern China: zircon U-Pb chronology, geochemistry and its tectonic implications

LA-ICP-MS zircon U-Pb dating and geochemical data for the Late Paleozoic volcanic rocks from eastern and southeastern margins of the Jiamusi Massif are presented to understand the regional tectonic evolution. Zircons from eight representative volcanic rocks are euhedral-subhedral in shape and display striped absorption and fine-scale oscillatory growth zoning as well as high Th/U ratios （0.33-2.37）, implying a magmatic origin. The dating results show that the Late Paleozoic volcanic rocks in the study area can be divided into two stages, i.e., the Early Permian （a weighted mean 205^Pb/238^U age of 288 Ma） and the Middle Permian volcanisms （a weighted mean 205^Pb/238^U age of 268 Ma）. The former is composed mainly of basalt, basaltic-andesite, andesite and minor dacite. They are characterized by low SiO2 contents, high Mg^# （0.40-0.59）, enrichment in Na （Na2O/K2O = 1.26-4.25） and light rare earth elements （LREEs）, relative depletion in heavy rare earth elements （HREEs） and high field strength elements （HFSEs）, indicating that an active continental margin setting could exist in the eastern margin of the Jiamusi Massif in the Early Permian. The latter consists mainly of rhyolite and minor dacite with high SiO2 （77.23%-77.52%）, low MgO （0.11%-0.14%）, enrichment in 1（20 （Na2O/K2O ratios 〈 0.80） and Rb, Th, U and depletion in Eu, Sr, P and Ti, implying a crust-derived origin. Therefore, it is proposed that the Middle Permian volcanic rocks could have formed under the collision of the Jiamusi and the Khanka Massifs.     

Timing of the Wudangshan, Yaolinghe volcanic sequences and mafic sills in South Qinling: U-Pb zircon geochronology and tectonic implication

The Wudangshan, Yaolinghe volcanic-sedimentary sequences and doleritic-gabbroic sills comprise the largest exposed Precambrian basement in South Qinling. Zircons separated from 5 volcanic-pyroclastic samples of the Wudangshan Group, 2 volcanic samples of the Yaolinghe Group and one sample for the mafic sills were used for U-Pb dating by laser ablation-inductively coupled plasma mass spectrometry （LA-ICPMS）. The results reveal that the Wudangshan volcanic sequence was formed at （755±3） Ma （a weighted mean from the 5 samples, MSWD=0.47）, whereas the Yaolinghe volcanic suite and the mafic sill were crystallized at （685±5） （2 samples, MSWD=0.36） and （679±3） Ma （MSWD=1.6）, respectively, which are equal to each other within analysis errors. These ages are markedly younger than those previously documented for the rocks. The newly obtained ages for the Wudangshan and Yaolinghe Groups are Identical to those of the bottom Liantuo and slightly older than those of the Nantuo Formations, respectively, lower strata of the Nanhua （middle to late Neoproterozoic） stratotype section in eastern Three Gorges, Yangtze creton. A range of inherited magmatic zircons was recognized with ages of 830 to 780 Ma, which are typical of Neoprotzrozoic magmatisms recorded along the margins and interior of the Yangtze craton. Thus, there is Neoproterozoic basement comprising 830-780 Ma igneous suites in South Qinling; the inherited zircons were detrital sediments derived from the northern margin of the Yangtze craton. Accordingly, it is suggested that the South Qinling is a segment of the Yangtze creton before the Qinling Orogeny.     

Metallogenetic epoch and mechanism of the tungsten ore in Yushan,Beishan orogenic belt,Gansu

Using SHRIMP zircon U-Pb dating methods and cathodoluminescence （CL） technique, we have precisely dated ore samples from tungsten ore deposit, ore-bearing volcanic-sedimentary strata and granite in the Yushan region within the east Tianshan-Beishan W-bearing zone. This study reveals Yushan tungsten ore deposit zone formed in 250 ± 9 Ma, and it is closely associated with the Permian granites and felsic volcanic rocks. This new type of tungsten ore deposit in the east Tianshan-Beishang multiple-metallogenetic province may probably be associated with the regionally right-literal shearing after the main Carboniferous collisional orogeny, and the formation of pull-apart basin and the felsic magmatism.     

Lasing on pyroclastic rocks:A case study of ~(40)Ar/~(39)Ar dating on Moshishan Group,eastern Zhejiang Province

It is difficult to date pyroclastic rocks,for almost all the dating methods,due to the multiple sources during their formation.40Ar/39Ar incremental heating results on groundmass selected from the samples show that the age spectra are meaningless geologically.However,singe crystal total fusions of CO2 lasing on the sanidine separates could yield rational 40Ar/39Ar results and distinguish their sources in this study.Timing on three formations of the Moshishan Group,after avoiding the exotic and altered grains by lasing on the single sanidine separate,was reported in this paper.The lowermost portion of the Chawan Formation gives an age of 113.7±0.3 Ma;the lower part of the Xishantou Formation was formed 116.4±0.4 Ma ago and the bottom of the Gaowu Formation took its shape at 118.4±0.4 Ma.These new ages are much younger than the previous ones,suggesting that these thick volcanic formations had been formed in very short durations.     

大兴安岭柴河流纹质碎斑熔岩锆石U-Pb定年及成因探讨

为了研究大兴安岭柴河地区流纹质碎斑熔岩的形成时代和岩石成因,进行了锆石U-Pb同位素年龄测试和地球化学分析.LA-ICP-MS锆石U-Pb定年结果显示,柴河流纹质碎斑熔岩形成于年龄为135~138Ma的早白垩世。岩石地球化学研究表明,柴河流纹质碎斑熔岩具有高硅富碱、贫钙镁的特征;稀土丰度总量∑REE介于1501×10-6~1915×10-6,轻重稀土分馏明显,m(La)/m(Yb)N=118~1445,Eu负异常(δEu=059~075);微量元素以富集Rb,Ba,K,亏损Nb,P和Ti为特征,与I型花岗岩相似;碎斑熔岩原始岩浆来源于地壳岩石的部分熔融.