Synthesis and luminescence properties of Mn4+-dopant Ca14Zn6Ga10−xAlxO35 solid solution

Mn~(4+)-activated oxide phosphors,owing to their desirable spectral features,eco-friendly and low cost,are emerging as a new class of non-rare-earth red phosphors for warm white LEDs.However,these phosphors possess low photoluminescence quantum efficiency excited by blue chip currently.Herein we report an isostructural solid solution of Ca_(14)Zn_6Ga_(10-x)Al_xO_(35):0.15Mn~(4+)(0≤x≤10)synthesized by a traditional solidstate reaction route.The microstructure and luminescent performance of this red-emitting phosphor are investigated in detail with the aids of X-ray diffraction,diffuse reflection spectra,photoluminescence spectra/decay/QE,and temperature-dependent PL/QE measurements.Blue shift of energy peaks of~4A_2→~4T_1and~4A_2→~4T_2transition is illustrated by the Tanabe–Sugano diagram and the configurational coordinate diagram.The crystal field strength(Dq)and the Racah parameters(B and C)are carefully calculated to estimate the nephelauxetic effectβrespectively.Particularly we achieve external and internal quantum efficiencies as high as26.1%and 40.3%for Ca_(14)Zn_6Ga_6Al_4O_(35):0.15Mn~(4+)excited by 466 nm,the highest one ever reported in Mn~(4+)activated oxide phosphors under the similar condition.     

Damage evolution and failure mechanism of thermal barrier coatings under Vickers indentation by using acoustic emission technique

Acoustic emission(AE) technique was adopted to monitor the damage evolution of air plasma-sprayed(APS) yttria-partially-stabilized zirconia(YSZ) thermal barrier coatings(TBCs) during instrumented indentation testing, and then the failure mechanisms were investigated by cluster analysis and wavelet transform methods.The results of cluster analysis showed that there were three classes associated with distinct failure types for the 8YSZ coatings under Vickers indentation. Based on wavelet transform, these three clusters could be clearly distinguished from their dominant frequency bands, which were concentrated on levels A5(0–156.25 kHz), D5(156.25–312.5 kHz) and D4(312.5–625 kHz), respectively. Thus, the failure mechanism of 8YSZ coatings under Vickers indentation could be clarified by the distribution of different failure types in indentation depth. To sum up, as indentation load increases, the 8YSZ coatings can accommodate the indenter by elastic or little plastic deformation, microcracks propagation and then debonding at the splat boundaries. By comparing the distribution of AE signals induced by different failure types in indentation depth for samples with different thermal exposure time, it can be inferred that thermal exposure treatment can accelerate the degradation of APS 8YSZ TBCs.     

基于声源定位的头部姿态检测系统研究与实现

研究了声源定位技术在鼾声检测上的应用,主要研究鼾声的声学特性、声源定位技术原理,并利用声源定位技术对人体打鼾时头部姿态进行识别.采用广义互相关函数法对多路声音采集系统采集到的鼾声信号进行延迟估计计算,根据得到的相对时延信息进行声音定位,结合定位信息和朝向信息推断出当前受试者打鼾时头部姿态.采用数据采集卡进行高速信号采集,使用虚拟仪器Labview进行信号处理和算法实现,实验中受试者以不同头部姿态在该系统监测下模拟打鼾,通过该系统检测头部姿态,综合判断正确率达到80%.     

力学性能对矿柱体系破坏影响的三维数值分析

在深部高应力等复杂地质条件下开采时,由多个矿柱构成的矿柱体系的稳定性对矿山安全生产至关重要.利用RFPA^3D-Parallel程序,研究了单轴抗压强度对串行和并行矿柱体系破裂过程的影响.结果表明,串行矿柱中强度较弱部分的失稳决定整个体系的稳定,对该段加固和监测有助于体系的稳定性控制;对并行布设的矿柱体系,其压力传递与柱的抗压强度密切相关,较弱柱先破坏,应力依次向强度较高的柱转移,直到矿柱系统失稳;可将声发射数的多峰现象或声发射累积增长阶梯型弧段作为矿柱体系中弱柱失稳破裂、应力向相邻强柱转移的依据.     

