Si基片各向异性腐蚀特性研究

为了制备高性能铁电薄膜红外探测器 ,对Si微桥的湿化学腐蚀工艺进行了研究 .利用Si基片各向异性腐蚀特性 ,在四甲基氢氧化铵 (简称TMAH )水溶液中加入氢氧化钾 (KOH)作为各向异性腐蚀液 (简称KTMAH) ,研究了TMAH与KOH摩尔比、腐蚀浓度、腐蚀温度对Si基片腐蚀特性的影响 .结果表明 :Si(1 0 0 )面的腐蚀速度随着腐蚀液浓度和温度的升高而增大 ,随着TMAH与KOH摩尔比的降低 ,KTMAH腐蚀液对掩膜层的腐蚀程度加剧 .选用 5 g/L的过硫酸盐 (PDS)与TMAH质量分数为 2 5 %、TMAH与KOH摩尔比为2的KTMAH混合液作为腐蚀液 ,并在 80℃× 2 .5h的腐蚀条件下能得到平整的腐蚀面 ,可以制备质量较好的微桥结构     

Comparison of short period InAs/GaSb superlattices on GaSb and GaAs substrates

Type Ⅱ superlattices(SLs) short period InAs(4ML)/GaSb(8ML) were grown by molecular-beam epitaxy on lattice-mismatched GaAs substrates and on GaSb substrates.A smooth GaSb epilayer was formed on GaAs substrates by inserting mulit-buffer layers including an interfacial misfit mode AlSb quantum dot layer and AlSb/GaSb superlattices smooth layer.SLs grown on GaAs substrates(GaAs-based SLs) showed well-resolved satellite peaks in XRD.GaSb-based SLs with better structural quality and smoother surface showed strong photoluminescence at 2.55μm with a full width at half maximum(FWHM) of 20 meV,narrower than 31 meV of GaAs-based SLs.Inferior optical absorption of GaAs-based SL was observed in the range of 2-3μm. Photoresponse of GaSb-based SLs showed the cut-off wavelength at 2.6μm.     

聚合物试剂的合成及应用研究

聚合物支载的有机合成反应比相应的小分子合成体系有独特的优越性。我院有机化学研究室多年来在制备聚合物试剂和催化剂及其在有机化合物反应中的应用进行了系统研究,并且在聚合物试剂和催化剂在不对称有机合成反应中的应用研究方面亦取得重要成果,对此近１０年的进展进行综合评述。     

不同培养料栽培猴头实验

猴头在杂木屑，棉籽壳和麦草粉三者为主或以其中之一为主的培养料上均可很好地生长发育，以杂木屑或棉籽壳为主的培养料产量较高，实验表明，以麦草粉为主的培养的产量仅比杂木屑为主的低１３％，所以，在麦产区以麦草为主栽培猴头是可行的，袋栽猴头后期脱袋埋土栽培技术值得提高。     

浅谈花卉栽培的新技术

概括了国内外无土栽培技术的发展历史;以基质和营养液为重点,论述花卉无土栽培的技术要点;阐明无土栽培技术在花卉领域尤其在家庭装饰方面应用前景的广泛性;明确今后研究的着眼点。     

Purification of breast cancer resistance protein ABCG2 and role of arginine-482

Human ABCG2 was efficiently overexpressed in insect cell membranes, solubilized with 3-[(3-cholamidopropyl)dimethyl ammonio]-1-propanesulfonate, and purified through N-terminal hexahistidine tag. Its functionality was assessed by high vanadate-sensitive ATPase activity, and nucleotide-binding capacity. Interestingly, the R482T point mutation increased both maximal hydrolysis rate and affinity for MgATP, and lowered sensitivity to vanadate inhibition. Direct nucleotide binding, as monitored by quenching of intrinsic fluorescence, indicated a mutation-related preference for ATP over ADP. The R482T mutation only produced a limited change, if any, on the binding of drug substrates, indicating that methotrexate, on the one hand, and rhodamine 123 or doxorubicin, on the other hand, bound similarly to wild-type and mutant transporters whether or not they were subject to cellular transport. In addition, the characteristic inhibitors GF120918 and 6-prenylchrysin, which alter mitoxantrone efflux much better for wild-type than mutant ABCG2, bound similarly to purified ABCG2, while the highly-potent Ko143 bound in the nanomolar range also effective in inhibition of drug transport. All results indicate that the role of the arginine-482 mutation on substrate drug transport and inhibitor efficiency is not mediated by changes in drug binding. Received 10 April 2006; received after revision 22 May 2006; accepted 12 June 2006 A. Pozza and J. M. Perez-Victoria contributed equally to this work     

NiW合金基带表面c(2×2)-S超结构的硫化处理

由于硫元素与氧元素化学特性相近,利用硫在Ni基带表面形成的c(2×2)-S超结构可以有效地控制氧化物缓冲层在Ni基带表面的织构.本研究提出将单质硫在120℃下挥发,利用单质硫在基带表面的吸附与脱附形成有序c(2×2)-S超结构的新技术路线.X光电子能谱(XPS)结果显示,采用新技术处理的金属基带表面有明显的硫元素,基带表面Ni和S的原子比例符合c(2×2)结构中S的覆盖度,即0.5的要求.在经过硫化处理后的NiW基带表面制备缓冲层,结果显示,新硫化处理技术改善了NiW基带表面的物理化学特性,有利于氧化物缓冲层的外延生长.     

介质协萃效应（Ⅱ）

根据空间效应，配置在铀酰赤道平面的配位体不应过挤或过松，可用配位体扇面角和（ＦＡＳ）作估算。ＵＯ２（ＯＡｃ）Ｂｒ（ＴＢＰ）２的ＦＡＳ为１８０°：空间配位最佳，预计形成更稳定的萃合物而呈现更高萃取率。用醋酸钠─醋酸和溴化钠混合介质萃取铀酰离子证实上述预测。保持阴离子总浓度恒定，醋酸根与溴化物浓度比为ｌ：ｌ０时出现协萃效应。用斜率法确证萃合物组成与预测一致。     

金属蜂窝状催化剂载体的制备及其强度研究

目的制备金属蜂窝状催化剂载体,并使其强度达到一定要求。方法采用浸渍-提拉法（dip-coating）在所选的金属基体材料上制备氧化铝涂层,所用的载体是用自制设备制作的金属蜂窝状载体。结果通过对样品进行检测得出浸渍-提拉的理想速度为2.5 mm/s,干燥温度为200℃,热处理温度为600℃,热震实验60次后样品质量损失L≤15%。结论小型试验阶段,整个实验过程是可行的,结果达到了预期要求。