Fabrication of bulk glassy Zr41Ti14Ni8Cu12.5Be22.5Fe2 alloy by water quenching

A glassy Zr41Ti14Ni8Cu12.5Be22.5Fe2 rod with a diameter of 9 mm was successfully produced by water quenching.The effects of iron addition on thermal stability and hardness of Zr41Ti14Ni8Cu12.5Be22.5Fe2 bulk amorphous alloy were investigated by XR D,DSC and microhardness test.It is found that the full annealing would enhance the strength of the alloy significantly.The cause of the increase in hardness was analyzed and the formation mechanisms of the bulk amorphous alloy are discussed.     

Mg-2.4Nd-0.5Sr-0.3Zr生物镁合金表面耐蚀抑菌层的制备与表征

以AgNO_3溶液为介质,采用水热法在Mg-2.4Nd-0.5Sr-0.3Zr生物镁合金表面制备具有抗菌性能的耐蚀膜层,通过XRD、SEM、EDS等技术,对不同水热温度及时间条件下所制膜层的形貌及物相结构进行表征,结合电化学测试及抑菌试验,考察了水热条件对膜层耐蚀性和抗菌性能的影响。结果表明,Mg-2.4Nd-0.5Sr-0.3Zr合金表面膜层主要由层片状Mg(OH)_2和颗粒状Ag/Mg(OH)_2聚集混合组成,随着水热温度的升高及反应时间的延长,膜层厚度逐渐增加。电化学测试结果显示,膜层能有效改善合金的耐蚀性,且随着表面膜层厚度的增加,对应合金样品的耐蚀性增强。此外,经过水热处理制得的合金样品在金色葡萄球菌培养24h后,产生了明显的抑菌圈,表现出了良好的抗菌效果。     

Microstructure,mechanical properties and formability of friction stir welded dissimilar materials of IF-steel and 6061 Al alloy

AA 6061 alloy and interstitial-free(IF)steel plates were joined by the friction stir welding(FSW)method,and the microstructure,mechanical properties,and biaxial stretch formability of the friction stir welded(FSWed)parts were investigated.The results indicate that the FSWed parts showed optimum tensile strength during FSW with the 0.4-mm offset position of the tool.The Fe4Al13 intermetallic compound formed in the defect-free intersection of AA 6061 and IF-steel plates during FSW.The hardness of the IF-steel part of the FSWed region increased almost 90%relative to its initial hardness of HV0.2 105.The tensile and yield strengths of FSWed regions were approximately 170 MPa and 145 MPa,respectively.According to the formability tests,the Erichsen Index(EI)of the IF-steel,AA 6061,and the FSWed samples were determined to be 2.9 mm,1.9 mm,and 2.1 mm,respectively.The EI of the FSWed sample was almost the same as that of the AA 6061 alloy.However,it decreased compared with that of the IF-steel.The force at EI(FEI)was approximately 1180 N for the FSWed condition.This value is approximately 70%higher than that of AA 6061 alloy.     

钛铁合金所含杂质对 Ti-IF 钢洁净度的影响

通过氧氮分析、SEM和EDS对Ti‐IF钢冶炼过程不同阶段钢液及铸坯进行分析,研究钛铁合金所含杂质对Ti‐IF钢洁净度的影响。结果表明,Ti‐IF钢冶炼过程添加FeTi70时,RH出站处钢液中的平均氮含量较添加FeT i30时增加值为8．86×10－6,铸坯平均氮含量较添加FeT i30时增加值为10．83×10－6,这是由于所用FeTi70合金中T（O）、N含量较高,这些在RH冶炼过程中较难去除的 O、N元素形成尺寸不同的含氧夹杂,其结果降低了T i‐IF钢洁净度。     

碳纤维布加固铝合金连接试验

铝合金材料的可焊性较差,焊接热影响区强度降低显著,用碳纤维布加固铝合金是一种有效的措施.为此探究了碳纤维布与铝合金间的黏结性能,完成2批共计37个碳纤维布加固铝合金双搭接节点试验,研究了碳纤维布黏结长度、宽度、层数、碳纤维布材料以及黏结构造等对黏结效果的影响.总结了碳纤维布加固铝合金双搭接节点的破坏模式和破坏机理,得到碳纤维布的应力应变分布规律,提出了双搭接节点的有效黏结长度和承载力实用计算公式.     

