铂(II)与胺类配合物的合成、晶体结构和抗肿瘤活性研究

研究铂(II)与三种胺类配合物的合成、晶体结构和体外抗肿瘤活性,化合物1的X-射线单晶结构分析表明:这是一个很少见的具有四方锥几何构型的铂(II)配合物,顺式平面四方形配位的铂的轴向上有第5个配位原子。其抗肿瘤活性实验显示3个配合物对几种研究的癌细胞都有较强的抑制作用。     

Pb isotopic geochemical study on the crustal structure of Tongbaishan

Pb isotopic composition of the Tongbai complex, distributed in the Tongbaishan to the west of the Dabieshan, ranges between the Dabie core complex and the Dabie ultral-high pressure (UHP) metamorphic complex, the latter having more radiogenic Pb isotopic composition than the former. Granites from the Jigongshan pluton, which intruded mainly into the Tongbai complex, are distinct from the Tongbai complex but similar to the Dabie core complex in Pb isotopic composition, showing that the magma of the Jigongshan granites was derived from the partial melting of the Dabie core complex. According to Pb isotopic compositional variation model in the vertical crustal section and magma source from the Jigongshan pluton, it is suggested that the Tongbai complex was an upper rock serial of the Dabie core complex, which is beneath the Dabie UHP metamorphic complex in the crustal structure of the Tongbai-Dabie orogenic belt. The Tongbai complex was not well preserved in the Dabie area due to the high exhumed crustal section. However, the crustal section in the Tongbai area was exhumed less than that in the Dabie area, and the deep crust in the Tongbai area still contains the basement composition similar to the Dabie core complex. Therefore, the crustal basements from the Dabie to Tongbai areas are united. The present distribution of the basement blocks in different locations of the Tongbai-Dabie orogenic belt reflects different exposure of the crustal section.     

Nd isotopic characteristics of Proterozoic metasedimentary rocks and constraints on their provenance in the eastern segment of Central Tianshan Belt, Xinjiang

Sm-Nd isotopic characteristics, εNd(t) values and Nd model ages (TDM) of Proterozoic metasedimentary rocks in the eastern segment of Central Tianshan Belt (ESCTB), Xinjiang, are used to constrain the sedimentary provenance as well as to evaluate their tectonic implications. εNd(t) and TDM values of these samples range from -4.00 to +6.36 and from 1.29 to 2.29 Ga, respectively. These feature values are distinguished from those of Archean Tarim Craton. Their average εNd(t) values of the Weiya, the Kumishi and the south to the Dikar samples are -2.46, +2.06 and +1.37, respectively. Nd model ages of the Weiya samples vary between 1.86 and 2.29 Ga, but those of the Kumishi and the south to the Dikar samples show a significant concentration at 1.6～1.9 Ga and the youngest Nd model age is 1.29 Ga. Those Nd isotopic characteristics suggest that these metasedimentary rocks could be derived from a significant proportion of Paleoproterozoic crustal source and a participation of young arc materials, rather than Archean Tarim Craton. Furthermore, the data also indicate that these two sources were paleogeographically separated. Thus we can deduce that the Kumishi and the south to the Dikar metasedimentary rocks were formed proximal to the arc side of the back-arc basin, but the Weiya metasedimentary rocks were closer to the continental side of the back-arc basin.     

Isotopic evolution of the terminal Neoproterozoic and early Cambrian carbon cycle on the northern Yangtze Platform, South China

Profound geotectonic, climatic and biological changes occur during the terminal Neoproterozoic and its transition into the early Cambrian. These are reflected in temporal variations of the chemical and isotopic composition of seawater. We are studying a sequence of sedimentary rocks at the Shatan section, northern Yangtze Platform, Sichuan Province of China. This succession comprises, in ascending stratigraphic order, predominantly calcareous sediments of the Sinian upper Dengying Formation and black shales of the lower Cambrian Guojiaba Formation (time equivalent of Niutitang Fm.). Paleoenvironmental setting represents shallow-water shelf deposits. The objective of our study is to provide temporal records for the isotopic compositions of organic and carbonate carbon throughout this time interval. Organic carbon isotope values display a range between -35.8‰ and -30.1‰ with clear stratigraphic variations. Carbonate carbon isotope data vary between -3.5‰ and +0.5‰. These secular variations are interpreted to reflect perturbations of the global carbon cycle, specifically changes in the fractional burial of organic carbon. However, local conditions have further affected the isotopic signals.     

