鄂尔多斯盆地含铀砂岩碳酸盐胶结物C-O同位素研究及地质意义

详细研究鄂尔多斯盆地含铀砂岩的碳氧同位素地球化学特征,探讨了鄂尔多斯盆地砂岩型铀矿富集成矿机理及多种能源共存的内在联系,从而进一步探讨盆地型多种能源富集成藏(矿)的潜在的规律.含铀砂岩的碳酸盐胶结物C-O同位素测定结果表明:所有样品δ13CPDB值变化范围为-4.2‰~-23.62‰,大部分样品δ13CPDB值落在碳酸盐岩δ13CPDB值范围内或略低,4个样品δ13CPDB值均低于-10‰;样品中碳酸盐胶结物含量为0.5%~16.12%.综合分析表明:含铀砂岩所属的中侏罗统直罗组在浅变质作用过程中受到过来自深部流体的交代渗滤作用,在淋滤与溶解盆地下古生界的海相碳酸盐过程与古生界的油气相互混合,在砂岩的成岩(成矿)过程中并且具有一定比例有机质的加入,使得含铀砂岩的胶结物中碳同位素值变低.含铀砂岩在成岩(成矿)过程中和一定比例有机质进行水岩交换作用,有机质的参与促使本区铀矿质的络合与运移,最终在有利氧化-还原条件下沉淀和富集.     

Re-Os isotopes and PGE geochemistry of black shales and intercalated Ni-Mo polymetallic sulfide bed from the Lower Cambrian Niutitang Formation, South China

The paleo oceanenvironmentalchangeduringthePrecambrian Cambriantransitionisakeyissuere latedtothecausesforanexplosiveradiationofdiffer entmetazoanphyladuringtheEarlyCambrianera .Thechemicalandisotopiccompositionsofmarinesed iments (carbonates ,phosphorites ,siliceousrocks ,andblackshales)recordthechangingcompositionandphysicalconditionsoftheseawaterinwhichtheserocksaccumulated .Organiccarbon richblackshalesfrommarineenvironmentsarecommonlyenrichedinanumberoftraceelementssuchasNi,Mo ,V ,Co ,…     

Sulfur and carbon isotopic variations in Neoproterozoic sedimentary rocks from southern China

A new set of δ34Ssulfide, δ34Ssulfate and δ13Ccarbonate values has been reported from Neoproterozoic sedimentary rocks in southern China. The interglacial black shales of the Datangpo Fm. display higher δ34Ssulfide values with >+20‰ average, but the postglacial black shales from the Doushantuo Fm. show negative δ34Ssulfide values. However, the Jinjiadong Fm., the same post-glaciation as the Doushantuo Fm., has positive δ34Ssulfide values, implying that the δ34S value of sedimentary sulfides would be controlled by lithofacies and paleogeographic environments. The δ34Ssulfate values relative to δ13Ccarbonate were obtained by extraction of trace sulfate from the successive carbonate sequences in the Yangtze Gorges sections. A preliminary interpretation suggests that the oceanic environment may fluctuate dramatically at the post-glacial Doushantuo stage and, then, recover its stability at the Dengying stage on the basis of the high resolution δ34S and δ13C curves of seawater.     

锶同位素地层学在海相地层定年中的潜在价值

锶同位素地层学在海相地层的对比和定年中具有十分重要的作用。随着锶同位素地层学的深入研究，人们清楚地认识到海水的锶同位素组成是全球变化的灵敏指示剂。显生宙以来全球海水的^87Sr／^86Sr比值是时间的函数，可以把锶同位素组成用于海相地层的定年和进行全球对比，估计沉积间断持续时间、生物带的时间范围和发展阶段，从而为重要地球化学周期的预测提供基础参数。当锶同位素地层学用于定年时，其地质年龄的精确度取决于几个因素，包括样品原始锶同位素组成的保存情况、分析精度、用于建立数据库样品年龄的可信度以及^87Sr／^86Sr比值—年龄曲线的最佳拟合方法等。     

铝酸锶铕系发光材料的制备及其发光机理

20世纪发现和发展起来的铝酸锶铕体系长余辉发光材料是一类重要的新型能源和节能材料.综合评述了铝酸锶铕系发光材料的光学性能,对其制备方法进行了系统描述,同时对其发光机理进行了介绍,并总结了这种发光材料的研究现状.     

