黑土水稳性团聚体测定方法研究

研究不同浸润方式、浸润时间和浸提剂对黑土水稳性团聚体总量和在各粒级间分布的影响，以及砾石对水稳性团聚体含量的贡献率。结果表明：非真空慢速浸润方式最适合黑土团聚体的测定；团聚体含量随浸润时间变化不显著；蒸馏水比自来水浸提出更多的团聚体；乙醇溶液对有机质含量较高的黑土保护作用不显著；黑土砾石含量较少，对团聚体含量的构成可以忽略。表4，参10。     

循环平稳性与随机共振理论的非绝热描述

噪声背景中周期信号的循环平稳性是信号处理中一个重要的特征.本文利用随机循环平稳过程的有关理论研究复杂随机动态系统中的随机共振现象.依据系统输出的一维准稳态概率密度近似理论,本文推导了系统输出二维跃迁概率密度、稳态自相关函数和系统输出信噪比的公式.输出信噪比随着输入噪声强度增加而呈现的随机共振现象,理论分析和数值试验结果非常吻合.此理论为随机共振理论的一种非绝热描述,不仅能够解释经典随机共振现象,而且能够描述驻留随机共振现象,对于复杂随机动态系统的信息处理机制具有重要理论指导意义.     

Enatioselective[2 2 2] Cycloaddition as A Synthetic Tool

1 Results Transition metal-catalyzed [2 2 2] cycloaddition is one of the most efficient protocols for the construction of six-membered ring system.Our group has comprehensively studied various types of highly enantioselective [2 2 2] cycloaddition for the synthesis of chiral cycloadducts; we already reported an iridium-catalyzed intermolecular [2 2 2] cycloaddition between α,ω-diynes,having various tethers and substituents on the alkyne termini,and monoalkynes,possessing oxygen or/and nitrogen functiona...     

Dipiphosphinoazines-from Rich Coordination Variability to Catalysis

1 Results Diphosphinoazines are very versatile,potentially up to tetradentate ligands,known to form complexes with many transition metals.Recently,we developed synthesis of diphosphinoazines with various substituents on phosphorus donor atoms.This fine tuning allowed to design novel catalytic systems for several organic reactions.Hydroamination of Michael-type substrates with selected primary and secondary amines revealed the reactivity of some amines in non-catalyzed reaction.Hydroamination of methyl m...     

多体互作用对13-原子团簇相变特性的影响

采用M.I.Baskes的Lennard-Jones Embedded-Atom(LJ-EMA)势作为原子之间的互作用,结合常能分子动力学模拟,计算了13-原子团簇的热曲线、方均根键长起伏、比热、动能的短时平均、位移平方的平均、其它12个原子相对于中心原子的角分布函数,着重地计算了相变区域的情形,对团簇融化-凝固相变特性进行了较为详细的研究,得出多体作用力的大小增加、范围减小导致融化温度(动能)的降低和共存区域范围变小的结论;证实了在一定的总能范围内类固(solidlike)和类液(liquidlike)两类特性团簇的共存;进一步明确了两步过程(表面融化)的成因;观察到在三种较大多体互作用范围势的情况下,出现负比热;进一步揭示了热曲线斜率、方均根键长起伏、比热和动能的短时平均分布之间的关联。     

Transitional phenomenon of particle dispersion in gas-solid two-phase flows

Without using any turbulent model, direct numerical simulation of a three-dimensional gas-solid two-phase turbulent jet was performed by finite volume method. The effects on dispersion of particles with different Stokes numbers by the transitional behavior of turbulent structures were investigated. To produce high-resolution results and reduce the computation and storage, the fractional-step projection algorithm was used to solve the governing equations of gas phase fluid. The low-storage, three-order Runge-Kutta scheme was used for time integration. The governing equations of particles were solved in the Lagrangian framework. These numerical schemes were validated by the good agreement be-tween the statistical results of flow field and the related experimental data. In the study of particle dis-persion, it was found that the effects on particle dispersion by the spanwise vortex structures were prominent. The new behaviors of particle dispersion were also observed during the evolution of the flow field, i.e. the transitional phenomenon of particle dispersion occurs for the particles with small and intermediate Stokes numbers.     

变频调速技术在细纱机恒张力控制中的应用

根据纱线长度，用变频器控制细纱机主轴转速，设计了纺纱过程中纱线恒张力控制．程序按照状态变化进行设计开发．实验结果表明，该设计达到设计要求．其产品已投入批量生产．     

体心立方过渡金属低指数表面单空位的改进分析型嵌入原子法模拟

应用改进分析型嵌入原子法(modified analytical embedded-atom method,MAEAM),计算了7种体心立方(body-centered cubic,BCC)过渡金属Fe、W、Mo、Cr、Ta、Nb和V等低指数(100)、(110)和(111)表面前9层上的单空位形成能.结果表明,对每一种金属,单空位形成能在同一低指数表面层中的第1层最低,且在表面第1层和第2层(Nb除外)随表面原子密度的减小而降低,即E(11f11),1相似文献   

开放性边界条件下优先随机慢化对交通流的影响

NaSch模型是一种描述单车道高速公路交通的概率性元胞自动机,但它不能再现实际交通中出现的同步流现象.研究表明:改变NaSch模型的基本演化次序后,开放性边界系统在高产生概率和高消失概率这两种情形下出现低速的同步相,减小了追尾事故发生的可能性,提高了道路的通行能力.计算机模拟的结果显示了同步流、启止坡、非平衡相变等实际交通所具有的特性.     

Formation of ζ phase in Cu-Ge peritectic alloys

Rapid growth behavior of ζ phase has been investigated in the undercooling experiments of Cu-14%Ge, Cu-15%Ge, Cu-18.5%Ge and Cu-22%Ge alloys. Alloys of the four compositions obtain the maximum undercoolings of 202 K（0.17TL）, 245 K（0.20TL）, 223 K（0.20TL） and 176 K（0.17TL）, respectively. As the content of Ge increases, the microstructural transition of ＂a（Cu） dendrite ＋ ζ＂ peritectic phase → ζ＂ peritectic phase →, ζ dendrite ＋ （ε＋ζ） eutectic＂ takes place in the alloy at small undercooling, while the microstructural transition of ＂fragmented α （Cu）dendrite ＋ ζ peritectic phase →, ζ peritectic phase →ζ dendrite ＋ ε phase＂ happens in the alloy at large undercooling. EDS analysis of the Ge content in peritectic phase indicates that undercooling enlarges the solid solubility of ζ rdendrite, which leads to a decrease in the Ge content in ζ phase as undercooling increases. In the Cu-18.5%Ge alloy composed of ζ peritectic phase, the Ge content in ζ phase increases when undercooling increases, which is due to the restraint of the Ge enrichment on the grain boundaries by high undercooling effect.