Adsorption of polyelectrolyte on the surface of ZnO nanoparticles and the stability of colloidal dispersions

How to prevent flocculation is a universal problem in synthesis and application of nanoparticles. Because of high surface activity, nanoparticles tend to form large di-mension of aggregates with some loose contact interface. When solid particles are suspended in polyelectrolyte so-lution, polymer chains are adsorbed on the surface of par-ticles and they render to stabilize the corresponding parti-cles. The stabilizing property of polyelectrolytes is the reason for wide application in many fiel…     

基于L-MBP神经网络的煤自然发火期预测

针对不同矿井、矿井不同工作面预测煤自然发火期的难题，采用具有较好收敛性的L-M（Levernberg-Marquardt）BP算法的神经网络，开发出煤自然发火期预测仿真系统软件。根据煤自燃的内凼和外因影响因素，在东北矿区各自燃采场收集了152个样本训练数据，并应用于该软件训练、预测其结果误差〈10％。在神东矿区进行预测时，预测结果与实际情况吻合较好，为制定预防采场自然发火的技术措施提供了可靠的技术参数。     

近距离煤层采空区自然发火预测模型研究

根据近距离煤层采空区渗流及扩散数学模型,利用东荣二矿近距离煤层采空区的特征,对该近距离煤层采空区作出了相应的假设,并利用近距离煤层工作面的现场观测数据,进行数据拟合,得出了相应的函数方程,建立了近距离煤层采空区自然发火预测模型.利用CFD软件FLUENT6.0进行解算,得出了近距离煤层采空区氧浓度变化值、速度变化值、压力变化值等结果,与实际相符.图2,参8.     

综放面采空区流场模拟及自燃危险区域划分

综放采空区容易发生自燃。以往对采空区“三带”的划分主要通过向采空区埋管观测来实现，对于现场观测不能实现的情况下，采空区自燃危险区域难以判定。笔者通过对采空区渗流场的数值模拟，得到采空区渗流速度及O2浓度的分布。结合实验测得的煤自然发火期和自燃临界参数，对采空区“三带”进行划分。该方法计算量比模拟采空区煤自燃全过程少得多，但划分精度却能够满足实际防灭火需要。     

Time-frequency analysis of SH waves in an isotropic plate bordered with one elastic solid layer

Acoustic sensing utilizing shear-horizontal acoustic plate mode (SHAPM) has attracted much interest in recent years[1―3] due to the fact that the absence of the component of the displacement normal to the surface allows each SH mode to propagate in the p…     

Theoretical model of particle orientation distribution function in a cylindrical particle suspension subject to turbulent shear flow

The equation for the orientation probability function of slender cylindrical particles suspended in planar turbulent flows was investigated. After ensemble averaging, the equations for the mean and fluctuating probability function were derived. The equation for the fluctuating probability function appearing in the equation of mean probability function was solved by using the method of characteristics analysis. The orientational dispersion terms due to the random motion of cylindrical particles in the equation of mean probability function are related to the mean probability function and the Lagrangian fluid velocity correlations. The evolution of the mean probability function was described by a modified orientation?space?convection equation, where the dispersion terms account for the randomizing effect of the turbulence.     

硅酸钠和PAM对纳米SiO_2分散性能的影响

选择九水合硅酸钠和聚丙烯酰胺(PAM)作为分散剂,通过激光粒度分析仪对纳米颗粒的分散稳定性进行评价,红外光谱仪对分散剂在颗粒表面的吸附状态进行识别.发现九水合硅酸钠和聚丙烯酰胺结合起来使用可以发挥协同效应,从而显著改善纳米SiO2颗粒在水溶液中的分散稳定性,而且当九水合硅酸钠和聚丙烯酰胺这两种分散剂的添加量相同时,先添加九水合硅酸钠后添加聚丙烯酰胺,与先添加聚丙烯酰胺后添加九水合硅酸钠相比,纳米颗粒的分散稳定性有所提高.     

用于外腔倍频激光的旋光滤波设计与分析

为了得到纯净的单色倍频光，依据石英晶体的旋光特性，利用石英晶体和起偏棱镜的组合，给出了一种用于将外腔倍频激光中的基频光去除的旋光滤波设计.石英晶体的厚度只要满足使倍频光与基频光的旋光角之差为π/2的奇数倍，就能滤除基频光而获取纯净的倍频光.利用Origin软件分析了石英晶体的厚度误差对滤光性能的影响，结果表明：厚度误差在±0.02 mm以内时，对滤波效果的影响可以忽略.     

城市街道内污染物扩散的数值模拟

随着我国城市汽车保有量的迅速攀升,城市中心区的空气质量与生态环境急剧恶化.利用CFD数值模拟研究街道峡谷污染物的扩散问题,对比分析了开放街道峡谷和城市街道峡谷污染物的扩散问题,证明了计算域和入流边界处湍动能k和湍动能耗散率ε取值的重要性.计算结果与经典风洞实验符合很好,证实了相同条件下城市街道峡谷的背风墙和迎风墙上的污染物浓度均大于开放街道峡谷的相应值.利用3维建筑群计算实例,指出了寻求建筑群优化布局对减小小区污染的重要性.     

确定地下水污染强度的梯度正则化方法

将梯度正则化方法(Gradient-Regulation method)应用于地下水溶质运移数学模型(对流—弥散方程)的源项反演,研究了山东省淄博市张店区沣水南部区域地下水中硫酸盐年入渗强度的数值反演问题.算例结果表明了应用梯度正则化方法解决此类问题的有效性和可行性.