Metabolism of 3β-hydroxycholest-5-en-26-oic acid in hamsters

Summary Metabolism of 26-hydroxycholesterol to 3-hydroxychol-5-en-24-oic acid and other C24-bile acids has been expected to occur by way of 3-hydroxycholest-5-en-26-oic acid in studies in vitro. 3-Hydroxycholest-5-en-26-oic acid was infused intravenously into bile fistula hamsters and the following C24-bile acids were identified: 3-hydroxychol-5-en-24-oic acid, lithocholic acid, chenodeoxycholic acid, and a small amount of cholic acid.     

Occurrence of 3-epi-22-deoxy-20-hydroxyecdysone and its phosphoric ester in diapause eggs of the silkworm,Bombyx mori

Ecdysteroids in diapause eggs of the silkworm,Bombyx mori, were analyzed using high-performance liquid chromatography (HPLC) combined with radioimmunoassay (RIA). A relatively large amount of an unidentified free ecdysteroid and its phosphoric ester (conjugated form) were detected. These two compounds were isolated by a combination of column chromatography on silicic acid, thin-layer chromatography (TLC), and HPLC using a reverse-phase (RP) column. The purified compounds were identified as 3-epi-22-deoxy-20-hydroxyecdysone (22d20E) and 3-epi-22-deoxy-20-hydroxyecdysone 2-phosphate (22d20E2P) by means of mass spectrometry and nuclear magnetic resonance spectroscopy. to our knowledge, this is the first report of 22d20E and 22d20E2P.     

高分子力学中的Valanis－Landel假说

根据经验公式的建立原则和橡胶的各向同性性能,讨论了Ｖａｌａｎｉｓ－Ｌａｎｄｅｌ假说中关于“任何一种应变类型的应力一应变关系,可从单一的纯剪试验推导出来”这一重要结论,并证明了结论的正确性,还研究了结论的应用。     

WS~*-闭空间的性质

该文引入了一类包含Ｓ－闭空间的拓扑空间——ＷＳ＊－闭空间,并讨论了它的一些性质,对一些关于Ｓ－闭空间的已知命题,建立或推广得到ＷＳ＊－闭空间的相应命题。     

一种磨茹香气香料——1-辛烯-3-醇的合成与应用研究

从１－戊醇出发,通过卤代反应,格氏反应,制备得到１－辛烯－３－醇。该产品具有愉快的蘑菇香气,可用于食品香精的调配中。     

Cu~(2+)与三磺基四苯基啿卟啉配位反应研究

利用吸收光谱法和直流极谱法研究了Cu~(2+)的还原状态、抗坏态、抗坏血酸浓度及溶解氧对Cu~(2+)与三磺基四苯基卟啉配位反应的影响。结果表明Cu~(2+)与三磺基四苯(?)基四苯基卟啉配位反应的可能机制为抗坏血酸首先将高价铜还原为亚铜,亚铜离子与配位剂生成对氧成对氧敏感的不稳定中间体Cu~(Ⅰ)——三磺基四:苯基卟啉配合物,立即又被溶解氧氧化为Cu(Ⅱ)——Ⅱ)——三磺基四苯基卟啉配合物。     

SAG法合成钛酸铅纳米晶粒的工艺和结构研究

ＳＡＧ法合成钛酸铅纳米晶粒的工艺和结构研究李永祥刘泽吴冲若（东南大学电子工程系,南京２１００９６）ＰｂＴｉＯ３是应用广泛的铁电和光电材料之－,研究ＰｂＴｉＯ３纳米晶粒的合成技术和电学性能对基础研究和新型复合功能材料研究都有重要意义．作者曾采用Ｓｏｌ...     

Leakage of mantle helium from the Liaodong Peninsula, China

The isotopic cumpositions of helium have been investigated in hot spring gases sampled from the Liaodong Peninsula. China. The³He/⁴He ratios range from 0.14 Ra (0.14 times the atmospheric³He/⁴He ratio of 1.40 × 10^-6 to 0.72 Ra.³He/⁴He versus⁴He/²⁰Ne ratios and He contents suggest that a small amount of mantle-derived helium reaches the earth’s surface. Helium iwtope ratios of the hot spring gases show a distribution pattern similar to the regional heat flow values, indicating that the positive thermal anomaly occurring in the rtrea is closely associated with the presence of mantle-derived helium. The observations described above provide some significant evidence that the molten magma originating from partial melting of the upper mantle may have intruded into the continental crust along the activity fault. The coupling of the presence of mantle He and heat flow anomalies to seismic activity in studied region seem to imply that there is an internal relationship between mantle degassing and seismic activity.     

KCaF3结构相变的分子动力学模拟

基于无调节参数的Ｇｏｒｄｏｎ－Ｋｉｍ势和一种检测离子运动的新技术,以ＫＣａＦ３的分子动力学模拟结果为例,对钙钛矿ＡＢＸ３的离子分子固体的结构相变作了探讨．包括对阱势、折叠结构、能垒、超离子态、稳定性骨架和离子分子集团ＢＸ６的“尺寸”和“形状”．以期对离子分子固体的结构相变有一个基本了解．     

藏产红景天混合提取物对BALB／c小鼠免疫功能的影响

选择淋巴器官脏器系数,迟发型变态反应,脾脏抗体生成细胞数,巨噬细胞蚕噬指数等免疫免疫学指标观察藏产多种红景天对ＢＡＬＢ／ｃ小鼠免疫功能的影响。结果表明,在５００－２０００ｍｇ／ｋｇ剂量范围内能增加ＢＡＬＢ／ｃ小鼠胸腺的相对重量,足跖厚度及脾脏抗体生成细胞的数量。