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81.
The hydrogen storage of(TiZr_(0.1))_xCr_(1.7-y)Fe_yMn_(0.3)(1.05x1.2,0.2y0.6)alloys,prepared by Ar plasma arc melting,were investigated by X-ray diffraction,pressure-composition-temperature(PCT).The results indicated that all(TiZr_(0.1))_xCr_(1.7-y)Fe_yMn_(0.3)(1.05≤x≤1.2,0.2≤y≤0.6)alloys were determined as C14-type Laves phase,the cell parameters a,c and unit cell volume of(TiZr_(0.1))xCr_(1.1)Fe_(0.6)Mn_(0.3)(1.05≤x≤1.2)alloys increased with increasing the(TiZr)super-stoichiometry from 1.05 to 1.2,and the value of a/c almost unchanged.The hydrogen absorption and desorption plateau pressure decreased from 5.6,4.4–2.6,2.2 MPa with the increase of(TiZr)super-stoichiometry from 1.05 to1.2 at 274 K respectively,and the hydrogen desorption plateau pressure decline was not obvious when the(TiZr)super-stoichiometry exceeded 1.15.The(TiZr_(0.1))_(1.1)Cr_(1.1)Fe_(0.6)Mn_(0.3)alloy had the best comprehensive properties about the maximum and reversible hydrogen storage capacity was 1.79 and 1.45 wt%respectively.The cell parameters a,c and unit cell volume of(TiZr_(0.1))_(1.1)Cr_(1.7-y)Fe_yMn_(0.3)(0.2≤y≤0.6)alloys increased as the ratio of Fe/Cr content decreased.The hydrogenation and dehydrogenation plateau pressure decreased from 4.5,3.4–1.0,0.9 MPa respectively and the maximum hydrogen storage capacity increased from 1.79 to 2.0 wt%as the Fe content reduced from 0.6 to 0.2 at274 K.The maximum and the reversible hydrogen storage capacity were about 2.0 and 1.65 wt%as the ratio of Fe/Cr was 0.13(ie,(TiZr_(0.1))_(1.1)Cr_(1.5)Fe_(0.2)Mn_(0.3)alloy),its relative molar enthalpy of dissociation hydrogen was24.30 kJ/mol H_2. 相似文献
82.
Dan Boneh等人提出了具有关键词搜索性质的公钥加密方案,并且构造出了在随机预言模型下可证明安全的基于BDH困难问题的双线性映射对下的具体构造.本文给出了一个具有关键字搜索性质的高效云存储加密方案,而且在随机预言模型下可证明CCA-安全.该方案能够安全高效的管理云服务器中的加密文件,能够对已经加密的文件进行相等配对.构造方案能够在无安全信道环境中传输陷门Tw. 相似文献
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85.
针对储气库循环注采过程中循环应力对储气库岩石产生疲劳损伤的问题。利用颗粒离散元法建立岩心真三轴数值模型,根据岩心室内试验标定数值模型参数,然后对数值模型进行多周期等幅值轴向循环应力加载,研究循环应力对储气库岩石微观结构及力学性质的影响。结果表明:循环应力加载过程中,模型内生成的无黏结接触数量和微裂缝数量逐渐增多,而生成位置受原始裂缝控制明显,模型孔隙度逐渐减小,且模型内无黏结接触数量、微裂缝数量和孔隙度的变化速率均呈递减趋势;相同应力水平下模型侧向应变和轴向应变均增大,但侧向应变占主导地位;模型弹性模量逐渐降低,而模型泊松比和损伤量逐渐增加,且模型弹性模量、泊松比和损伤量的变化速率均呈递减趋势。 相似文献
86.
