Leaching Mechanism of Complicated Antimony-Lead Concentrate and Sulfur Formation in Slurry Electrolysis

Anodic reaction mechanism of complicated antimony-lead concentrate in slurry electrolysis was investigated by the anodic polarization curves determined under various conditions. The main reactions on the anode are the oxidations of FeCln^(2-n) . Though the oxidation of jamesonite particle on the anode can occur during the whole process, it is less. With the help of mineralogy studies and relevant tests, the leaching reaction mechanism of jameson[to and gudmundite during slurry electrolysis was ascertained. Because of the oxidation reaction of FeCl3 produced by antimony-lead concentrate itself, the non-oxidation complex acid dissolution of jameson[re, the oxidation complex acid dissolution of gudmundite, and the oxidation of air carried by stirring, the leaching ratio of antimony reaches about 35% when HCl-NH4Cl solution is used to leach antimony-lead concentrate directly. So when the theoretical electric quantity is given to oxidation of antimony in slurry electrolysis, all of antimony, lead and iron containing in antimony-lead concentrate, are leached. The formation of sulfur is through the directly redox reaction of Fe^3 and jameson[re. The S^2- in jamesonite is oxidized into S^0 , and forms the crystals of sulfur again on the spot. The redox reaction of Fe^3 and H2S formed by non-oxidative acid dissolution of jamesonite is less.     

无纺织物过滤黏土的梯度比试验及机理研究

采用2种土工织物和黏土进行梯度比试验,并通过试验后黏土试样微观结构的电镜扫描,从微观上认识土工织物过滤黏土机制。结果表明:在土工织物过滤黏土的过程中,初期梯度比会快速上升,达到峰值后,织物-黏土体系淤堵情况逐渐缓解,透水性相对改善,梯度比下降并趋于稳定;在过滤过程中靠近织物的黏土中会发生细颗粒穿过土工织物逃逸的现象,这是织物-黏土体系的透水性改善的内在机制;过滤后的黏土主要以聚粒形式存在,结构较疏松,在靠近织物的黏土中出现较大的孔隙;不同孔径和工艺的土工织物过滤黏土机制相同,但淤堵程度不同。     

新工科背景下大学生创新创业能力培养模式研究

为适应新经济、新产业发展的需要,发展新工科,对接新兴产业,培养新工科人才,是当前高等教育领域的热门话题和研究前沿。聚焦如何提高高校新工科人才创新创业能力,首先阐明了大学生创新创业的现状及存在的问题,以蚌埠医学院卫生管理系为例,从课程设置、学生竞赛、创新创业、激励机制、校企合作等5个方面为切入点,探索了创新创业教育的培养模式和实施路径。     

基于遗忘机制的ISWI积极思想传播模型

针对现阶段对积极思想传播的研究较少运用动力学模型进行分析的问题,提出了一种基于遗忘机制的积极思想传播ISWI模型。利用Hurwitz判据、Lyapunov稳定性定理和LaSalle不变性原理,分析并证明了思想传播平衡点的局部稳定性和全局稳定性,并得出了传播阈值与思想传播的影响因子遗忘率和接触率之间的关系。仿真结果表明:遗忘率降低时,思想传播的范围会扩大;接触率提高时,传播范围也会扩大。遗忘率与传播范围呈负相关,接触率与之呈正相关。     

基于超螺旋精度提升机制的OFDM网络信道噪声消除算法

为解决当前OFDM网络信道噪声消除算法难以规避信道中的窄带莱斯噪声,且抗信道衰落能力不强,以及信道间普遍存在严重的频率干涉问题,提出了一种基于超螺旋精度提升机制的OFDM网络信道噪声消除算法.首先,根据各个传输子信道具有差异化的频率载波特性,将传输子信道等价为接收背景中的接收点,从而构建了超螺旋接收结构,有效消除不同传输子信道间存在的频率干扰特性,降低信道窄带莱斯噪声对信号预发射过程的衰落影响;随后,基于角度识别方式进行锐-钝识别,并结合拐点思想,采用序列重排技术,将待发射信号进行消波处理,并进行自旋精度提升,从而提高了其抗窄带莱斯噪声的性能.仿真实验表明:与常见的超高频精度自适应机制(UHF adaptive,UHFA)、共线度自旋精度提升机制(the degree of accuracy of collinear spin,DACS)相比,本文算法与理想状态下的OFDM功率谱密度曲线最为接近,具有更高的信号增益水平与更低的信道误码率.     