北秦岭柳树湾花岗伟晶岩型铀矿床流体包裹体和氢-氧-硫同位素研究

河南省柳树湾花岗伟晶岩型铀矿床位于北秦岭东段,含矿伟晶岩受灰池子岩体与秦岭岩群的接触带控制。通过对研究区的地质特征、流体包裹体以及氢-氧-硫同位素的研究,探讨柳树湾花岗伟晶岩型铀矿床的成矿物质、流体来源。伟晶岩型铀矿成矿流体温度为513.5℃～567.4℃,H同位素为-107.9‰～-89.6‰,O同位素为11‰～13.2‰,S同位素为3.5‰～5.8‰。研究结果表明：柳树湾花岗伟晶岩型铀矿床成矿流体主要为深部岩浆水,成矿物质主要来自深部岩浆。     

塔里木盆地顺北地区中下奥陶统硅质岩特征及其成因

为明确顺北地区中下奥陶统硅质岩特征及其成因。在岩石学特征研究基础上,对不同产状硅质岩样品进行稀土元素和微量元素测试分析,结合硅氧同位素测试结果开展顺北地区中下奥陶统硅质岩特征及成因研究。研究结果表明:硅质以灰黑色条带状、团块状和灰白色条带状分布于灰岩之间,与基质灰岩粒屑镶嵌发育。岩心断面局部可见贝壳类和介壳类生物碎屑。硅质岩样品稀土元素含量很低,平均仅0.3μg/g,整体表现为轻稀土富集、重稀土亏损,两者分异明显且具有明显正Eu和正Ce异常,指示热液流体对硅质岩形成具有重要影响,且硅质岩颗粒Ni/Co值为6.53～55.45,平均值23.7,表明硅质岩主要形成于相对还原的成岩环境中。不同产状硅质岩δ~(30)Si‰值分布范围0.6‰～2.74‰,平均1.74‰,指示交代成因为主。综合分析认为,顺北地区中下奥陶统硅质主要来源于深部富硅流体,流体在颗粒灰岩发育相带交代围岩形成硅质岩,但改造作用使原岩颗粒孔隙降低,整体表现为破坏性成岩作用。     

精馏与化学交换法分离硼同位素的数学模型及优化

采用精馏与化学交换法，针对三氟化硼-苯甲醚分离体系，研究了硼同位素分离生产过程的特点，建立了分离过程的稳态数学模型，并利用Matlab程序进行模型求解，同时对操作参量进行优化，得到了不同分离要求的优化参量和操作条件对化学交换过程中理论塔板数的影响以及丰度的分布，该教学模型可以指导工艺设备的改进和优化，为下一步的放大和操作过程提供了理论依据．     

Carbon isotope negative excursions across the Triassic-Jurassic boundary interval in the Tibetan Himalayas

Fossils from sections at Germig in the Tibetan Himalayas allow the establishment of ammonoid assemblages ranging from uppermost Triassic to basal Jurassic. The carbon isotope profile from these sections shows a majority of positive values in the Rhaetian, and negative values within the Hettangian intervals. Pronounced negative excursions between the Triassic and Jurassic boundary corresponds to the end-Triassic extinction. A stepwise pattern of the end-Triassic extinction is demonstrated by the bivalves and ammonoids. However, the warm episode persisting throughout from late Triassic to basal Hettangian in the Tibetan Himalayas, indicated by subtropic and tropic forms remains to be interpreted.