化学法制备微米铜粉的研究

在NH3-NH4Cl体系中,以NH3为配合剂,利用铜自身的还原作用,通过岐化反应制备微米级铜粉,其中一定比例的铜粉粒度接近纳米级,在空气中相当稳定.NH3的浓度及pH值的控制对反应有重要影响,最佳反应条件是:反应温度为40℃,pH为11.4,NH 4的浓度为0.1mol·L-1,NH3的浓度为12.5mol·L-1;硫酸的浓度和酸化的时间影响产物的粒度,硫酸的质量分数为20%,加酸流速为4mL/min时,产物粒度最小.     

图的最大亏格与面度

利用图在曲面上的嵌入特征,特别是面的度的大小,研究图的最大亏格的下界.     

影响木材火焰传播速度特征量的实验研究

木材着火时火焰的传播规律将为木材在火灾场景中的行为提供重要参考,分析了木材燃烧的机理和影响木材燃烧时火焰传播速度的特征量,借助于实验的方法,研究了空间方位角和几何尺寸等特征量对火焰传播速度的影响.结果表明,方位角越小,不同尺寸木条火焰传播速度差别越大;火焰传播速度随方位角的增大而增大;木条宽度越大,火焰传播速度越慢.     

邻苯二甲酸酯对海洋藻类的致毒效应

采用评价化学药品对藻类毒性的标准方法，对邻苯二甲酸醋与海洋藻类的相互影响进行探讨．通过对邻苯二甲酸二甲酯(DMP)、邻苯二甲酸二乙醋(DEP)、邻苯二甲酸二丁醋(DBP)海洋藻类的致毒试验，分别得出此3种物质对三角褐指藻、盐藻、等边金藻、中肋骨条藻48h、96h的半致死浓度，探讨了上述几种海洋藻类对DMP、DEP、DBP的忍受限度．     

载荷板尺寸效应的试验研究

在试验室模拟路基现场的工况,建立平板载荷试验模型,进行了地基系数与载荷板尺寸的相关性试验,并与理论公式进行了对比。根据试验成果归纳出不同载荷板尺寸的地基系数间的换算公式。     

考虑端部效应的铁磁梁式板磁力摄动分析

基于磁场摄动技术和广义变分原理得到的磁力公式,对铁磁梁式板在斜磁场作用下的磁场和磁力摄动展开研究,给出了斜磁场作用下铁磁梁式板结构的摄动磁场及其磁力摄动表达式,使得解析分析斜磁场作用下铁磁梁式板磁弹性耦合问题成为可能。研究表明:只有考虑了磁场端部效应的斜磁场磁力摄动公式才能模拟铁磁结构的弯曲模式且能够定性揭示铁磁简支梁式板弯曲构形为双半波形。     

The fate of injectant coal in blast furnaces: The origin of extractable materials of high molecular mass in blast furnace carryover dusts

The aim of the work was to investigate the fate of injectant coal in blast furnaces and the origin of extractable materials in blast furnace carryover dusts. Two sets of samples including injectant coal and the corresponding carryover dusts from a full sized blast furnace and a pilot scale rig have been examined. The samples were extracted using 1-methyl-2-pyrrolidinone (NMP) solvent and the extracts studied by size exclusion chromatography (SEC). The blast furnace carryover dust extracts contained high molecular weight carbonaceous material, of apparent mass corresponding to 10⁷?10⁸ u, by polystyrene calibration. In contrast, the feed coke and char prepared in a wire mesh reactor under high temperature conditions did not give any extractable material. Meanwhile, controlled combustion experiments in a high-pressure wire mesh reactor suggest that the extent of combustion of injectant coal in the blast furnace tuyeres and raceways is limited by time of exposure and very low oxygen concentration. It is thus likely that the extractable, soot-like material in the blast furnace dust originated in tars is released by the injectant coal. Our results suggest that the unburned tars were thermally altered during the upward path within the furnace, giving rise to the formation of heavy molecular weight (soot-like) materials.     

非线性随机效应模型的若干统计推断

该文利用非线性随机效应模型在欧氏空间的BW几何结构，求出了固定效应参数估计的渐近性质与随机展开式。利用随机展开式，求出固定效应参数的偏差和方差的曲率表示式。     

平面锥形光波导模斑转换器的研究

基于三维有限差分束传输法（FD－BPM）对平面光波导器件中的关键元件之一－平面锥形模斑转换器作了深入的研究，对线性和数种非线性侧面边界的模斑转换器进行了数值仿真和对比，分析了平面锥形模斑转换器侧面边界函数对耦合损耗的影响，以及模斑转换器中模场分布随传输距离的变化，确定了不同长度的平面锥形模斑转换器的最佳侧面边界，指出长度在200－1000μm范围内具有余弦边界的平面锥形模斑转换器性能最佳，并且发现，光纤中的出射光进入模斑转换器以后，光波模式会逐渐发生变化，并最终转化为单模。     

Contributions of different land cover types in Otindag Sandy Land and Bashang area of Hebei Province to the material source of sand stormy weather in Beijing

Different land cover types in Otindag Sandy Land and Bashang area of Hebei Province are linked to a material source of sand stormy weather in Beijing based on results of field vegetation and soil survey and laboratory works. Results of grain size analysis show that dust release potential in per unit area of moving sandy land is small,while lowland meadow and meadow steppe in stony hills have high potential of releasing dusts in per unit area during sand stormy weather occurrence. Further considering the effects of vegetation, it is inferred that the moving sandy land served as a material source of past dust storm and the possibility of dust release in per unit area is low in current time.Typical steppe in stony hills is undergoing desertification and its dust release possibility in per unit area is high. Farmland has strong potential of release dusts when they are ploughed in spring, but a large amount of therophytes grow and thus prevent dusts from release when cultivation was terminated.Potentials of dust release in per unit area in fixed sand dunes,stony mountain meadow steppe and low land meadow are lowdue to high cover of perennials. Sand dune reactivation and desiccation of lakes and lowlands under estimated future climatic change will make them serve as a future material source of sand stormy weather.