NiCoCrAlYTa粘结层与镍基高温合金基体的界面高温互扩散行为

采用真空等离子体喷涂技术(vacuum plasma spraying, VPS)在镍基高温合金GH3128基体表面沉积NiCoCrAlYTa粘结层,并在1 100 ℃进行不同时间的热处理。采用扫描电子显微镜（scanning electron microscopy,SEM）、能谱仪（energy dispersive spectrometer,EDS）等分析NiCoCrAlYTa粘结层与GH3128高温合金界面元素的互扩散行为。结果表明,在热处理过程中,互扩散区(interdiffusion zone,IDZ)和二次反应区(secondary reaction zone,SRZ)的厚度随着热处理时间延长而增大,且在SRZ中明显观察到拓扑密堆(topological close-packed,TCP)相晶粒的生长。Al、Ta、Co元素由NiCoCrAlYTa粘结层向GH3128高温合金扩散,Ni、W、Mo元素由GH3128高温合金向NiCoCrAlYTa粘结层扩散。依据EDS检测的粘结层/基体界面处元素成分,计算出上述元素在界面处的扩散系数,掌握了各元素在高温热处理过程中的扩散速率,揭示了VPS制备的NiCoCrAlYTa粘结层与GH3128高温合金界面处元素在高温下的互扩散规律。     

基于GIS的集成二次开发

介绍了 GIS的集成二次开发技术 ,并指出这种方式正成为应用型 GIS开发的主流方向 ,最后对 Power Builder采用 OL E Automation技术进行 Mapinfo集成开发进行了具体讨论     

均匀半空间中心回线瞬变电磁法正演研究

通过对均匀半空间中心回线装置瞬变电磁法表达式分析,可以为瞬变电磁法的反演提供理论正演数据、可以为瞬变电磁法的反演提供一定的方法,同时还可以为野外生产设计与室内数据筛选与剔除提供一定的参考。通过一个反演实例说明在晚期微小的二次电位误差将对视电阻率的计算会产生很大的影响,并编制了matlab程序计算各种工作装置和视电阻率理论正演二次电位衰减到噪声影响程度高的准确时间,对工程设计、评价视电阻计算的准确度及剔除受噪声影响严重的数据有一定的参考性。     

Structural characterization of two papaya chitinases, a family GH19 of glycosyl hydrolases

Two chitinases, able to use tetra-N-acetylglucosamine, chitin and chitosan as substrates, were characterized after purification from Carica papaya latex. The complete amino acid sequence of the major form and about 40% of the minor one were determined through proteolytic digestions and mass spectroscopy analysis. Sequencing demonstrated that both papaya chitinases are members of the family 19 of glycosyl hydrolases (GH19). Based on the known 3-D structures of other members of family GH19, it was expected that papaya chitinases would adopt all-alpha structures. However, circular dichroism and infrared spectroscopy indicated, for the papaya chitinases, a content of 15–20% of extended structures besides the expected 40% of alpha helices. Since the fully sequenced papaya chitinase contains a large number of proline residues the possibility that papaya chitinase contains polyproline II stretches was examined in the context of their resistance against proteolytic degradation. Received 11 July 2006; received after revision 13 October 2006; accepted 25 October 2006     

