_1~2H~*-e 接触俘获与_1~2H-_0~2N 聚变(冷聚变探索(Ⅱ))

本文在分析研究冷聚变基础上提出一个_1~2H-_0~2聚变的理论模型,并讨论了电解池中某些聚变效应,氘核对钯晶中电子接触俘获的条件以及双中子态的质量和结合能.作者进一步给出氚产额和骤发中子群的两个表达式,并利用理论结果解释了氘核-氘核聚变框框中不能理解的一些实验现象.     

新N4型酒石酸酰胺配体的合成、标记及其生物分布研究

以L(+)-酒石酸为原料,设计、合成了R,R构型的2种N4型配体以及99mTc的配合物,它们均为光化学纯结构,化合物通过了IR,1HNMR, 13CNMR及元素分析的测试. 进行了99mTc的标记,动物实验结果表明,2个目标物的99mTc标记配合物在小鼠肾中有较高的初始摄取量,尤其是N, N-二乙基酒石酸二乙二胺99mTc-配合物不仅有较高的肾摄取,且有较长的滞留时间,肾与血的活度比高,有望发展成为一种新的肾功能显像剂.     

用中子飞行时间分析氢同位素深度分布

论述了一种注入或者吸附在材料中的氚和氘的深度分布的测量方法.样品为氚(钛)靶和氘(钛)靶.用2MeV入射质子束,T(p,n)反应研究氚的深度分布;用1MeV入射氘束,D(d,n)反应研究氘的深度分布.用标准的飞行时间方法测量中子能谱。由中子能量确定起反应的质子或氘核的能量。进而得出氚或者氘在钛层中的深度分布.本方法的灵敏度可达0.1at.％.对氚(钛)靶,当靶厚为5mg/cm~2时,深度分辩好于0.5mg/cm~2.     

Photopromoted carbonylation of olefins with carbon dioxide and labelling studies with ^13CO2 and ^13CH3OH

Photopromoted carbonylation of olefins with carbon dioxide can be completed in ambient conditions (room temperatures and atmospheric pressure) by Co(OAc)2 catalysis. It was found that in carbonyl carbons of methyl ester of aliphatic acid 50% is from CO2 and the other 50% from CHsOH by labelling experimental with ^13CO2 and ^CH3OH.     

一类二部图的(d,1)-全标号

图G的一个k-(d,1)-全标号是一个映射f:V(G)∪E(G)→｛0,1,2…,k｝,使得(1) 相邻的顶点标不同的号;(2) 相邻的边标不同的号;(3) 顶点与所关联的边标号数相差至少为d (d≥2)。图G的(d,1)-全标号数定义为G有一个k-(d,1)-全标号的最小的k值。给出了一类二部图的(d,1)-全标号数。     

Evidence for tritium production in the Earth’s interior

We have made a new investigation on the vertical profiles of tritium and helium isotopes in Lakes Van and Nemrut （Eastern Turkey）, using experimental data from the reference by Kipfer et al. for study of long-term vertical mixing and deep water renewal in Lake Van. Lakes Van and Nemrut are crater lakes. Lake Nemrut is at the western border of Lake Van. The ^3He and ^4He are injected at the bottom of Lakes Van and Nemrut, and the both helium isotopes are confirmed from the mantle source. From ^3H （tritium） data in Lakes Van and Nemrut, we have observed ＂^3H anomaly＂ at the vertical profile of ^3H concentrations in Lake Nemrut. The ^3H concentration at the lake bottom is 10% higher than at the surface. The difference of ^3H concentrations between surface and bottom is about 3.7±1.2 TU. This excess ^3H should be injected from the lake bottom. An investigation on the origin of the injected tritium has been made. The results show the conventional origins are excluded, such as residence of precipitation tritium from nuclear testing in the early 1950s--1960s and tritium from known nuclear reactions. Based on the correlation of excess ^3H with ^3He and heat flow in Lake Nemrut, we infer that the ^3He and ^3H might be all from the mantle source, and produced by the supposed natural-nuclear-fusion, which might occur in an environment rich in water （H） and （U ＋ Th） at high temperature and high pressure in the deep Earth. Detection of tritium in the Earth＇s interior is a key evidence for exploration of natural nuclear fusion in the deep Earth. Based on the published data, we have found that the excess ^3He and ^3H injected at the bottom of Lake Laacher （Germany） were also released from the mantle source. The present work will be helpful to the further study of mechanism of natural nuclear fusion in the Earth＇s interior.     

CECE法重水电解分离氚的热力学研究

文章研究了CECE法中D2-含氚重水同位素交换以及电解的热力学问题,即可逆分解电压和2个反应(19-1) 和(19-2)的热力学平衡条件。研究给出了H2O, HDO, D2O, DTO和T2O的可逆分解电压。H2O(0) 与T2O(4)的可逆分解电压的相差为0.047 V,如要保留T2O,则实际的分解电压不能大于H2O的分解电压。同时,导出了这5种氢同位素水的平衡蒸汽压和汽化热与温度(0～100 ℃)的函数关系。从热力学来讲,反应(19-1)和(19-2)的平衡常数都很小,在静态反应中难以实现,如果在流动系统中,则能符合条件Q < K,使反应进行。电解分离氢同位素水的最大的难点是选择性差,可以探索使用光催化分离的方法。     

路与扇形图联图的(2,1)-全标号

图G的一个k-(2,1)-全标号是一个映射f:V(G)∪E(G)→{0,1,2,…,k},使得(1)相邻的顶点标不同的号,(2)相邻的边标不同的号,(3)顶点与所关联的边标号数相差至少为2.图G的(2,1)-全标号数定义为G有一个k-(2,1)-全标号的最小的k值,记为λT2(G).根据路与扇图联图的特点,找到一种特殊的标号方法,给出路与简单扇图联图的(2,1)-全标号数的上界.     

中国氦冷固态试验增殖模块(CH HCSB BT-TBM)产氚优化

借助一维中子输运计算程序ONEDANT对ITER实验包层模块(TBM)设计的产氚问题进行了计算分析与优化设计,基于初始的模块结构设计,首先计算出不同材料区的产氚增值比和能量密度分布,改变不同材料区的氚增值材料后,进行中子学计算和分析,最后得到最佳的氚增殖材料分布和产氚分布等参数。     

大鼠胰岛β细胞胰岛素分泌颗粒上Ⅲ型IP3受体的免疫电镜定位分析

研究Ⅲ型1,4,5三磷酸肌醇受体(IP3R-Ⅲ型)在大鼠胰岛β细胞胰岛素分泌颗粒上的定位.利用免疫电镜技术,5nm胶体金标记IP3R-Ⅲ型抗原后定位观察其分布情况.实验表明在胰岛β细胞中,金颗粒大量定位于胰岛素分泌颗粒的内部及颗粒膜上.在分泌颗粒表面的切线部位,也有金颗粒的聚集.本研究证明胰岛素分泌颗粒存在IP3R-Ⅲ型,提示IP3-IP3R3型可能参与了β细胞胰岛素分泌的调节.