Pulse radiolysis studies of functionally substituted imidazolium-based ionic liquids

The reactions of imidazolium-based ionic liquids having different substituent groups on the ring with hydrated electrons (eaq-),hydroxyl radicals (·OH),and sulfate anion radicals (SO4·-) were investigated using nanosecond pulse radiolysis techniques.The spectra of these ionic liquids on reaction with eaq-all exhibited a similar peak at about 320 nm,and a typical peak for eaq-in aqueous ionic liquid solutions.The reaction rate constants for 1,3-disubstituted imidazolium-based ionic liquid hexafluorophosphates (BMIPF 6) with eaq-were deduced to be 10 10 L mol-1s-1,however the values were lower for trisubstituted ionic liquids.For example,the rate constant for 1-butyl-2,3-dimethylimidazolium tetrafluoroborate (BMMIBF 4) was 5.5×10 9 L mol-1s-1.Imidazolium-based ionic liquids reacted with hydroxyl radicals via adducts to produce a mixture of isomeric OH adducts,and the pk a value of the OH adducts was deduced to be 8.4±0.4 for 1-butyl-3-methylimdazolium tetrafluoroborate (BMIBF 4).Moreover,imidazolium cations were also oxidized by SO4·-to produce bivalent cation radicals,which exhibit a peak at 320 nm,and these rate constants are of the same order of magnitude,i.e.,10 9 L mol-1s-1,except that for 1-(2-hydroxyethyl)-3-methylimdazolium tetrafluoroborate with SO4·-(k=2.8×10 8 L mol-1 s-1).Theoretical calculations were carried out to estimate the structures of the products of reduction by eaq- and the results were related to the experimental data.     

Attenuation of ultraviolet radiation reaching the surface due to atmospheric aerosols in Guangzhou

The UV attenuation due to atmospheric aerosols in Guangzhou was quantitatively assessed using surface ultraviolet radiation (UV,295-385 nm) observation,sun photometer and radiation models.Observations showed that the annual average value of aerosol optical depth (AOD) was 1.19 in UV spectral region of 340 nm,the annual average occurrence frequency of aerosol optical depth AOD 340 nm >1.0 was 55%,and the annual average attenuation rate of surface UV direct radiation of 340 nm was 68%.It was proven in the observation of surface UV radiation and model evaluation that annual average attenuation of UV due to atmosphere was 75%,and that reached 72% in the dry season (October,November,December and January);while average attenuation of UV due to atmospheric aerosols reached 62% in the dry season.It was indicated that very significant UV attenuations due to atmospheric aerosols existed in Guangzhou urban agglomeration,and at least half of UV radiation was attenuated due to atmospheric aerosols.Such large-amplitude attenuation will have a significant impact on urban ecosystem and species chemical cycles,especially photochemical reaction processes.     

钢丝磨削试验研究

砂带磨削作为一种新工艺,在机械加工领域发挥着越来越大的作用,满足了各种加工要求。本文简单介绍了砂带磨削的概念,阐述了一个针对钢丝表面除锈的新型砂带磨削设备的工作原理及其机床的主要机构,并通过试验研究磨削压力、金属去除率、砂带磨损、磨削比、磨削深度、钢丝走速之间的关系,为砂带修磨线材生产线提供了合理的磨削工艺参数。     

应用导风板提高循环区有效风量率的分析研究

矿山应用受控循环通风技术的目的在于有效提高工作面的有效风量,进行了应用导风板提高循环区有效风量率的研究,通过研究表明:在循环横巷出风口处安设引导风流的导风板,使循环风流面向回采工作面,背向外来新鲜风流,利用风流动压方向性,使循环风流最大限度地流向工作面,达到了导风板应用的目的.     

基于M／G／1排队模型的业务流性能研究

针对无线传感器网络可能存在的拥塞问题,提出了一种新的业务流性能刻画方法．利用M／G／1排队模型建立了一步转移概率矩阵,在先来先服务策略的基础上推导了业务流的队列长度和等待时间的数学表达式,通过仿真实验分析了当服务源分别服从定长分布和后阶Erlang分布时,系统的等待时间与服务率、到达率之间的关系．结果表明,等待时间与到达率成正相关,与服务率成负相关,并且对k阶Erlang分布的影响更大．     

基于随机补货间隔和非线性变质率的易腐商品补货模型

研究了一类需求率随价格变动、有一定保鲜期的易变质商品的随机补货间隔的多周期补货策略.变质率是非线性的时变函数,补货间隔是随机变量.针对补货间隔的密度函数是一个区间上的均匀分布情形,构建了以补货水平为决策变量的补货优化模型,利用Matlab求出极值优化解.并给出了算例和补货间隔的灵敏度分析.算例表明由于商品存在保鲜期,保鲜期后有变质损失,取最优解时经常会出现商品有出空现象,为了提高顾客需求满足率,可以缩短补货间隔,减少商品空缺期.该模型为配送中心的配货决策和商场的补货策略提供了一种决策方法.     

多核平台的并行实时调度与内存分配算法

多核处理器凭借着低功耗高性能的优势占据了市场.针对多核平台上并行实时任务,提出局部与全局EDF相结合的调度算法,其中任务的截止期划分、执行预算以及迁移时机由所设计的处理器带宽预留服务器决定.同时,提出了内存分配算法,该算法能够更好地为并行实时任务管理内存资源.实验结果表明新的调度算法具有更高的调度成功率.另外,在内存资源竞争的前提下,内存分配算法可以保证并行任务的实时性与系统稳定性.     

改进流通服务工作 提高文献利用率——基于浙江财经学院图书馆流通数据统计分析的思考

文献利用率是衡量高校图书馆服务质量的重要依据。对浙江财经学院图书馆2005—2010年的流通服务数据进行了统计分析,就如何提高文献利用率、改进流通服务工作进行了探讨。     

Superplastic Behavior and Deformation Mechanisms of AI-12.7Si-0.7Mg Alloy

对Al-12.7Si-0.7Mg合金在Instron5500电子万能材料试验机上进行超塑性拉伸实验.通过对该合金超塑性过程中延伸率δ,应变速率敏感性指数m值的计算,获得了不同变形温度、不同应变速率下δ和m值的变化规律.该合金在温度为793 K,应变速率为1.67×10-4s-1时,合金的应变速率敏感性指数和延伸率均达到最大值,分别为0.44,379%.分别构建了该合金的功率耗散率图以及铝合金RWS变形机理图.运用功率耗散率图预报该合金的超塑性变形区域;应用铝合金变形机理图并结合该合金超塑性拉伸前后显微组织变化规律,根据不同温度下Al-12.7Si-0.7Mg合金柏氏矢量补偿的晶粒尺寸值、模量补偿的应力值预报该合金的超塑性拉伸变形机理.     

对南京师范大学自然地理学博士学位论文引文的分析与研究

以2002—2011年南京师范大学自然地理学34篇博士学位论文作为统计源,采用文献计量学方法,得出中文与外文引文量大体相当,引文类型主要为期刊与图书,引文中期刊、会议论文及专著中外文相当,中外文文献均具有一定时长的使用时效,中外文引文有向核心期刊集中的效应等规律,并提出了改进图书馆文献资源建设的建议。