针对柴油储存过程中质量衰变问题,利用典型柴油样品,开展烃化合物对中国成品柴油储存安定性影响规律研究。烃组成分析测定结果表明,柴油中总芳烃和链烷烃之间存在很强的相关性(相关系数为0.90)。综合采用相关分析、逐步线性回归等方法,建立了安定性指标与烃组成的关联模型,拟合验证表明模型可靠,可以直接用于柴油储存安定性预测;研究确定了柴油储存安定性的主要影响物质,按照对储存安定性指标影响的严重程度将烃类物质分为三个等级,其中苊烯和三环芳烃对柴油质量衰变影响最大,链烷烃对十六烷值和热值影响最大。 相似文献
87.
主要从Map Reduce作业调度和Hive性能调优两个方面对Hive的性能优化进行研究.对于Map Reduce主要从编程模型切入,分析其执行过程,并从map端、reduce端进行参数调优.接着从Hive框架角度入手,分别从分区表和外部表以及常用数据文件的压缩、行式存储与列式存储等方面进行深入研究.实验结果表明,snappy压缩、orcfile/parquet存储格式对于列式查询,提高查询效率,对于大数据分析平台有较好的兼容性. 相似文献
88.
Graphene-based hybrid materials and their applications in energy storage and conversion 总被引:1,自引:0,他引:1
Graphene attracts more and more scientists and researchers owing to its superior electronic,thermal,and mechanical properties.For material scientists,graphene is a kind of versatile building blocks,and considerable progress has been made in recent years.Graphene-based hybrid materials have been prepared by incorporating inorganic species and/or cross-linking of organic species through covalent and/or noncovalent interactions.The graphene-based hybrid materials show improved or excellent performance in various fields.In this review,we summarize the synthesis of graphene and graphene-based hybrid materials,and their applications in energy storage and conversion. 相似文献
89.
军事用途的地下洞库,防水施工是施工控制的关键。防水施工是系统的施工过程,贯穿于洞库施工的各个阶段,任何一个阶段没有处理好,都会给整个工程留下隐患,从而影响到洞库的使用效果,加大后期使用成本。通过阐述6205洞室各施工阶段防水施工的控制要点,并结合现场施工实际,提出防水施工的具体施工方案。 相似文献
90.
The effect of Mg substitution for La on microstructure, hydrogen storage and electrochemical properties of the annealed La_(1-x) Mg_x Ni_3.5(x=0.20, 0.23, 0.25 at%) alloys have been studied. All the samples were mainly composed of(LaMg)_2Ni_7,(LaMg)Ni_3, and LaNi_5 phases. Mg substitution for La changed the phase abundance, but did not change the constitution of all phases, which is con fi rmed by the results of backscattered SEM images and EDS analysis. The P–C isotherms indicated that the La_(1-x) Mg_x Ni_3.5alloys reversibly absorbed and desorbed hydrogen smoothly at 298 K. The hydrogen absorption cyclic stabilities of La_(1-x) Mg_x Ni_3.5alloy after 5 hydrogen absorption/desorption cycles reached the maximum values of91.9% and 96.0% at 298 K and 323 K, respectively. The hydrogen desorption capacity and plateau pressure for the La_(1-x) Mg_x Ni_3.5alloy reached the maximum values of 1.055 H/M and 0.074 MPa, respectively. The desorption capacities of La_(1-x) Mg_x Ni_3.5reached 0.193 H/M and 0.565 H/M in the fi rst minute at 298 K and 323 K, respectively. Electrochemical property measurement indicated that La_(1-x) Mg_x Ni_3.5(x=0.20,0.23, 0.25 at%) alloys possessed excellent activation capability and were completely activated within3 cycles. Discharge capacities of La_(1-x) Mg_x Ni_3.5alloys reached 378.2 m A h/g(x = 0.20 at%), 342.7 m A h/g(x = 0.23 at%), and 369.6 m A h/g(x = 0.25 at%), respectively. Moreover, energy density of La_(1-x) Mg_x Ni_3.5alloy was much larger than that of La_0.80Mg_0.20Ni_3.5 alloy and nearly approaches the maximum value of La0.75Mg0.25Ni3.5. Thus, the La_(1-x) Mg_x Ni_3.5alloy exhibits optimum comprehensive properties of hydrogen storage and electrochemistry. 相似文献