Improvement in hydrogen storage performance of Mg by mechanical grinding with molten salt etching Ti3C2Clx

Mg-based materials are currently a hot research topic as hydrogen storage materials due to their considerable theoretical hydrogen storage capacity. However, the kinetic performance of hydrogen absorption and desorption of Mg is too slow and requires high temperature, which seriously hinders the application of this material. MXene is a new type of two-dimensional material with significant role in improving thermodynamics and kinetics. In this experiment, a two-dimensional layered MXene containing Cl functional group was prepared by molten salt etching using the Ti-containing MAX phase as the raw material. Then different ratios of Ti₃C₂Cl_x were uniformly dispersed onto the surface of Mg by high energy ball milling. The samples were characterized by hydrogen absorption and desorption kinetics, SEM, XRD, XPS, and DSC to investigate the effect of Ti₃C₂Cl_x on the hydrogen absorption and desorption performance of Mg. The onset hydrogen absorption temperature can be reduced to room temperature and the hydrogen release temperature is reduced by 200 ​°C by doping Ti₃C₂Cl_x. And there is also 5.4 ​wt% hydrogen storage in the isothermal hydrogen absorption test at 400 ​°C. The results of DSC demonstrate that the E_a of Mg+15 ​wt% Ti₃C₂Cl_x was reduced by 12.6% compared to pristine Mg. The ΔH is almost invariable. The results of XPS show that the presence of multivalent Ti promotes electron transfer and thus improves the conversion between Mg²⁺/Mg and H⁻/H. This study provides a guideline for further improving the hydrogen absorption and desorption performance of Mg-based hydrogen storage materials.     

蓄电池容量自动测试仪

本文根据国标《CB5008.1～3—85》的规定,设计了一种蓄电池容量自动测试仪.该仪器利用8位单片计算机进行控制,完成测试过程中的自动恒流、自动测量时间和温度、自动进行数据处理、自动停机等功能.它的优点是操作简单,测量精度高,成本低.本文介绍了蓄电池容量的测量原理和计算方法,对单片机的硬件和软件系统都做了全面的叙述.     

A user designer-based systems methodology

This paper develops the argument that in organizational redesign it is desirable to utilize user-designers as the architects for the redesign. A methodology is developed which emphasizes the use of ideal systems models by user-designers to plan for the organization's future. The methodology involves the creation of an ideal system model, then an analysis of the present system through the creation of root definitions and process models of the existing system. Then root definitions and process models for the idealized system are created. Finally, the two are compared and desirable changes are generated which bring the existing system toward the idealized.     

泵引起的液压系统振动分析

通过液压系统产生振动和噪音的振源及振动量传递的分析,开发了测定泵的振源特性的新方法,－２压力／２系统”法,介绍了用阻抗求解管内压力脉动的方法及通用仿真程序包,实验表明,仿真结果与实测结果一致。     

一类一阶线性非齐次方程组的解法

利用二阶线性微分方程的可解定理,给出一阶线性非齐次方程组的一种新解法     

贵州省粮食储藏地理区划初步研究

通过对贵州省气象特征的分析,尤其是对影响粮食安全储藏的主要环境因素温度和相对湿度的分析,得出贵州省粮食储藏可划分为四个地理区域。依据各区域的储藏气候条件和主要粮食的储藏特点,提出相应的储藏技术措施。     

无初始状态统计知识时多变量系统的最优平滑与预报

在无初始状态统计知识的情况下,我们分别就固定点平滑、固定滞后平滑与预报３种情况给出了动态系统的最优线性最小偏差估计（ＢＬＩＭＢＥ）,同时还给出了完全（ｉ,ｊ,Ｔｉ）－可重构性的概念及系统完全（ｉ,ｊ,Ｔｉ）－可重构的充要条件     

贮氢合金的开发与研究进展

贮氢合金是近年来开发的一类新型高性能材料。本文介绍了贮氢合金的开发和研究的最新进展,论述了它在氢的提纯、热泵、空调、压缩机和镍—氢化物电池等高技术领域中的应用前景。     

DMloDS的多媒体存储服务器中可丢弃帧的分配问题

分布式多媒体信息点播系统（ＤＭＩｏＤＳ）要求其多媒体存储服务器能够同时为大量的客户提供实时的信息服务,为了保证每个客户的ＱｏＳ要求,系统必须提供接纳控制机制以限制客户的数量．首先从理论上描述了一种适合于ＤＭＩｏＤＳ中多媒体存储服务器的统计型接纳控制算法ＳＡＣＡ,并对统计过程中产生的可弃帧的分配问题进行了深入的研究,提出了可丢弃帧分配的数学模型,保证了每个客户的基本ＱｏＳ要求,为ＤＭＩｏＤＳ系统的设计提供了理论依据     

区间Lurie型控制系统的鲁棒绝对稳定性

研究了区间Ｌｕｒｉｅ型直接控制系统和间接控制系统的鲁棒绝对稳定性,给出了系统鲁棒绝对稳定的充分条件,应用的例子说明所得的结果简单实用并且得到了较大的鲁棒度。