聚苯胺/活性炭复合材料电容性能研究

以商品化活性炭为原料，在1mol／L盐酸环境下采用原位聚合法制备了聚苯胺／活性炭复合材料（PANI／C），复合材料中聚苯胺的质量分数为46．4％．用循环伏安、交流阻抗、恒流充放电测试等方法考察比较了新材料与原活性炭在1mol／L H2SO4溶液中的电容性能．结果表明，新材料的比容量和大电流充放电性能均优于碳材料．3．0mA／cm^2电流密度下，复合材料电极比容量高达448．7F／g，比原碳材料提高60％．     

凹凸棒粘土比表面改性方法的研究

利用不同的化学试剂和不同的加热时间等方法,对改进凹凸棒粘土的比表面积进行了研究.结果表明,在5%硫-磷混酸并加热一定时间的条件下,凹凸棒粘土的比表面积由原来的140 m2/g增加到400 m2/g.经过XRDI、R、SEM测试,发现其结构和构型均未变化.     

无机-有机杂化材料的制备及其对Cu^2＋吸附性能研究

通过正硅酸乙酯（TEOS）与钛酸正丁酯（Ti（OC4H9）4）间的醇解反应和溶胶-凝胶法制备了一系列无机-有机杂化材料，并观察了Cu^2＋的浓度、体系的pH值等参数对Cu^2＋吸附性能的影响．结果表明：随着杂化材料中钛含量的增加，它们的比表面积随之增大．Cu^2＋吸附实验表明：该类杂化材料确实能够吸附Cu^2＋，而且不同比例的Si／Ti杂化材料对Cu^2＋的吸附能力不同．因此该类杂化材料能够用于废水中Cu^2＋的分离和回收，所以在废水处理等环境保护方面具有潜在的应用价值．     

Bimetallic-organic coordination polymers to prepare N-doped hierarchical porous carbon for high performance supercapacitors

Single metal-organic coordination polymers have limited functions as precursors for porous carbon electrode materials.The construction of bimetallic organic coordination polymers can effectively utilize the advantages of each single metal-organic coordination polymer to improve the performance of the derived carbon materials.Herein,High performance nitrogen-doped porous carbon(BC_(Fe–Ni))have been produced by directly carbonizing bimetallic organic coordination polymers formed by 4,4'-bipyridine(BPD)reaction with Fe Cl_3and NiCl_2.The BC_(Fe–Ni) exhibits high nitrogen content(12.66 at%),large specific surface area(1049.51 m~2g~(-1))and hierarchical porous structure,which contributes to an excellent gravimetric specific gravity of 320.5 Fg~(-1)and 108%of specific capacitance retention after 10000 cycles.The BC_(Fe–Ni)assembled symmetrical supercapacitor shows an energy density of 18.3 Wh kg~(-1)at a power density of 350 W kg~(-1).It is expected that the as-prepared N-doped porous carbon derived from bimetallic-organic coordination polymer is a promising electrode material for high performance energy storage devices.     

数字后端约束设计

主要介绍集成电路设计中数字集成电路后端的完整设计流程和一些参数设计的问题,侧重分析了时序约束文件的生成方法和与数字集成电路前端时序约束的区别和联系,最后通过一个USB1.1模块实例系统地介绍了数字后端设计实现的原理和方法。     

How helpful are spatial effects in forecasting the growth of Chinese provinces?

In this paper, we make multi‐step forecasts of the annual growth rates of the real gross regional product (GRP) for each of the 31 Chinese provinces simultaneously. Beside the usual panel data models, we use panel models that explicitly account for spatial dependence between the GRP growth rates. In addition, the possibility of spatial effects being different for different groups of provinces (Interior and Coast) is allowed for. We find that both pooling and accounting for spatial effects help substantially to improve the forecast performance compared to the benchmark models estimated for each of the provinces separately. It is also shown that the effect of accounting for spatial dependence is even more pronounced at longer forecasting horizons (the forecast accuracy gain as measured by the root mean squared forecast error is about 8% at the 1‐year horizon and exceeds 25% at the 13‐ and 14‐year horizons). Copyright © 2010 John Wiley & Sons, Ltd.     

介孔固体研究进展

介绍了介孔固体的特征、制备方法及其应用     

关于直线相关系数计算方法的一点看法

本文就直线相关系数在单变量分组条件下的传统计算公式提出一点看法。应根据资料的具体情况进行具体计算,才能得出正确的结论。     

小议汉语称代

现代汉语表达方式中的"称代",其作用是避复求简,使语言表达简洁紧凑.不同类型的称代有着不同的表意特点,能从不同方面丰富和提高称代的表意功能.运用"称代"时,不仅要求称代的语体明确,还必须注意交际场合,协调语体,做到言与意合.     

方文山“中国风”歌词的艺术质感

"中国风"是现代流行歌曲中兼具"谱曲可唱"的音乐性与"离谱可赏"的文学性之双重特性的类型。以方文山的"中国风"歌词为研究对象,联系文学理论的有关知识,采用追本溯源的研究方法,通过分析"中国风"歌词中韵味无穷的意象美与含蓄空灵的意境美,全面展现怀旧中国背景与现代元素二者合力打造的"中国风"歌词的艺术魅力。