引用次序对类目体系建立的影响

复合主题的文献在进行信息标引的时候,按照不同的标引次序所组成的类目体系是不相同的,因而也就造成检索结果的不同。通过分析采用不同引用次序对建立类目体系的影响,从而得出根据不同的需要采用相应的引用次序。     

21～30阶群嵌入置换群的一些讨论

本文主要讨论了21阶到30阶的群到置换群的最小嵌入，并讨论了最小嵌入的个数及共轭类划分，并且最终得到了所有的结果．     

硫酸钛为钛源制备二氧化钛的实验条件研究

实验以硫酸钛为钛源、尿素为沉淀剂、聚乙二醇600为分散剂,采用均匀沉淀法制备二氧化钛粉末。主要讨论了影响沉淀形成时间的主要因素:尿素的用量及加入方法、聚乙二醇的用量、以及水浴的温度等。实验结果表明,以硫酸钛为钛源、尿素为沉淀剂、聚乙二醇600为分散剂,采用均匀沉淀法制备二氧化钛粉末最佳反应条件为:在水浴加热343 K条件下,将尿素缓慢滴加到硫酸钛和聚乙二醇600的混合液中,硫酸钛和聚乙二醇600的混合液在磁力搅拌器搅拌时滴加尿素,用硫酸调节pH在1.5~2,保持硫酸钛、尿素和聚乙二醇600的摩尔比1∶12∶0.01。     

一种有效估计着陆引导信号多径时延的方法

利用导航信号收发已知且具有周期性的特点,提出了一种对着陆引导信号多径时延进行有效估计的方法。该方法首先计算相关函数,而后对相关函数进行二次微分,对时延值进行初步估计。最后通过直线拟合算法和比例拟合算法提高估计精度。通过计算机仿真,验证了算法的有效性。该算法具有在低采样率的条件下,估计精度高的特点。     

炼钢厂连铸机的开浇时间决策优化模型

针对炼钢厂连铸机开浇时是否连浇以及开浇时间确定等问题,从钢厂生产线上待加工的铁水/钢水金属资源平衡的角度,建立了以连铸生产总效益最大为目标函数的连铸机开浇决策的混合整数规划模型,并用基于MATLAB软件的YALMIP优化工具进行模型的求解.针对某钢厂的实际情况进行模型的应用测试,结果表明:模型可以优化决策连铸机各浇次的开浇时间,有助于编制合理的炼钢厂生产调度作业计划,稳定各班次之间的生产条件,降低生产线上的积压金属量,为炼钢厂连铸机的有序开浇提供了技术手段.     

基于瞬时铣削力的球头铣刀铣削力系数辨识

面向多轴铣削加工的铣削力预测,提出了基于瞬时铣削力的球头铣刀铣削力系数辨识方法.首先建立了铣削过程中刀具的瞬时坐标系来准确描述多轴加工中刀具的位置和位姿,在此基础上建立了球头铣刀任意位置和位姿的通用铣削力模型,即建立了铣刀刀刃微元的切削弧长,刀刃微元的切削宽度和瞬时未变形切削厚度的数学模型.然后根据铣削力模型推导了基于瞬时铣削力的铣削力系数辨识模型.最后通过铣削力系数辨识实验和铣削力仿真计算,验证了方法的正确性和可靠性.     

Atomic layer deposition on Pd nanocrystals for forming Pd-TiO2 interface toward enhanced CO oxidation

Pd typically exhibits relatively low catalytic activity in CO oxidation, as CO is apt to be adsorbed on Pd to poison the surface for O2 activation. In this Letter, we report that this limitation can be overcome by integrating Pd with TiO2. The TiO2 was coated on Pd nanocubes with a controllable thickness using atomic layer deposition (ALD) method. Given the different work functions of TiO2 and Pd, the electrons in TiO2 semiconductor will flow toward Pd. With the electron density increased on Pd, the adsorption of CO to Pd will be weakened while the oxygen activation can be facilitated. Meanwhile, the interface-confined sites at Pd-TiO2 may further enhance the oxygen activation. As the species adsorption and activation are strongly correlated with electron density, the performance of Pd-TiO2 in CO oxidation turns out to depend on the TiO2 thickness, which determines the number of transferred electrons, within a certain range (<1.8 nm). This work provides a new strategy for enhancing catalytic performance through tailoring charge densities in hybrid catalysts.     

Alternative synthetic route for the heterometallic CO-releasing [Sb@Rh12(CO)27]3− icosahedral carbonyl cluster and synthesis of its new unsaturated [Sb@Rh12(CO)24]4− and dimeric [{Sb@Rh12Sb(CO)25}2Rh(CO)2PPh3]7− derivatives

The evolution of the optical absorption spectrum of bimetallic Ag-Au monolayer-protected clusters (MPC) obtained by progressively doping Ag into the experimentally known structure of Au133(SR)52 was predicted via rigorous time-dependent density-functional theory (TDDFT) calculations. In addition to monometallic Au133(SR)52 and Ag133(SR)52 species, 5 different (Ag-Au)133(SR)52 homotops were considered with varying Ag content and site positioning, and their electronic structure and optical response were analyzed in terms of Projected Density Of States (PDOS), the induced or transition electron density, and Transition Component Maps (TCM) at selected excitation energies. It was found that Ag doping led to the effects rather different from those encountered in bare metal clusters. And it was also observed that Ag doping could produce structured spectral features, especially in the 3–4 eV range but also in the optical region if Ag atoms were located in the sub-staple region, as rationalized by the accompanying electronic analysis. Additionally, Au doping into the staples of Ag-rich MPC also gave rise to a more homogeneous induced electron density. These findings show the great sensitivity of the electronic response of MPC nanoalloy systems to the exact location of the alloying sites.     

中国书画颜料颜色仿真与存储方法研究

在虚拟绘制中,基于Kubelka-Munk颜色光学理论,提出了一种中国书画颜料颜色仿真新方法,其主要思想是:根据颜料R/G/B三颜色通道的遮盖力(c)和单位厚度颜料在黑背景下的反射率(Rb)计算得到颜料各颜色通道吸收系数(K)和散射系数(S),通过K、S和宣纸反射率计算得到宣纸上有效厚度为d时颜料的反射率(Rd),根据该反射率与下一层颜料的K、S和d计算得到两层颜料合成时的反射率,依此类推得到多层颜料合成时的反射率,将该反射率转换成颜色亮度值(R,G,B),从而得到宣纸上多层颜料合成时的颜色(RGB).在此基础上提出一种颜色存储方法,通过存储宣纸上颜色(RGB)实现对绘制结果的实时存取和显示.所提方法已成功应用于基于力反馈技术的虚拟绘制系统中,较好地仿真了植物色与矿物色在颜色合成中的不同特征.     

NaCl和KCl溶液康普顿散射的影响因素

自康普顿散射提出以来,其理论研究和应用研究一直是国内外的热点。基于NaCl和KCl溶液的康普顿散射,通过一定的近似处理,从理论上分析适合这两种溶液的康普顿散射光子数与溶液浓度之间的关系表达式;然后,通过康普顿散射实验验证康普顿散射的理论和实验研究。为了从更微观的角度来把握NaCl和KCl溶液康普顿散射的机理,笔者立足于密度泛函理论对NaCl与KCl溶液的电子结构作了深入分析,得出结论:除质量密度、散射衰减因子以及溶液的浓度外,电子数密度和电子受到的束缚也对康普顿散射光子数有影响,其中,电子数密度是影响NaCl与KCl溶液康普顿散射光子数的主要因素。