含孔花岗岩破裂过程不同区域声发射特征

利用孔洞对声发射(AE)传播的阻隔作用,对AE探头监测区域进行分区.通过含孔花岗岩双轴加载破坏过程的AE多通道监测实验,研究了岩石变形破坏过程不同区域AE特征及其与破坏模式之间的关系.结果表明:试件的AE探头监测区域分为独测区、共测区、盲测区;试件共有两种破坏形式,“V”型和贯穿型;对于“V”型破坏的试件,主破裂发生在独测区,各通道的AE特征明显不同;对于贯穿型破坏试件,主破裂发生于共测区,各通道的AE特征较为相近.     

航空器巡航阶段空气污染的排放和扩散

为了探索航空器巡航阶段的排放和扩散,本文假设航空器巡航阶段推力为其最大推力的70％,以国际民航组织（International Civil Aviation Organization,ICAO）发动机排放数据库中的GEnx-2B67/P发动机氮氧化物（NOx）的排放为例,利用全空域航空排放评估系统（System for Assessing Aviation’s Global Emissions,SAGE）进行数值仿真,计算得到飞行方向上的排放强度。然后假设飞行方向为恒定的线源排放方向,且与风向垂直,基于高斯扩散模型,得到航空器巡航阶段的污染扩散模型。最后采取ICAO在2012 年美国俄亥俄州Peebles数据,对NOX浓度扩散进行数值仿真,成功计算出当时当地GEnx-2B67/P发动机在巡航状态下飞机排放的NOX浓度分布情况。     

基于贝叶斯推断的脉冲星偏振位置角拟合算法

脉冲星辐射束的偏振位置角与相位的关系可用旋转矢量模型(RVM)描述,现有的Levenberg-Marquardt非线性拟合和格点搜寻算法对RVM的拟合存在效率低、易过拟合等问题。本文发展了一套基于贝叶斯推断的马尔可夫链蒙特卡洛算法(MCMC),并用该方法对已有文献中的10颗脉冲星偏振位置角进行了拟合。结果表明,MCMC算法不仅能得到与已有文献一致的结果,而且该算法具有高效、不易过拟合、能更好地估计参数的可信度区间等优点。     

基于模态扩展的变速器箱体振动识别及辐射噪声优化

提出一种基于模态扩展技术的变速器箱体振动识别方法.以某变速器为例,应用有限元方法计算出变速器箱体的模态频率和特征向量,通过试验测得箱体在运行工况下部分点的振动加速度,将振动加速度映射到有限元模型上,得到各阶模态的参与因子,依据模态参与因子与特征向量识别箱体有限元模型中所有节点的振动加速度.研究表明,识别出的加速度值与实测值的最大平均残差为9.7%,基于模态扩展技术的箱体振动识别方法有效.最后根据识别的加速度计算变速器箱体辐射声功率,确定了3个辐射声功率较大的区域并进行优化,优化后的变速器箱体辐射声功率最大下降1.8dB.     

核裂变中子发射多重性的蒙特卡罗模拟

本文采用c,h,α参量描述核的形变,建立了含中子发射的朗之万耦合模型,并完成了核裂变前中子发射多重性的蒙特卡罗计算.经过验证,采用蒙特卡罗方法得到的计算结果与实验结果符合较好;另外,本文区分了鞍点前及鞍点后的中子发射,重点考察了裂变核的鞍点振荡,发现鞍点振荡期间的中子发射多重性不可忽略,并且其数量随入射粒子实验室能量及复合核质量数的增加而增大,因此对于热的重核,鞍点振荡期间的中子发射多重性将极大地影响核裂变碎片角分布的计算.     

模糊环境下含次品供应链成本与碳排放优化管理

针对生产过程不完美并且考虑将次品返运回生产方的二级闭合供应链系统,基于所有参数和决策变量均为梯形模糊数的情景,研究如何利用碳限额与交易机制实现对供应链总成本与碳排放的有效管理.建立供应链模糊总成本与碳排放优化模型,利用梯级平均综合表示法和Kuhn-Tucker条件法求解得到经济订货量、最优总成本和最小碳排放.结果表明:模糊参数相对于确定参数的不同方向与幅度的变化会导致差异较大的决策结果;次品率对总成本的影响与生产率和碳限额的影响方向相反,碳价对总成本的影响受给定碳限额的制约;次品率降低、生产率和碳价提高会降低碳排放,碳限额对碳排放无直接影响.