研究型大学政府间国际科技合作的现状、效益和趋势

本文讨论了政府间国际科技合作在研究型大学中的地位和作用。以浙江大学为案例 ,介绍了政府间国际科技合作的现状及带来的效益。并以此为例预测了政府间国际科技合作在研究型大学中的发展趋势     

对培育建筑企业技术创新能力的思考

知识经济时代 ,知识资源已成为企业竞争的核心 ,培育建筑企业技术创新能力 ,丰富建筑企业知识资源 ,是实施建筑企业科技兴业、质量兴业和输出兴业战略的迫切需要 ,通过建筑企业的观念创新、系统规划、管理创新、机制创新、文化创新、优化人才资源、强化教育培训、积极引进先进技术、加大投资力度、全员互动来培育和提高其技术创新能力 ,以促进建筑企业技术进步 ,增强建筑企业的国际竞争能力     

发展循环经济的科技策略的探讨

自工业革命以来 ,人类创造了大量的物质财富 ,但也付出了沉重的代价 ,环境污染和地球生态系统的破坏 ,已经严重影响并会制约经济的发展。当前的经济已经从工业经济向循环经济演进 ,如何在保持经济发展的同时不破坏环境 ,作者提出了发展循环经济的科技策略 ,即重构、调整、及合作 ,对当前经济发展具有一定的指导作用。     

内蒙古师范大学中老年教职工血脂、血糖指标检测结果分析

对内蒙古师范大学840名中老年教职工空腹血糖(SG)、甘油三酯(TG)、总胆固醇(T—CH)的测定结果进行了统计分析。结果表明，男性和女性血糖异常率分别为5．09％和3．95％，男性和女性高甘油三酯症的检出率分别为21．53％和13．98％，均为男性高于女性；男性和女性高总胆固醇检出率分别为7．63％和7．90％，无明显差异，男性和女性上述3项指标的平均值和异常检出率均随年龄增长呈上升趋势，且50岁后变化较明显。     

井下掺液抽稠油泵研究

通过对常规泵进行串联、改造 ,研制出了井下掺液抽稠油泵。对泵结构的可行性进行了论证 ,阐述了泵的工作原理 ,并对泵的工作参数进行了分析。该泵是通过从油管掺入液、从油套环空产出液 ,在上冲程时吸入产出液 ,在下冲程时举升混合液 ,从而实现了在柱塞下方掺液 ,避免了出现砂磨柱塞的现象 ,减少了稠油对柱塞运动的阻力 ,克服了泵上掺液不能降低进泵原油粘度的缺点 ,解决了在井筒降粘和稠油抽汲中存在的问题。该泵使用了连动式凡尔与弹簧 ,保证了底阀与顶阀打开与关闭的同步性 ,能够达到吸入产出液、加入掺入液以及举升混合液同时进行的目的。该泵的设计原理可行 ,工艺容易实现 ,是一种理想的新型抽稠油泵。     

准噶尔盆地陆东地区白垩系储层特征及其主控因素

从岩石学特征、成岩作用、孔隙类型、结构特征以及储层性质的主要影响因素等方面 ,对准噶尔盆地陆东地区白垩系储层进行了研究。结果表明 ,储层岩石为长石质岩屑砂岩 ,成岩作用进入早成岩B亚期 ;孔隙类型主要为原生残余粒间孔 ,另有少量的溶蚀孔及微孔隙。该储层孔隙结构非均质性强 ,呼二段中粗孔喉最多 ,呼一段次之 ,连木沁组多为中孔细喉和较细喉 ,清水河组为细孔、细喉。储层性质差别较大 ,呼一段、呼二段为中孔、中渗储层 ,连木沁组为低孔、低渗储层 ,清水河组为低孔、特低渗储层。储层性质主要受沉积相、古气候、压实作用及砂岩粒径等因素的影响。