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141.
The relaxation of the highly vibrationally excited CO (v = 1–8) by CO2 is studied by timeresolved Fourier transform infrared emission spectroscopy (TR FTIR). 193 nm laser photolysis of the mixture
of CHBr3 with O2 generates the highly vibrationally excited CO(v) molecules. TR FTIR records the intense infrared emission of CO(v→v-1). The
vibrational populations of each level of CO(v) have been determined by the method of spectral simulation. Based on the evolution
of the time resolved populations and the differential method, 8 energy transfer rate constants of CO(v = 1–8) to CO2 molecules areobtained: (5.7±0.1), (5.9±0.1), (5.2±0.2), (3.4±0.2), (2.4±0.3), (2.2±0.4), (2.0±0.4) and (1.8±0.6) (1014 cm3 · molecule−1 · s−1), respectively. A two-channel energy transfer model can explain the feature of the quenching of CO(v) by CO2. For the lower vibrational states of CO, the vibrational energy transfers preferentially to the u3 mode of CO2 For the higher levels, the major quenching channel changes to the vibrational energy exchange between CO(v→v-1) and the u1 mode of CO2. 相似文献
142.
The range and the nonextinction property of a supercritical superdiffusion and solutions of its corresponding differential
equation are studied. It is pruved that under a suitable condition, the conditioned superprocess of the supercritical superdiffusion
is a subcritical superdiffusion. 相似文献
143.
The vibrational energy transfer from highly vibrationally excited CO to H2O molecules is studied by time-resolved Fourier transform infrared emission spectroscopy (TR FTIR). Following the 193 nm laser
photolysis of CHBr3 and O2 the secondary reactions generate CO(v). The infrared emission of CO(v → v−1) is detected by TR FTIR. The excitation of H2O molecules is not observed. By the method of the spectral simulation and the differential technique, 8 rate constants for
CO(v)/H2O system are obtained: (1.7 ±0.1), (3.4 ±0.2), (6.2 ±0.4), (8.0 ±1.0), (9.0 ±2.0), (12 ±3), (16 ±4) and (18 ±7) (1013cm3 · molecule-1· s-1). At least two reasons lead to the efficient energy transfer. One is the contributions of the rotational energy to the vibational
energy defect and the other is the result of the complex collision. With the SSH andab initio calculations, the quenching mechanism of CO(v) by H2O is suggested. 相似文献
144.
The effect of lanthanum ions on the structural and conformational change of yeast tRNA Phe was studied by 1H NMR. The results suggest that the tertiary base pair (G-15)(C-48), which was located in the terminal in the augmented dihydrouridine helix (D-helix), was markedly affected by adding La 3+ and shifted 0.33 downfield. Based pair (U-8)(A-14), which is associated with a tertiary interaction, links the base of the acceptor stem to the D-stem and anchors the elbow of the L structure, shifted 0.20 upfield. Another imino proton that may be affected by La 3+ in tRNA Phe is the tertiary base pair (G-19)(C-56). The assignment of this resonance is tentative since it is located in the region of highly overlapping resonances between 12.6 and 12.2. This base pair helps to anchor the D-loop to the TΨC loop. 相似文献
145.
在一定条件下,研究了一类二阶非线性微分方程解的性质,分析了其解的单调性、振动性以及其解有界的充分必要条件,并讨论了其解在单调有界的条件下当t→+∞时的渐近性质。 相似文献
146.
从能斯特方程出发,考虑到国产CNa电极的离散性,给出实用的数学模型,并用MCS-51单片机构成高性能价格比的微量钠离子检测仪。 相似文献
147.
以圆周为界面两相材料多裂纹反平面问题 总被引:1,自引:0,他引:1
运用复变函数及积分方程方法,求解了以圆周为界面的两相材料中的多裂纹反平面问题.为解决该问题,建立了两种类型的基本解,分别对应于单裂纹在圆域内和圆域外的情形.利用叠加原理和所得的基本解把两相材料中的多裂纹问题化为单裂纹问题的叠加,得出了一组以基本解密度函数为未知函数的Fredholm积分方程组.通过对该积分方程组的数值求解,可以得出密度函数的离散值,进而得出裂纹尖端的应力强度因子.文中对于两条裂纹分别位于圆域内和圆域外以及两条裂纹均在圆域外的情形进行了数值计算. 相似文献
148.
In this paper, the integrals appeared in BEM model for Poisson equation are all implemented analytically. Wherein, the boundary
and the domain are discretized by linear boundary elements and linear internal triangle cells respectively. The closed formulations
for all integrals are presented so that the computer effort for numerical solution is reduced considerably with higher accuray.
The numerical example shows that the results are more accurate in comparision with Gaussian integration in the same discrezition.
The basic idea of this paper could be extended to BEM model for Helmholtz equation and/or the time-dependent second other
differential equations.
Supported by the National Natural Science Foundation of China
Tang Shaowu: born in 1971, Ph. D. 相似文献
149.
关于时滞Liénard型方程的周期解 总被引:1,自引:0,他引:1
本文研究具有时滞的Lienard型方程周期解的存在性,得到了一些新的结果。 相似文献
150.
应用分层理论证明了二维Navier-Stokes方程的c^2不稳定性,并给出了重要例证分析。 相似文献