基于Jacobian矩阵的5UPS-RPS并联机构全域性能指标分析

提出一种由一个RPS约束分支和5个UPS主动分支构成的新型空间对称五自由度并联机构.为研究动平台和定平台半径变化对该五自由度并联机构速度性能指标的影响规律,利用虚设机构法求出机构一阶和二阶影响系数矩阵,并推导了速度和加速度表达式,利用推导的Jacobian矩阵对机构进行速度全域性能指标分析,并绘出上述性能指标图谱,得到动平台和定平台尺寸变化对并联机构性能的影响趋势,同时也得到所给动平台和定平台尺寸范围内速度性能较好的尺寸,为机构优化设计提供了理论依据.      

Damage evolution and failure mechanism of thermal barrier coatings under Vickers indentation by using acoustic emission technique

Acoustic emission(AE) technique was adopted to monitor the damage evolution of air plasma-sprayed(APS) yttria-partially-stabilized zirconia(YSZ) thermal barrier coatings(TBCs) during instrumented indentation testing, and then the failure mechanisms were investigated by cluster analysis and wavelet transform methods.The results of cluster analysis showed that there were three classes associated with distinct failure types for the 8YSZ coatings under Vickers indentation. Based on wavelet transform, these three clusters could be clearly distinguished from their dominant frequency bands, which were concentrated on levels A5(0–156.25 kHz), D5(156.25–312.5 kHz) and D4(312.5–625 kHz), respectively. Thus, the failure mechanism of 8YSZ coatings under Vickers indentation could be clarified by the distribution of different failure types in indentation depth. To sum up, as indentation load increases, the 8YSZ coatings can accommodate the indenter by elastic or little plastic deformation, microcracks propagation and then debonding at the splat boundaries. By comparing the distribution of AE signals induced by different failure types in indentation depth for samples with different thermal exposure time, it can be inferred that thermal exposure treatment can accelerate the degradation of APS 8YSZ TBCs.     

力学性能对矿柱体系破坏影响的三维数值分析

在深部高应力等复杂地质条件下开采时,由多个矿柱构成的矿柱体系的稳定性对矿山安全生产至关重要.利用RFPA^3D-Parallel程序,研究了单轴抗压强度对串行和并行矿柱体系破裂过程的影响.结果表明,串行矿柱中强度较弱部分的失稳决定整个体系的稳定,对该段加固和监测有助于体系的稳定性控制;对并行布设的矿柱体系,其压力传递与柱的抗压强度密切相关,较弱柱先破坏,应力依次向强度较高的柱转移,直到矿柱系统失稳;可将声发射数的多峰现象或声发射累积增长阶梯型弧段作为矿柱体系中弱柱失稳破裂、应力向相邻强柱转移的依据.     

玉米芯基活性炭吸附去除水中重金属的实验及机理研究

运用农作物废弃物玉米芯为原料,通过马弗炉在不同工艺条件下碳化制备玉米芯基活性炭,考察了其对锌、锰和铅三种重金属的吸附性能,并利用傅里叶红外光谱、扫描电镜(SEM及EDS)等手段研究了其吸附重金属锌的机理,并对吸附后的吸附剂进行解吸实验.实验结果表明,合适工艺下生产的玉米芯基活性炭对水中锌离子有极高的吸附率,吸附动力学行为符合准二级动力学方程;对玉米芯基活性炭的解吸,酸解吸法比电场干预解吸法能取得更好的效果.初步判断玉米芯基活性炭可用于吸附重金属,是一种低成本吸附剂.     

铜钼浮选分离中硫化钠的消耗机理

针对铜钼浮选分离生产过程中,往往存在着硫化钠抑制剂消耗量过大、生产成本过高的现象,使用硫离子选择电极动态监测不同条件下硫化钠溶液中硫离子电位,来初步研究硫化钠大量消耗的机理.结果表明:铜钼浮选分离过程中,空气的鼓入和矿浆的未加温处理会增加硫化钠的氧化消耗,是硫化钠消耗量大的原因之一.浮选矿浆中的矿物(如辉钼矿、黄铜矿和黄铁矿)有着催化硫化钠氧化分解的作用,加上矿物本身对硫化钠的吸附作用,是造成铜钼浮选分离过程中硫化钠大量消耗的又一原因.此外,矿浆中溶出的少量金属阳离子(如Cu²⁺和Fe³⁺)对硫化钠的氧化分解也有一定作用,进一步加剧了硫化钠的消耗.