Effect of thermal exposure on the stress-rupture life and microstructure of a low Re-containing single crystal alloy

In this paper, the stress-rupture tests of a low Re-containing single crystal alloy IC21 before and after thermal exposure at 1100 ℃for various periods of time were conducted under the test condition of 1100 ℃/137 MPa, and the microstructure of the tested specimens was characterized by SEM and TEM. The experimental results showed that the stress rupture life of this alloy was over 150 h after the standard heat treatment of1320 ℃, 10 h/AC t 870, 32 h/AC, however the stress rupture life decreased with the increase of exposure time due to the microstructure degradation. The TEM analysis revealed that the interface mismatch dislocation networks were well established. It was observed that these mismatch networks could form at 1100 ℃ even after thermal exposure for 1 h without the external stress, which is quite different from that in the traditional single crystal superalloys.     

Prediction of hot deformation behavior in Ni-based alloy considering the effect of initial microstructure

High temperature heat treatments were conducted for as-cast N08028 alloy to obtain various microstructures with different amounts of σ-phase,and then hot compression tests were carried out using Gleeble-3500 thermo-mechanical simulator in deformation temperature range from 1100 to1200 ℃ and strain rate range from 0.01 to 1 s-1. For the same initial microstructure, the flow stress was observed to increase with increasing the strain rate and decreasing the deformation temperature, while for the same deformation condition, the flow stress was found to increase with increasing the amount of σ-phase in the initial microstructure. Moreover, dynamic recrystallization was found to be the main dynamic soften mechanism. On this basis, Arrhenius-type constitutive equations and artificial neural network(ANN) model with back-propagation learning algorithm were established to predict hot deformation behavior of the alloy. Furthermore, the parameters of constitutive equations were found to be dependent on the initial microstructure, which was also as one of the inputs for the ANN model. Suitability of the two models was evaluated by comparing the accuracy, correlation coefficient and average absolute relative error, of the prediction. It is concluded that the ANN model is more accurately than the constitutive equations.     

Hot deformation behavior and the processing map of Zr–1.0Be alloy in single α phase

The hot deformation behavior,hot workability and dynamic recrystallization evolution of Zr-1.0(wt%) Be alloy in single a phase were investigated by conducting hot compression tests.The strain rates ranging from 10~(-3) s~(-1) to 10° s~(-1) and testing temperatures varying from 650 ℃to 850℃ were used.Flow stress was found to increase with increasing strain rate and decrease with the increment of the deformation temperature.A constitutive equation of flow behavior was established to describe the dependence of flow stress on strain rate and deformation temperature.The activation energy for deformation of Zr-1.0Be alloy was determined to be Q= 301 kJ/mol.The processing map of Zr-1.0Be alloy was constructed at strain rates ranging from 10~(-3) s~(-1) to 10° s~(-1) and deformation temperatures varying from 650 ℃ to 850 ℃ at the true strain of 0.7.A processing map was used to identify the best domains of thermal processing,including a domain at a temperature of 650 ℃ and strain rate of 10~(-3) s~(-1) as well as another domain at deformation temperatures ranging from 800 ℃ to 850 ℃ and strain rates varying from 10~(-3) s~-~(-1) to 10~(-1) s~(-1).Microscopic analysis of Zr-l.OBe alloy showed that the flow instability and kink were very obvious at low temperatures and high strain rates.At high temperatures and low strain rates,the dynamic recrystallization became the main softening mechanism during hot working.     

基于ANSYS有限元的Ag-Cu-Ti合金钎焊金刚石磨粒残余应力分析与优化研究

研究金刚石包埋深度分别为20%、40%、50%、60%、80%的钎料对单层钎焊金刚石工具性能的影响。利用有限元软件ANSYS对Ag-Cu-Ti合金钎焊金刚石过程中形成的残余应力进行数值模拟,采用线性和静态的分析方法。研究结果表明,最大应力值位于金刚石和钎料界面结合处的最底部,应力从金刚石底部到顶部逐渐减小,金刚石受拉应力,钎料和工具基体受压应力。当金刚石的包埋深度介于20%与40%之间时,钎焊残余应力最小。     

镁合金薄带双辊铸轧过程的数值模拟

基于立式薄带双辊铸轧工艺的特点,采用有限元法求解镁合金薄带双辊铸轧过程的三维宏观传输方程,并应用ANSYS软件的智能网格划分技术,实现了对铸轧过程中熔池内部温度场、速度场及凝固过程的耦合模拟.分析了铸轧速度及浇注温度等主要工艺参数对熔池内流场、温度场和凝固终了点的影响规律.研究结果表明,随着浇注温度和铸轧速度的增加,熔池出口处的温度升高,凝固终了点向熔池出口处移动.通过对模拟结果的讨论,给出了适合镁合金薄带铸轧过程的工艺参数:浇注温度为640~660℃,铸轧速度为20~30 m/min.