巢湖流域典型城市环城河沉积物重金属形态及垂直分布特征

采用改良的连续提取法(BCR)对巢湖市环城河沉积物重金属总量及其赋存形态进行了测定和分析.结果表明,巢湖市环城河采样点表层(0～10 cm)沉积物中重金属的质量分数分别为29.5～224.3 mg·kg-1 (Pb),21.3～78.1 mg·kg-1 (Ni),67.5～1 126.3 mg·kg-1 (Cr),50.7～217.4 mg·kg-1 (Cu);新城区西环城河沉积物重金属的质量分数明显高于老城区东环城河;其中以Cr的质量分数在不同采样点差异最为显著.不同采样点沉积物中重金属总量随深度变化特征差异明显,西环城河沉积物不同深度重金属的质量分数较低,且随深度变化较小;受污染较严重的东环城河沉积物不同深度重金属的质量分数普遍较高,且垂直变化波动较大;所调查的4个沉积物柱状样能较好表征周边环境现状和污染历程.4个采样点不同深度沉积物重金属的可交换及碳酸盐结合态的质量分数占总量的百分比均不超过5％,Pb主要以铁锰氧化物结合态存在;Ni主要以残渣态存在;Cr主要以有机物及硫化物结合态和残渣态存在;Cu则主要以铁锰氧化物结合态和残渣态存在;不同采样点柱状沉积物各重金属形态垂向分布也存在显著差异,次生相与原生相分布比值(Rsp)法分析结果显示,巢湖市东环城河2个采样点柱状沉积物R.值明显高于西环城河,其重金属潜在污染生态风险较高,其中Pb和Cr属于中度或重度污染水平.     

基于Pro/Toolkit的形位公差国标标注系统的二次开发

论述了在Pro/E Wildfire 4.0的环境下,利用VC++.Net技术和Pro/E二次开发工具Pro/Toolkit,通过动态连接库方式来实现形位公差标注的二次开发定制.并对其中所涉及到的菜单以及MFC对话框等关键技术进行了开发设计,研究出符合国标且简单易用的形位公差标注插件.     

辽河油田齐40块蒸汽驱二氧化碳成因分析

渤海湾盆地辽河油田欢喜岭地区齐40块稠油油藏历经多年的蒸汽驱开发,其伴生气体中CO2含量已上升至60％ ～90％.通过对该区块的油藏条件及开发前后的储层流体矿物分析,认为CO2浓度的上升主要由于蒸汽驱开发导致油藏温度升高,储层流体和矿物发生化学反应结果,其中与CO2形成有关的化学反应包括:稠油水裂解、硫酸盐热还原、矿物...     

PVA-ECC加固RC足尺梁受弯性能试验研究

对6根足尺聚乙烯醇纤维水泥(PVA-ECC)加固的钢筋混凝土梁进行了正截面抗弯一次和二次受力的试验研究.通过与另1根同配置未加固钢筋混凝土梁的试验结果的对比,研究了加固梁纵向加固配筋率对抗弯承载力和变形能力的影响.试验采用三面U型加固形式,量测试验梁裂缝分布形态、荷载-挠度曲线、钢筋和混凝土应变发展规律等.试验结果表明PVA-ECC钢筋网薄层加固是一种有效的加固方法,能够显著地提高钢筋混凝土梁的抗弯承载力、截面刚度以及抗裂性能.     

The equilibrium between diagenetic calcites and dolomites and its impact on reservoir quality in the sandstone reservoir of Kela 2 gas field

Based on the equilibrium theory of chemical reactions between water and rocks,this paper establishes a thermodynamic phase relationship diagram among calcites,dolomites and water solution under the condition of diagenesis based on the thermodynamic database of related minerals and fluids and dolomite's degree of order parameters.It has been discovered that the equilibrium between calcites and dolomites in the diagenetic environment is strongly impacted by temperature and the Ca/Mg ratios in groundwater,and that the dolomite's degree of order in the diagenetic environment is a function of crystallization temperature and time,not controlled by water solution.Hereby,the authors make a further analysis of the close relationship of chemical reaction between carbonate cements and pore water in the sandstone reservoirs of Kala 2 gas field in Kuche sag.It can be seen that there are different impacts on sandstone reservoir quality among the equilibrium system of calcites,dolomites and pore water at different depths of reservoirs.     

沥青混凝土油石比对路面提前开裂的影响

某沥青混凝土路面出现提前开裂工程事故,通过现场取样进行了抽提试验,经对比分析各相关因素后,得出沥青用量(油石比)偏低是造成沥青混凝土路面提前开裂的主要诱因之一的结论,据此提出了具有针对性的工程处理措施.